• Title/Summary/Keyword: lithium metal

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Charge/Discharge Characteristics of Lithium ion Secondary Battery Using Ag-deposited Graphite as Anode Active Material (은 담지한 흑연을 부극 활물질로 이용한 Lithium ion 2차전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.727-732
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    • 1998
  • Ag-deposited graphite powder was prepared by a chemical reduction method of metal particles onto graphite powder. X-ray diffraction observation of Ag-deposited graphite powder revealed that silver existed in a metallic state, but not in an oxidized one. From SEM measurement, ultrafine silver particles were highly dispersed on the surface of graphite particles. Cylindrical lithium ion secondary battery was manufactured using Ag-deposited graphite anodes and $LiCoO_2$ cathodes. The cycleability of lithium ion secondary battery using Ag-deposited graphite anodes was superior to that of original graphite powder. The improved cycleability may be due to both the reduction of electric resistance between electrodes and the highly durable Ag-graphite anode.

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Electrochemical Properties of Lithium Batteries with Nickel Sulfide by Ammonium Polysulfide (다황화암모늄에 의해 제조된 황화니켈을 이용한 리튬전지의 전기 화학적 특성 평가)

  • RYU, HO SUK
    • Journal of Hydrogen and New Energy
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    • v.32 no.6
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    • pp.612-617
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    • 2021
  • In the case of a metal sulfide electrode, it is used as an anode or cathode active material in a lithium battery. The reason is that the voltage exists between 0.8 and 2.0 V via lithium electrode and the discharge and charge capacity is high. In order to manufacture nickel sulfide for electrode, which are widely used, nano-nickel powder was sulfided using ammonium polysulfide, and single-phase NiS electrodes were manufactured through heat treatment. The prepared NiS electrode had a high initial capacity of 500 mAh/g or more, and was stabilized after 20 cycles to maintain a capacity of 400 mAh/g or more until 100 cycles.

A Study on the Mg-doped LAS Ceramics Using Metal Alkoxide (금속 알콕사이드를 이용한 Mg-doped LAS계 내열세라믹스의 제조 및 소결에 관한 연구)

  • 김영배;김형태;이응상
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.45-50
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    • 1995
  • In order to densify LAS(Lithuim Aluminosilicate)system compounds, we used metal alkoxides as precursors. Also Mg was added by sol-gel method using metal alkoxides to the LAS system for improving the sinterability, thermal and mechanical properties. The result was that the synthesizing temperature was lowered about 10$0^{\circ}C$, the sintering temperature was lowered by over 10$0^{\circ}C$ and MOR of samples from metal alkoxides was two times larger than that of sample form oxide.

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A Modified Process for the Separation of Fe(III) and Cu(II) from the Sulfuric Acid Leaching Solution of Metallic Alloys of Reduction Smelted Spent Lithium-ion Batteries (폐리튬이온전지의 용융환원된 금속합금상의 황산침출액에서 철(III)과 구리(II)의 분리를 위한 공정 개선)

  • Nguyen, Thi Thu Huong;Tran, Thanh Tuan;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.1
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    • pp.12-20
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    • 2022
  • The smelting reduction of spent lithium-ion batteries results in metallic alloys containing Co, Cu, Fe, Mn, Ni, and Si. A process to separate metal ions from the sulfuric acid leaching solution of these metallic alloys has been reported. In this process, ionic liquids are employed to separate Fe(III) and Cu(II). In this study, D2EHPA and Cyanex 301 were employed to replace these ionic liquids. Fe(III) and Cu(II) from the sulfate solution were sequentially extracted using 0.5 M D2EHPA with three stages of cross-current and 0.3 M Cyanex 301. The stripping of Fe(III) and Cu(II) from the loaded phases was performed using 50% (v/v) and 60% (v/v) aqua regia solutions, respectively. The mass balance results from this process indicated that the recovery and purity percentages of the metals were greater than 99%.

Fabrication and Electrochemical Characterization of All Solid State Thin Film Micro-Battery by in-situ sputtering (In-situ 스퍼터링을 이용한 마이크로 박막 전지의 제작 및 전지 특성 평가)

  • 전은정;신영화;남상철;조원일;손봉희;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.159-162
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    • 1999
  • All solid state thin film micro-batteries consisting of lithium metal anode, an amorphous LiPON electrolyte and cathode of vanadium oxide have been fabricated and characterized, which were fabricated with cell structure of Li/LiPON/V$_2$O$\sub$5/Pt. The vanadium oxide thin films were formed by d.c. reactive sputtering on Pt current collector. After deposition of vanadium oxide films, in-situ growths of lithium phosphorus oxynitride film were conducted by r.f. sputtering of Li$_3$PO$_4$ target in mixture gas of N$_2$ and O$_2$. The pure metal lithium film was deposited by thermal evaporation on thin film LiPON electrolyte. The cell capacity was about 45${\mu}$Ah/$\textrm{cm}^2$ $\mu\textrm{m}$ after 200 cycle. No appreciable degradation of the cell capacity could be observed after 50 cycles .

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