• Title/Summary/Keyword: long period structure

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Structural Changes in Isothermal Crystallization Processes of Synthetic Polymers Studied by Time-Resolved Measurements of Synchrotron-Sourced X-Ray Scatterings and Vibrational Spectra

  • Tashiro, Kohji;Hama, Hisakatsu
    • Macromolecular Research
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    • v.12 no.1
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    • pp.1-10
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    • 2004
  • The structural changes occurring in the isothermal crystallization processes of polyethylene (PE), poly-oxymethylene (POM), and vinylidene fluoridetrifluoroethylene (VDFTrFE) copolymer have been reviewed on the basis of our recent experimental data collected by the time-resolved measurements of synchrotron-sourced wide-angle (WAXS) and small-angle X-ray scatterings (SAXS) and infrared spectra. The temperature jump from the melt to a crystallization temperature could be measured at a cooling rate of 600-1,000 $^{\circ}C$/min, during which we collected the WAXS, SAXS, and infrared spectral data successfully at time intervals of ca. 10 sec. In the case of PE, the infrared spectral data clarified the generation of chain segments of partially disordered trans conformations immediately after the jump. These segments then became transformed into more-regular all-trans-zigzag forms, followed by the formation of an orthorhombic crystal lattice. At this stage, the generation of a stacked lamella structure having an 800-${\AA}$-long period was detected in the SAXS data. This structure was found to transfer successively to a more densely packed lamella structure having a 400-${\AA}$-long period as a result of the secondary crystallization of the amorphous region in-between the original lamellae. As for POM, the formation process of a stacked lamella structure was essentially the same as that mentioned above for PE, as evidenced from the analysis of SAXS and WAXS data. The observation of morphology-sensitive infrared bands revealed the evolution of fully extended helical chains after the generation of lamella having folded chain structures. We speculate that these extended chains exist as taut tie chains passing continuously through the neighboring lamellae. In the isothermal crystallization of VDFTrFE copolymer from the melt, a paraelectric high-temperature phase was detected at first and then it transferred into the ferroelectric low-temperature phase at a later stage. By analyzing the reflection profile of the WAXS data, the structural ordering in the high-temperature phase and the ferroelectric phase transition to the low-temperature phase of the multi-domain structure were traced successfully.

Evaluation of Agricultural Reservoir Behavior by Seismic Shaking Table Test (지진 모형시험을 통한 농업용 저수지 거동 평가)

  • Lim, Seongyoon;Song, Changseob;Kim, Myeonghwan
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.3
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    • pp.55-63
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    • 2015
  • Embankment of agricultural reservoir started by four major rivers project. Most agricultural reservoirs must insure the agricultural water, they need must be ensured stability of embankment. Recently, there is a growing interest in seismic stability of structure by earthquake. Results of evaluation of the structural stability through seismic vibration test and numerical analysis, maximum displacement and the maximum acceleration is a similar trends. Appeared by increasing occurrence of the value of the displacement and acceleration of the structure with the result long period wave type in accordance with the seismic wave in the case of seismic waves, which shows the results of similar tendency as long period wave type consists of waveform seismic acceleration. Model test and numerical analysis results with in order to increase embankment agricultural reservoir, the displacement was found to ensure it is displayed within one percentage structural stability of the embankment.

Effect of A-Zeolite on the Crystallization Behavior of In-situ Polymerized Poly(ethylene terephthalate) (PET) Nanocomposites

  • Shin, Young-Hak;Lee, Wan-Duk;Im, Seung-Soon
    • Macromolecular Research
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    • v.15 no.7
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    • pp.662-670
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    • 2007
  • The crystallization behavior and fine structure of poly(ethylene terephthalate) (PET)/A-zeolite nanocomposites were assessed via differential scanning calorimetry (DSC) and time-resolved small-angle X-ray scattering (TR-SAXS). The Avrami exponent increased from 3.5 to approximately 4.5 with increasing A-zeolite contents, thereby indicating a change in crystal growth formation. The rate constant, k, evidenced an increasing trend with increases in A-zeolite contents. The SAXS data revealed morphological changes occurring during isothermal crystallization. As the zeolite content increased, the long period and amorphous region size also increased. It has been suggested that, since PET molecules passed through the zeolite pores, some of them are rejected into the amorphous region, thereby resulting in increased amorphous region size and increased long period, respectively. In addition, as PET chains piercing into A-zeolite pores cannot precipitate perfect crystal folding, imperfect crystals begin to melt at an earlier temperature, as was revealed by the SAXS profiles obtained during heating. However, the spherulite size was reduced with increasing nanofiller content, because impingement between adjacent spherulites in the nanocomposite occurs earlier than that of homo PET, due to the increase in nucleating sites.

Effect of poorly-compacted backfill around embedded foundations on building seismic response

  • Kim, Yong-Seok
    • Earthquakes and Structures
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    • v.3 no.3_4
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    • pp.549-561
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    • 2012
  • Many building foundations are embedded, however it is not easy to compact the backfill around the foundation especially for the deeply embedded ones. The soil condition around the embedded foundation may affect the seismic response of a building due to the weak contact between the soil and the foundation. In this paper, the response accelerations in the short-period range and at the period of 1 second (in the long-period range) for a seismic design spectrum specified in the IBC design code were compared considering perfect and poor backfills to investigate the effect of backfill compaction around the embedded foundation. An in-house finite-element software (P3DASS) which has the capability of horizontal pseudo-3D seismic analysis with linear soil layers was used to perform the seismic analyses of the structure-soil system with an embedded foundation. Seismic analyses were carried out with 7 bedrock earthquake records provided by the Pacific Earthquake Engineering Research Center (PEER), scaling the peak ground accelerations to 0.1 g. The results indicate that the poor backfill is not detrimental to the seismic response of a building, if the foundation is not embedded deeply in the soft soil. However, it is necessary to perform the seismic analysis for the structure-soil system embedded deeply in the soft soil to check the seismic resonance due to the soft soil layer beneath the foundation, and to compact the backfill as well as possible.

Seismic Responses of Multi-DOF Structures with Shallow Foundation Using Centrifuge Test (원심모형실험을 활용한 얕은 기초가 있는 다자유도 구조물의 지진응답)

  • Kim, Dong Kwan;Kim, Ho Soo;Kim, Jin Woo
    • Journal of the Earthquake Engineering Society of Korea
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    • v.26 no.3
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    • pp.117-125
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    • 2022
  • In this study, centrifuge model tests were performed to evaluate the seismic response of multi-DOF structures with shallow foundations. Also, elastic time history analysis on the fixed-base model was performed and compared with the experimental results. As a result of the centrifuge model test, earthquake amplification at the fundamental vibration frequency of the soil (= 2.44 Hz) affected the third vibration mode frequency (= 2.50 Hz) of the long-period structure and the first vibration mode (= 2.27 Hz) of the short-period structure. The shallow foundation lengthened the periods of the structures by 14-20% compared to the fixed base condition. The response spectrum of acceleration measured at the shallow foundation was smaller than that of free-field motion due to the foundation damping effect. The ultimate moment capacity of the soil-foundation system limited the dynamic responses of the multi-DOF structures. Therefore, the considerations on period lengthening, foundation damping, and ultimate moment capacity of the soil-foundation system might improve the seismic design of the multi-DOF building structures.

A Study on the Temporal Correlation of Long-term Exposure Test and Accelerated Corrosion Test of Rebar (장기폭로 시험과 철근 부식 촉진시험의 시간적 상관성에 관한 연구)

  • Lee, Min-Woo;Park, Sang-Soon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.307-313
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    • 2014
  • Recent interest in the increased structural performance and durability evaluation of this concrete structure in a salt damage environment is increasing. The most secure and reliable method of accelerated corrosion test is a method to carry out the rebar corrosion monitoring can be exposed directly to the marine test site exposure. However, long-term exposure testinghas the disadvantage that a long period is necessary. So, a lot of research on RC of salt damage environment have beenpromoted as alternatives to replace this. However, accelerated corrosion test, in the short term only is appropriate and is but an accelerated test method to evaluate the critical chlorine concentration, there is a difficult problem that you still get the answer. It is one of the correlation problems accelerated test correspond to a certain period of exposure environment. Therefore, in this study, to clarify the differences rebar corrosion beginning, through the actual corrosion accelerated test in corrosion time and laboratory test chamber of the structure of the marine environment results in both environments, it is an object of correlation coefficient derived.

Elastic floor response spectra of nonlinear frame structures subjected to forward-directivity pulses of near-fault records

  • Kanee, Ali Reza Taghavee;Kani, Iradj Mahmood Zadeh;Noorzad, Assadollah
    • Earthquakes and Structures
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    • v.5 no.1
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    • pp.49-65
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    • 2013
  • This article presents the statistical characteristics of elastic floor acceleration spectra that represent the peak response demand of non-structural components attached to a nonlinear supporting frame. For this purpose, a set of stiff and flexible general moment resisting frames with periods of 0.3-3.6 sec. are analyzed using forty-nine near-field strong ground motion records. Peak accelerations are derived for each single degree of freedom non-structural component, supported by the above mentioned frames, through a direct-integration time-history analysis. These accelerations are obtained by Floor Acceleration Response Spectrum (FARS) method. They are statistically analyzed in the next step to achieve a better understanding of their height-wise distributions. The factors that affect FARS values are found in the relevant state of the art. Here, they are summarized to evaluate the amplification and/or reduction of FARS values especially when the supporting structures undergo inelastic behavior. The properties of FARS values are studied in three regions: long-period, fundamental-period and short-period. Maximum elastic acceleration response of non-structural component, mounted on inelastic frames, depends on the following factors: inelasticity intensity and modal periods of supporting structure; natural period, damping ratio and location of non-structural component. The FARS values, corresponded to the modal periods of supporting structure, are strongly reduced beyond elastic domain. However, they could be amplified in the transferring period domain between the mentioned modal periods. In the next step, the amplification and/or reduction of FARS values, caused by inelastic behavior of supporting structure, are calculated. A parameter called the response acceleration reduction factor ($R_{acc}$), has been previously used for far-field earthquakes. The feasibility of extending this parameter for near-field motions is focused here, suggested repeatedly in the relevant sources. The nonlinearity of supporting structure is included in ($R_{acc}$) for better estimation of maximum non-structural component absolute acceleration demand, which is ordinarily neglected in the seismic design provisions.

OKAYAMA ASTROPHYSICAL OBSERVATORY WIDE-FIELD CAMERA

  • YANAGISAWA KENSHI
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.109-112
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    • 2005
  • We present the design, expected performance, and current status of the wide field near-infrared camera (OAOWFC) now being developed at Okayama Astrophysical Observatory, NAOJ, NINS. OAOWFC is a near-infrared survey telescope whose effective aperture is 91cm. It works at Y, J, H, and $K_s$ bands and is dedicated to the survey of long period variable stars in the Galactic plane. The field of view is $0.95 {\times} 0.95 deg^2$ which is covered by one HAWAII-2 RG detector of 2048 ${\times}$ 2048 pixels with the pixel size of $18.5 {\mu}m\;{\times}\;18.5{\mu}m$, that results in the sampling pitch of 1.6 arcsec/pixel. OAOWFC can sweep the area of $840 deg^2$ every 3 weeks, attaining a limiting magnitude of 13 in $K_s$ band. It allows us to observe long period variables embedded in the Galactic plane where interstellar extinction is severe in optical.

Optimization of Thermo-Optic Parameters for Temperature-Insensitive LPWG Refractometers

  • Lee, Dong-Seok;Kim, Kyong-Hon;Hwang, Seok-Hyun;Lee, Min-Hee;Lee, El-Hang
    • ETRI Journal
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    • v.28 no.6
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    • pp.739-744
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    • 2006
  • In this paper, we report numerically calculated results of testing a temperature-insensitive refractive sensor based on a planar-type long-period waveguide grating (LPWG). The LPWG consists of properly chosen polymer materials with an optimized thermo-optic coefficient for the core layer in a four-layer waveguide structure. The resonant wavelength shift below the spectral resolution of the conventional optical spectrum analyzer is obtained accurately over a temperature change of ${\pm}7.5^{\circ}C$ even without any temperature control. The refractive index sensitivity of the proposed grating scheme is about 0.004 per resonant wavelength shift of 0.1 nm for an optimized thermo-optic coefficient.

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A Study On The Construction Methods In PSC Rail Beams (PSC 궤도빔의 가설공법에 대한 검토)

  • Ahn, Yong-Mo
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.1293-1299
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    • 2010
  • Daegu urban railroad line 3 is introduced with straddle-type monorail system within the country at the first time. This system is long line with 24km in total length which has not the results of construction in Korea. The rail beam of monorail bridge to be constructed/ installed in the city is adopted on the basis of the PSC rail beam. It is required to apply the steel rail beam at rapid/ curved line parts or location to be required the long span bridge as passing river and intersection. The composition of span bridge is various and the height of bridge is change with each section and exist the different curve radius due to all section is passes in the city. The rail beam shall be considered the ground conditions and then consider the construction methods. It is analyzed to construction period of PSC rail beam to be linked with period of infrastructure construction and construction of steel rail beam, structure construction of station etc. It is compared to crane construction methods and launching girder as alternative construction methods and propose to upper construction methods which is superior in economic and construction.

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