• Journal of the Korean Ceramic Society
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• v.55 no.4
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• pp.325-336
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• 2018

Perovskite solar cells (PSCs) are a new class of photovoltaic devices, which have attracted significant attention due to their remarkable optoelectrical properties, including high absorption coefficients, high carrier mobilities, long carrier diffusion lengths, tunable bandgaps, low cost, and facile fabrication. PSCs have reached efficiencies of 22.70% and 18.36% on rigid fluorine-doped tin oxide and poly(ethylene terephthalate) substrates, respectively; these are comparable to those of single-crystal silicon and copper-indium-gallium-selenium solar cells. Over the past eight years, the photo conversion efficiency of PSCs has been significantly improved by device-architecture adjustments, and absorber and electron/hole transport layer optimization. Each layer is important for the performance of PSCs; hence, we discuss achievements in flexible perovskite solar cells (FPSCs), covering electron/hole-transport materials, electrode materials. We give a comprehensive overview of FPSCs and put forward suggestions for their further development.

• Ceramist
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• v.21 no.1
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• pp.98-111
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• 2018

The lead-based perovskite (CH3NH3PbI3) material has a high molar coefficient, high crystallinity at low temperature, and long range of balanced electron-hole transport length. In addition, PCE of perovskite solar cells (PSCs) has been dramatically improved by over 22% by amending the electronic quality of perovskite and by using state-of-the-art hole transporting materials (HTMs) such as tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD) due to enhanced charge transport toward the electrode via properly aligned energy levels with respect to the perovskite. Replacing the spiro-OMeTAD with new HTMs with the desired properties of appropriate energy levels, high hole mobility in its pristine form, low cost, and easy processable materials is necessary for attaining highly efficient and stable PSCs, which are anticipated to be truly compatible for practical application. Furthermore, Recently Pb-free perovskite materials much attention as an alternative light-harvesting active layer material instead of lead based perovskite in photovoltaic cells. In this work, we demonstrate a Pb-free perovskite material for the light harvesting and emitter as optoelectronic devices.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.5
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• pp.468-473
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• 2008

A MgO layer is used as electrode protective film in the alternating current plasma display panel (AC PDP). The properties of MgO layer are thought to be one of the most important factors that affects the panel reliability through the firing voltage variation. In this study, we investigated the relations between the surface characteristics and e-beam evaporation process parameters such as deposition rate, temperature of substrate and distance between the MgO pellet and substrate. To produce the MgO layer of (200) crystal orientation, we suggest the high temperature of the substrate, the long distance between the pellet and substrate and the high deposition rate.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.775-778
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• 2000

In this paper, the life-time of macro interface between Epoxy/EPDM which consists in underground power cable joints is predicted. The electrode system of specimen is designed by FEM(finite elements method). The breakdown strength of specimens are observed by applying high AC voltage at the room temperature. The breakdown times under the constant voltage below the breakdown voltage were gained. As constant voltage is applied, the breakdown time is proportion to the breakdown strength. The life exponent n is gained by inverse power law, and the long breakdown life time can be evaluated.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.11a
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• pp.85-88
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• 1999

대용량 발전 시설의 개발을 목표로, 연구에 대한 많은 관심이 집중되어 온 인산형 연료전지는 이미 전 세계적으로 연구의 선두에 있는 국가들에서 수백 KW급 규모로 상용화단계에 진입해 있는 상태이고 미국 등지에서는 전력회사 등을 통하여 MW급 규모의 응용이 이루어지고 있다. 다른 연료전지에서와 마찬가지로 인산형 연료전지에서도 산소의 환원반응이 느린 점과 산소의 환원시 높은 과전압으로 인한 성능이 감소가 한계요인으로 되고 있어 이의 극복을 위한 많은 연구가 있어 왔으며 최근의 개발 방향은 발전시스템의 고성능화와 전지의 수명연장, 그리고 경제성 확보 등의 측면에서 이루어지고 있다.(중략)

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.146-152
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• 2018

Due to their excellent mechanical durability and high electrical conductivity, carbon and silicon composites are potentially suitable anode materials for Li-ion batteries with high capacity and long lifespan. Nevertheless, the limitations of the composites include their poor ionic diffusion at high current densities during cycling, which leads to low ultrafast performance. In the present study, seeking to improve the ionic diffusion using hydrothermal method, electrospinning, and carbonization, we demonstrate the unique design of excavated carbon and silicon composites (EC/Si). The outstanding energy storage performance of EC/Si electrode provides a discharge specific capacity, impressive rate performance, and ultrafast cycling stability.

• Journal of the Semiconductor & Display Technology
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• v.18 no.4
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• pp.124-128
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• 2019

In this paper, a high temperature plastic film type water level sensor was developed. The high temperature film type water level sensor was manufactured by attaching a copper film to a polyimide film which can be used for a long time at 250℃, by laminating process and patterning the electrode by etching process. For the performance evaluation of the developed film type water level sensor, the temperature dependence of the capacitance was measured, and the deformation was examined after standing for 8 hours in 150℃ air. The developed film type water level sensor can be used at up to 150℃, and can be applied to electric ports and steam devices.

• Journal of the Korean Applied Science and Technology
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• v.36 no.1
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• pp.269-278
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• 2019

We fabricated glucose oxidase (GOx)-modified biosensor for detection of glucose by physical immobilization of GOx after electrochemical polymerization of the conductive mixture monomers of the 3-thiophenecarboxylic acid (TCA) and thiophene (Th) onto ITO electrode in this study. We confirmed the successfully fabrication of GOx-modified biosensor via FT-IR spectroscopy, SEM, contact angle, and cyclic voltammetry. The fabricated biosensor has the detection limit of $0.1{\mu}M$, the linearity of 0.001-27 mM, and sensitivity of $38.75mAM^{-1}cm^{-2}$, respectively. The fabricated biosensor exhibits high interference effects to dopamine, ascorbic acid, and L-cysteine, respectively. From these results, the fabricated GOx-modified biosensor with long linearity and high sensitivity could be used as glucose sensor in human blood sample.

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.226-240
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• 2023

This paper provides an overview of the trends and future directions in the development of anode materials for solid oxide fuel cells (SOFCs) using hydrocarbons as fuel, with the aim of enabling a decentralized energy supply. Hydrocarbons (such as natural gas and biogas) offer promising alternatives to traditional energy sources, as their use in SOFCs can help meet the growing demands for energy. We cover several types of materials, including perovskite structures, high-entropy alloys, proton-conducting ceramic materials, anode on-cell catalyst reforming layers, and anode functional layers. In addition, we review the performance and long-term stability of cells based on these anode materials and assess their potential for commercial manufacturing processes. Finally, we present a model for enhancing the applicability of fuel cell-based power generation systems to assist in the realization of the H₂ economy as the best practice for enabling distributed energy. Overall, this study highlights the potential of SOFCs to make significant progress toward a sustainable and efficient energy future.

• Journal of the Microelectronics and Packaging Society
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• v.28 no.3
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• pp.17-24
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• 2021

Perovskite solar cells (PSCs) can be fabricated through solution process economically with variable bandgap that is controlled by composition of precursor solution. Tandem cells in which PSCs combined with silicon solar cells have potential to reach high power conversion efficiency over 30%, however, lack of long-term stability of PSCs is an obstacle to commercialization. Degradation of PSCs is mainly attributed to the mass transport of halide and metal electrode materials. In order to ensure the long-term stability, the mass transport should be inhibited. In this study, we confirmed degradation behaviors due to the mass transport in PSCs and designed buffer layers with LiF and/or SnO₂ to improve the long-term stability by suppressing the mass transport. Under high-temperature storage test at 85℃, PSCs without the buffer layers were degraded by forming PbI₂, AgI, and the delta phase of the perovskite material, while PSCs with the buffer layers showed improved stability with keeping the original phase of the perovskite. When the LiF buffer and encapsulation were applied to PSCs, superior long-term stability on 85℃-85% RH dump heat test was achieved; efficiency drop was not observed after 200 h. It was also confirmed that 90.6% of the initial efficiency was maintained after 200 hours of maximum power tracking test under AM 1.5G-1SUN illumination. Here, we have demonstrated that the buffer layer is essential to achieve long-term stability of PSCs.