• Journal of Sensor Science and Technology
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• v.23 no.1
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• pp.42-45
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• 2014

Recently, tremendous application utilizing electrospun nanofibers have been actively reported due to its several advantages, such as high surface to volume ratio, simple fabrication and high-throughput manufacturing. In this paper, we developed highly sensitive and consistent nanofiber humidity sensor by electrospinning. The humidity sensor was fabricated by rapid electrospinning (~2 sec) $TiO_2$/PVP/LiCl mixed solution on the micro-interdigitated electrode. In order to evaluate the humidity sensing performances, we measured current response using DC bias voltage under various relative humidity levels. The results show fast response / recovery time and marginal hysteresis as well as long-term stability. In addition, with the aid of micro-interdigitated electrode, we can reduce a total resistance of the sensor and increase the total reaction area of nanofibers across the electrodes resulting in high sensitivity and enhanced current level. Therefore, we expect that the electrospun nanofiber array for humidity sensor can be feasible and promising for diverse humidity sensing application.

• Journal of radiological science and technology
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• v.9 no.1
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• pp.73-81
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• 1986

This paper carried out an experiment on the characteristics of time, temperature, electric field and the dependense of electrode materials and gap length by the conduction current of the insulating oil used for x-ray tube housing. The obtained results can be summarized as following: 1. In the x-ray tube housing insulating oil with vacuum condition, conduction current is declined more than the x-ray tube housing insultaing oil with the air, and is held stable states. 2. At the low electric field the higher temperature of the x-ray tube housing insulating oil is increased, the more conduction current. 3. The dependence of electrode material is appeared at the low electric field and the short gap length than the high and the long with Fe> Cu >Al. 4. At the I-E characteristics, the low electric field than 1000 [V/cm] is appeared Ohm's law region, and the high become saturation region. 5. At the same electric field, the longer gap length become, the more conduction current is increased, and the same applied voltage, the longer, the less conduction current is decreased, the less low than high temperature x-ray tube housing insulating oil.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.90-90
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• 2012

The electron/hole injections in organic electronic devices have long been an issue due to the large energy level mismatches between electrode and organic layer. To utilize the organic materials in electronic devices, functional thin layers have been used, which reduce the electron/hole injection barrier from electrode to organic material. Typically, inorganic compounds and organic molecules are used as an electron and hole injection layer, respectively. Recently, CsN3 and 1,4,5,8,- naphthalene-tetracarboxylic-dianhydride (NTCDA) are reported as a potential electron and hole injection layers. CsN3 shows unique properties that it breaks into Cs and N and thus Cs can dope organic layer into n-type. On the other side, hole injection anode, NTCDA forms gap states with anode material. In this presentation, we show the electronic structure changes upon the insertion of CsN3 and NTCDA at proper interfaces to reduce the charge injection barriers. These barrier reductions are correlated with device characteristics.

• Analytical Science and Technology
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• v.8 no.4
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• pp.723-730
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• 1995

Cyclic voltammetry and in situ STM were employed to examine the interfacial structures of a Pt(111) electrode in 0.1 mM KCN (pH9.5) and 0.1 mM KSCN (pH7) solutions. In situ STM atomic resolution revealed well ordered (2${\surd}$3${\times}$2${\surd}$3)$R30^{\circ}$-6CN and ($2{\times}2$)-2SCN structures within the double layer charging region. Six CN adsorbates formed a hollow hexagon, which embraced a coadsorbed $K^+$ cation. In contrast, the coadsorbed $K^+$ cations on the SCN covered Pt(111) were poorly ordered, despite adsorbed SCN formed a long range ordered ($2{\times}2$)-2SCN adlattice. In situ STM revealed the pronounced influence of potential in controlling the structures of compact layers at the proximity of a Pt electrode. Cathodic polarization facilitated the replacement of the coadsorbed cations by protons.

• Journal of Welding and Joining
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• v.16 no.4
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• pp.125-135
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• 1998

The shielded metal arc welding (SMAW) by AC power source was performed to evaluate the arc stability by arc monitoring and analysing. In this study, the arc stability index was evaluated quantitatively by using he coefficient of resistance variation for welding time. This coefficient was obtained for the long time (20sec.) by analysing the waveforms of welding current, voltage and resistance. The coefficient was applied to indicate numerically the variation level of arc length and the degree of arc extinction. Using the coefficient of resistance variation in practical welding, the arc stability of the high titanium oxide electrode (KS E4313) turned out to be better than that of the low hydrogen electrode (KS E4316). In evaluating the skill level of welders by the coefficient, the horizontal fillet weaving welding became clear to be very discriminating because the higher level welder could weave in keeping constant arc length, but the lower level welder showed the characteristics of weaving with the unstable arc length. And it was confirmed that the welding defects as blow holes was formed when the arc stability index were high.

• Journal of the Korean Chemical Society
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• v.36 no.1
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• pp.75-80
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• 1992

The electrochemical spectral sensitization of a $SnO_2$ electrode with eosin B, a Xanthene dye, has been studied in acetonitrile. Measurements of the photocurrent have been carried out in the presence of supersensitizers such as thiourea, 1-allyl-2-thiourea, NaSCN, and NaI. The magnitude of the supersensitized photocurrent was greater than that of the sensitized photocurrent for all of the supersensitizers studied. However, the long time span of irradiation causes a significant decrease of the supersensitized photocurrent as well as the absorbance. These results, together with infrared spectra and fluorescence spectra, are taken into account to elucidate the mechanism of photoreaction between eosin B and supersensitizers in acetonitrile.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.601-604
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• 2014

Two classes of morpholino-substitued thioacetate have been successfully synthesized and their electrochemical properties of self-assembled monolayers (SAMs) on Au electrode are measured by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The barrier property of the SAMs-modified surfaces is evaluated by using potassium ferro/ferri cyanide. The results suggest that the arenethioacetate forms higher-quality close-packed blocking monolayers in comparison with alkanethioacetate. Furthermore, it has shown that the barrier properties of these monolayers can be significantly improved by mixed SAMs formation with decanethiol. From our experimental results we find that the electron transfer reaction of $[Fe(CN)_6]^{3/4-}$ redox couple occurs predominantly through the pinholes and defects present in the SAM and both SAMs show a good and fast capacity in recognition for $Ag^+$. The morphological and elementary composition have also been examined by scanning electron microscope (SEM) and energy dispersive spectrometer (EDS).

• Polymer(Korea)
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• v.31 no.3
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• pp.255-262
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• 2007

In this work, two types of copolymers are manufactured by a radical polymerization to develop a material for humid membrane. Each copolymer contains three monomers that have functions to improve humid-resistance, membrane stability, flexibility, impedance, and adhesion to the electrode. MDBAB (N,N'-dimethyl-2-methacryloxyethyl-3-bromopropyl ammonium bromide) having a salt form decreases the impedance of the humid membrane and reacts with amines to produce a cross-linking structure. HEMA (2-hydroxyethyl methacrylate) has an important role which reduces the impedance and increases the adhesion strength to the electrode. The other monomers are DAEMA (N,N'-dimethylamino ethyl methacrylate), 4-VP(4-vinyl pyridine), and 2-EHA(2-ethylhexyl acrylate) and all the monomers are formulated with several compositions to make a humid membrane. At specific composition, we could attain a satisfactory results having good performance and long term durability.

• Applied Science and Convergence Technology
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• v.25 no.6
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• pp.138-144
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• 2016

The discharge characteristics of pulse-driven coplanar micro barrier discharges for an ultraviolet (UV) light source using Ne-Xe mixture have been investigated using a two-dimensional fluid simulation at near-atmospheric pressure. The densities of electrons, the radiative excited states, the metastable excited states, and the power loss are investigated with the variations of gas pressure and the gap distance. With a fixed gap distance, the number of the radiative states $Xe^*(^3P_1)$ increases with the increasing driving voltage, but this number shows weak dependency on the gas when that pressure is over 400 Torr. However, the number of the radiative states increases with the increase of the gap distance at a fixed voltage, while the power loss decreases. Therefore, a long gap discharge has higher efficiency for UV generation than does a short gap discharge. A slight change in the electrode tilt angle enhances the number of radiative species 2 or 3 times with the same operation conditions. Therefore, the intensity and efficiency of the UV light source can be controlled independently by changing the gap distance and the electrode structure.

• Journal of Electrochemical Science and Technology
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• v.8 no.1
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• pp.53-60
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• 2017

Fluoroethylene carbonate (FEC) was studied as an additive for the electrolyte in lithium ion batteries with the $LiNi_{0.5}Mn_{1.5}O_4$ (LNMO) spinel cathode operating at a high potential beyond 4.7 V (vs. $Li/Li^+$). It was found that the FEC additive was electrochemically active for the $1^{st}$ charge cycle on the LNMO cathode. The presence of a large amount of FEC (more than 40 vol%) in the electrolyte caused severe side reactions with abnormally long voltage plateaus. In contrast, when the electrolyte contained less than 30 vol% FEC, the surface of the LNMO cathode was stabilized by the formation of the solid-electrolyte interphase (SEI), leading to improved cyclability. However, the resistance from the SEI limited the rate capability because of sluggish lithium transportation through the SEI and electronic insulation between the particles in the electrode.