• Transactions of the Korean hydrogen and new energy society
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• v.12 no.4
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• pp.287-292
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• 2001

The optical transmittance change of Pd thin film due to hydrogen absorption and desorption was examined at room temperature. Hydrogen absorption and desorption cycling effects on optical transmittance were measured 6 times in the pressure range between 0 and 640 torr. Optical transmittance of Pd film was increasing with increasing hydrogen pressure. Ratio of optical transmittance to the change of pressure at $\beta$ phase is bigger than that of low hydrogen pressure range.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.19 no.2
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• pp.117-129
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• 2023

Hydrogen embrittlement of a pipe is an important factor in hydrogen transport. To characterize hydrogen embrittlement, tensile and fracture toughness tests should be conducted. However, in the case of hydrogen-embrittled materials, it is difficult to perform tests in hydrogen environment, particularly at low temperatures. It would be useful to develop a methodology to predict the fracture toughness of hydrogen-embrittled materials at low temperatures using more efficient tests. In this study, the fracture toughness of API X52 steels in hydrogen at low temperatures is predicted from numerical simulation using coupled finite element (FE) damage analyses with FE diffusion analysis, calibrated by analyzing small punch test data.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.67-76
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• 2000

Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

• Proceedings of the KSME Conference
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• 2000.11a
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• pp.67-76
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• 2000

Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

• Journal of the Korean Institute of Gas
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• v.19 no.6
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• pp.85-91
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• 2015

As the interest in hydrogen energy is being increased, it is a widely issue to develop a lot of hydrogen technologies in the field of production, storage, transportation, application and others. In the aftermath, there is a hydrogen town in Ul San, which is expected to expand application fields of hydrogen energy, as a demonstration project. The hydrogen town in Ul San can consist of high and low pressure part by the gas pressure. The high pressure part is managed by 'the high pressure gas safety control act'. And, low pressure part is managed by 'the guideline for the safety management of demonstration project of hydrogen town'. In this paper, to improve efficiency of safety management, the direction of safety management is reviewed by an analysis of low pressure hydrogen facility and safety management items. And then, some improvement directions are suggested. In the end, it is expected that the results of this study could help to activate construction of hydrogen town and improve efficiency of safety management as well.

• Journal of Aerospace System Engineering
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• v.18 no.3
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• pp.8-16
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• 2024

Because hydrogen has very low density, a different storage method is required to store the same amount of energy as fossil fuel. One way to increase the density of hydrogen is through liquefaction. However, since the liquefied temperature of hydrogen is extremely low at -252 ℃, it is easily vaporized by external heat input. When liquid hydrogen is vaporized, a self-pressurizing phenomenon occurs in which the pressure inside the hydrogen tank increases, so when designing the tank, this rising pressure must be carefully predicted. Therefore, in this paper, the internal pressure of a cryogenic liquid fuel tank was predicted according to the liquid hydrogen filling ratio. A one-dimensional thermodynamic model was applied to predict the pressure rise inside the tank. The thermodynamic model considered heat transfer, vaporization of liquid hydrogen, and fuel discharging. Finally, it was confirmed that there was a significant difference in pressure behavior and maximum rise pressure depending on the filling ratio of liquid hydrogen in the fuel tank.

• Journal of ILASS-Korea
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• v.27 no.2
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• pp.84-93
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• 2022

To implement carbon-neutrality in transportation sectors until 2050, hydrogen is considered a promising fuel for internal combustion engines because hydrogen does not contain carbon itself. Although hydrogen does not emit CO₂ emission from its combustion process, the low energy density in a volume unit hinders the adoption of hydrogen. Therefore, the understanding of hydrogen jet behavior and measurement of equivalence ratio must be conducted to completely implement the high-pressure hydrogen direct injection. The main objective of this research is feasibility test of hydrogen local equivalence ratio measurement by laser-induced breakdown spectroscopy (LIBs). To visualize the macroscopic structure of hydrogen jet, high-speed schlieren imaging was conducted. Moreover, LIBs has been adopted to validate the feasibility of hydrogen local equivalence ratio measurement. The hydrogen injection pressure was varied from 4 MPa to 8 MPa and injected in a constant volume chamber where the ambient pressure was 0.5 MPa. The increased injection pressure extends the vertical penetration of hydrogen jet. Due to the higher momentum supply when the injection pressure is high, the hydrogen has easily diffused in all directions. As the laser trigger timing has delayed, the low hydrogen atomic emission was detected due to the longer mixture formation time. Based on equivalence ratio measurement results, LIBs could be applied as a methodology for hydrogen local equivalence ratio measurement.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.689-697
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• 2023

The high-pressure hydrogen valve is intended to supply hydrogen charged at high pressure in the hydrogen tank to the fuel cell stack, which decompresses high-pressure hydrogen gas to low pressure and primarily limits the excessive flow. It consists of a pilot valve, a main valve, and a excessive flow valve to operate in a wide pressure range from 2 to 70 MPa of charging pressure. The opening characteristics of the valve were confirmed by computation fluid dynamics applying the moving grid technique. The behavior of the valve was predicted by predicting the force acting on the valve over time. In addition, the difference in behavior according to supply pressure was compared.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.302-310
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• 2013

As an initial step to develop a liquid hydrogen pump of piston type operated under cryogenic and high pressure, leakage and piston head shape for the piston pump were discussed with temperature and pressure. As the results, the leakage depended on correlation among density, viscosity, clearance area by the low temperature. In order to reduce the leakage, it was found that the air-tightness can be improved by minimizing contact surface between piston and cylinder, and also increasing pressure in-cylinder can reduce piston clearance. Among the proposed piston shapes, D type piston shape had the most air-tightness. D type piston had smaller contact surface than other piston shape and easier expansion of cup shape by pressure. The leakage of D type piston shape was found about 7%, compared with A type piston shape. But it was required that analyze about vapor lock by friction and wear resistance.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.3
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• pp.163-171
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• 2021

Securing energy sources is a key element essential to economic and industrial development in modern society, and research on renewable energy and hydrogen energy is now actively carried out. This research was conducted through experiments and analytical methods on the hydrogen filling process in the hydrogen storage tank of the hydrogen charging station. When low-temperature, high-pressure hydrogen was injected into a high-pressure tanks where hydrogen is charged, the theoretical method was used to analyze the changes in temperature and pressure inside the high-pressure tanks, the amount of hydrogen charge, and the charging time. The analysis was conducted in the initial vacuum state, called the First Cycle, and when the residual pressure was present inside the tanks, called the Second Cycle. As a result of the analysis, the highest temperature inside the tanks in the First Cycle of the high-pressure tank increased to 442.11 K, the temperature measured through the experiment was 441.77 K, the Second Cycle increased to 397.12 K, and the temperature measured through the experiment was 398 K. The results obtained through experimentation and analysis differ within ±1%. The results of this study will be useful for future hydrogen energy research and hydrogen charging station.