• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 1997년도 International Symposium on Fire Science and Technology
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• pp.104-111
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• 1997

Cluster systems are microcrystals of vanadiumoxided compounds such as Barium, Calcium or Sodium Metavanadates or Sodium Vanadium Bronze which are distributed into dimethyl- or diethylphosphites or microcrystals of vanadium oxides, for instance, vanadium oxide (+3), distributed into the methylphosphonic acid melted. During the interaction of vanadium compounds with the correspondent phosphororganic substances biue viscous liquids are formed. These liquids have paramagnetic properties. According to the UV and IR spectroscopic investigations as well as the results of EPR spectra the substances obtained consist of the nucleus containing 6 to 12 of vanadium atoms and the shell including ligands which are molecules of phosphites or methylphosphonic acid. Here every atom of vanadium interacts with four of phosphorus containing molecules. Sizes of the particles in these systems donot exceed 200 nm. Introduction of cluster systems (0,1 -0,3 % vanadium) into epoxy compositions before the introduction of curing agent - polyethylenepolyamine 6 -8 % leads to the acceleration of composition crosslinking and to the combustion decreasing: 1) Oxygen Index grows to 35: 2)mass losses during combustion decrease to 1-2%, 3) combustion time does not exceed 1 s; 4) the intumescence of material sample is being observed during the burner action as well as the foam coke formation.

• 대한화학회지
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• 제11권3호
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• pp.105-110
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• 1967

액체구조의 천이상태이론을 아산화질소($N_2O$)와 사산화질소($N_2O_4$)에 적용하여 이 액체들의 상태합을 유도하였다. 이상태합들을 써서 각 액체의 몰부피, 증기압, 증발엔트로피, 임계점에서의 성질 등, 여러가지 열역학적양들을 계산한 결과 모두 실험치와 좋은 일치를 얻었다.

• 대한금속재료학회지
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• 제50권2호
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• pp.122-128
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• 2012

Water model experiments were carried out to understand the mixing behavior of reducing agents in molten slag through vortex stirrer, which makes use of a gravitational energy to mix reducing agent in the molten slag without imparting artificial energy. At a water flow rate of 6 L/min vortex was not generated, and a stable vortex was formed when the water flow rate was 7 L/min or higher with the present experimental apparatus. Water level increased linearly with increasing the water flow rate. In the upper vortex region, the vertical and horizontal velocities slightly decreased with increasing the water flow rate, whereas those in the lower vortex region increased remarkably. Accordingly, strong mixing behavior was obtained in the lower vortex region. Owing to the strong centrifugal force, particles move downwards with approaching the funnel wall. When 40 grams of polypropylene particles added to the lower vortex, they were instantaneously mixed well.

• 공업화학
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• 제27권4호
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• pp.439-443
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• 2016

본 연구에서는 $MnO_2$ 나노입자들이 기능화된 그래핀에 증착된 나노복합체를 제조하고 이의 우수한 전기화학적 특성을 순환전압전류법, 정전류 충전-방전법 및 임피던스 분석을 통하여 증명하였다. 환원된 그래핀 산화물의 표면 개질을 위하여 이온성 액체를 도입함으로써, 그래핀 시트들 간의 뭉침현상을 제어하고 $MnO_2$ 나노입자들의 성장부위를 제공하였다. 상기 제조된 $MnO_2/RGO$ 나노복합체는 전자주사현미경, 투과전자현미경, X선 광전자 분광기, X선 회절기를 사용하여 분석하였다. $MnO_2/RGO$ 전극의 전기화학적 특성은 $Na_2SO_4$ 전해액을 사용하여 3상 전극 시스템 하에서 분석실시하였다. $MnO_2/RGO$ 전극은 높은 비정전용량(251 F/g), 고속 충방전(80.5% 용량 유지율) 및 장수명 특성(93.6% 용량 유지율)을 나타내었다.