• 한국수소및신에너지학회논문집
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• 제12권4호
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• pp.287-292
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• 2001

The optical transmittance change of Pd thin film due to hydrogen absorption and desorption was examined at room temperature. Hydrogen absorption and desorption cycling effects on optical transmittance were measured 6 times in the pressure range between 0 and 640 torr. Optical transmittance of Pd film was increasing with increasing hydrogen pressure. Ratio of optical transmittance to the change of pressure at $\beta$ phase is bigger than that of low hydrogen pressure range.

• 한국압력기기공학회 논문집
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• 제19권2호
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• pp.117-129
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• 2023

Hydrogen embrittlement of a pipe is an important factor in hydrogen transport. To characterize hydrogen embrittlement, tensile and fracture toughness tests should be conducted. However, in the case of hydrogen-embrittled materials, it is difficult to perform tests in hydrogen environment, particularly at low temperatures. It would be useful to develop a methodology to predict the fracture toughness of hydrogen-embrittled materials at low temperatures using more efficient tests. In this study, the fracture toughness of API X52 steels in hydrogen at low temperatures is predicted from numerical simulation using coupled finite element (FE) damage analyses with FE diffusion analysis, calibrated by analyzing small punch test data.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.67-76
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• 2000

Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집A
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• pp.67-76
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• 2000

Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

• 한국가스학회지
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• 제19권6호
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• pp.85-91
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• 2015

전 세계적으로 수소에너지에 대한 관심이 점차 증가함에 따라 수소 생산, 저장, 운송, 이용 분야에서 응용 기술의 개발이 활발히 진행되고 있다. 국내에서도 울산 수소타운을 조성하여 시범운영 중에 있어 수소에너지 응용처 확대에 대한 가능성을 높이고 있다. 울산 수소타운은 가스 사용 압력에 따라 고압부와 저압부로 구분할 수 있는데 고압부는 '고압가스안전관리법'을 적용하여 안전관리를 하고 있고 저압부는 '수소타운 시범사업의 안전관리에 관한 지침'을 적용하여 운영 중에 있다. 본 논문에서는 울산 수소타운 내 0.1MPa 이하 저압 수소 사용시설의 안전관리 효율성 향상을 위해 저압 수소사용 시설 및 안전관리 항목 분석을 통해 안전관리 방향성을 검토하고 향후 개선 방향을 제시하고자 하였다. 본 연구의 결과를 통해 국내 수소타운 활성화 및 안전 관리 효율성 증대에 도움이 될 수 있을 것으로 기대한다.

• 항공우주시스템공학회지
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• 제18권3호
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• pp.8-16
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• 2024

수소는 매우 낮은 밀도를 갖기 때문에 화석연료와 동일한 수준의 에너지량을 저장하기 위해서는 기존과 다른 저장방식이 요구된다. 수소의 밀도를 높이는 방법으로는 수소를 액화하여 저장하는 방법이 있다. 하지만, 수소의 액화온도는 -252 ℃의 극저온이기 때문에 외부 열 유입에 의해 쉽게 기화된다. 액체수소가 기화되면 탱크 내부의 압력이 증가되는 자가증압 현상을 발생하므로, 탱크 설계 시 이 상승하는 압력을 잘 예측해야 한다. 따라서, 본 논문에서는 극저온 액체수소 연료탱크의 액체수소 충전 비율에 따른 내부 압력을 예측하였다. 탱크 내부의 압력 상승을 예측하기 위하여 1차원 열역학적 모델을 적용하였다. 열전달 모델은 열 유입, 액체수소의 기화, 연료 배출에 현상이 고려되었다. 최종적으로 연료탱크 내의 액체수소의 충전 비율에 따라 압력 상승 거동과 최대 상승 압력에 큰 차이가 있음을 확인하였다.

• 한국분무공학회지
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• 제27권2호
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• pp.84-93
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• 2022

To implement carbon-neutrality in transportation sectors until 2050, hydrogen is considered a promising fuel for internal combustion engines because hydrogen does not contain carbon itself. Although hydrogen does not emit CO₂ emission from its combustion process, the low energy density in a volume unit hinders the adoption of hydrogen. Therefore, the understanding of hydrogen jet behavior and measurement of equivalence ratio must be conducted to completely implement the high-pressure hydrogen direct injection. The main objective of this research is feasibility test of hydrogen local equivalence ratio measurement by laser-induced breakdown spectroscopy (LIBs). To visualize the macroscopic structure of hydrogen jet, high-speed schlieren imaging was conducted. Moreover, LIBs has been adopted to validate the feasibility of hydrogen local equivalence ratio measurement. The hydrogen injection pressure was varied from 4 MPa to 8 MPa and injected in a constant volume chamber where the ambient pressure was 0.5 MPa. The increased injection pressure extends the vertical penetration of hydrogen jet. Due to the higher momentum supply when the injection pressure is high, the hydrogen has easily diffused in all directions. As the laser trigger timing has delayed, the low hydrogen atomic emission was detected due to the longer mixture formation time. Based on equivalence ratio measurement results, LIBs could be applied as a methodology for hydrogen local equivalence ratio measurement.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.689-697
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• 2023

The high-pressure hydrogen valve is intended to supply hydrogen charged at high pressure in the hydrogen tank to the fuel cell stack, which decompresses high-pressure hydrogen gas to low pressure and primarily limits the excessive flow. It consists of a pilot valve, a main valve, and a excessive flow valve to operate in a wide pressure range from 2 to 70 MPa of charging pressure. The opening characteristics of the valve were confirmed by computation fluid dynamics applying the moving grid technique. The behavior of the valve was predicted by predicting the force acting on the valve over time. In addition, the difference in behavior according to supply pressure was compared.

• 한국수소및신에너지학회논문집
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• 제24권4호
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• pp.302-310
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• 2013

As an initial step to develop a liquid hydrogen pump of piston type operated under cryogenic and high pressure, leakage and piston head shape for the piston pump were discussed with temperature and pressure. As the results, the leakage depended on correlation among density, viscosity, clearance area by the low temperature. In order to reduce the leakage, it was found that the air-tightness can be improved by minimizing contact surface between piston and cylinder, and also increasing pressure in-cylinder can reduce piston clearance. Among the proposed piston shapes, D type piston shape had the most air-tightness. D type piston had smaller contact surface than other piston shape and easier expansion of cup shape by pressure. The leakage of D type piston shape was found about 7%, compared with A type piston shape. But it was required that analyze about vapor lock by friction and wear resistance.

• 한국수소및신에너지학회논문집
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• 제32권3호
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• pp.163-171
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• 2021

Securing energy sources is a key element essential to economic and industrial development in modern society, and research on renewable energy and hydrogen energy is now actively carried out. This research was conducted through experiments and analytical methods on the hydrogen filling process in the hydrogen storage tank of the hydrogen charging station. When low-temperature, high-pressure hydrogen was injected into a high-pressure tanks where hydrogen is charged, the theoretical method was used to analyze the changes in temperature and pressure inside the high-pressure tanks, the amount of hydrogen charge, and the charging time. The analysis was conducted in the initial vacuum state, called the First Cycle, and when the residual pressure was present inside the tanks, called the Second Cycle. As a result of the analysis, the highest temperature inside the tanks in the First Cycle of the high-pressure tank increased to 442.11 K, the temperature measured through the experiment was 441.77 K, the Second Cycle increased to 397.12 K, and the temperature measured through the experiment was 398 K. The results obtained through experimentation and analysis differ within ±1%. The results of this study will be useful for future hydrogen energy research and hydrogen charging station.