• Title/Summary/Keyword: liquid-phase

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Process Analysis for Rheology Forming Considering Flow and Solidification Phenomena in Lower Solid Fraction (저고상율 소재의 유동 및 응고현상을 고려한 레올로지 성형공정해석)

  • Jung, Young-Jin;Cho, Ho-Sang;Kang, Chung-Gil
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.9
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    • pp.156-164
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    • 2001
  • Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum alloy has been studied. Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The proposed mathematical model is applied to the die shape of the two types. To calculate the velocity and temperature fields during rheology forming process, the earth governing equation correspondent to the liquid and solid region are adapted. Therefore, each numerical models considering the solid and liquid region existing within the semi-solid material have been developed to predict the deflect of rheology forming gnarls. The Arbitrary Boundary Maker And Cell (ABMAC) method is employed to solve the two-phase flow model of the Navier-Stokes equation. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity. The liquid viscosity is pure liquid state value, however solid viscosity is considered as a function of the shear rate, solid fraction and power law curves.

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Changes in Physical Properties Especially, Three Phases, Bulk Density, Porosity and Correlations under No-tillage Clay Loam Soil with Ridge Cultivation of Rain Proof Plastic House

  • Yang, Seung-Koo;Seo, Youn-Won;Kim, Sun-Kook;Kim, Byeong-Ho;Kim, Hee-Kwon;Kim, Hyun-Woo;Choi, Kyung-Ju;Han, Yeon Soo;Jung, Woo-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.4
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    • pp.225-234
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    • 2014
  • This study was carried out to investigate the sustainable agriculture of no-tillage technique including recycling of the ridge and the furrow of a field for following crops in Korea. No-tillage systems affect soil physical properties such as three phase (solid, liquid, and air phase) and distribution of soil granular. Solid ratio of subsoil in 3-year of no-tillage (NT) treatment was remarkably lower than that in conventional (CT, 2-year of no-tillage + 1-year of tillage) treatment, while air ratio of subsoil in NT remarkably increased. Bulk density of subsoil in NT remarkably decreased. Porosity of subsoil in NT remarkably increased. Deviation of air phase, bulk density, and porosity of top soil and subsoil in NT remarkably decreased in NT compared with CT. Solid phase ratio and liquid phase ratio in NT and CT had positive (+) correlation. Solid phase ratio and air phase ratio in NT and CT had negative (-) correlation, also liquid phase ratio and air ratio had negative (-) correlation. Bulk density and liquid ratio in soil had positive (+) correlation at top soil and subsoil in NT. Bulk density and air ratio in soil had negative (-) correlation in NT and CT. Porosity and liquid phase ratio had negative (-) correlation, r =1), the significant value was lower in NT than in CT. Porosity and air phase ratio had positive (+) correlation (r =1).

The Effect of Layer Spacing Changes in the SmA Phase on Defects Observed in SSFLC Devices.

  • Wang, Chenhui;Bos, Philip J.;Kumar, Satyendra;Wand, Michael;Handschy, Mark
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.193-197
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    • 2004
  • The effect of the temperature dependence of the smectic layer spacing in the smectic-A (SmA) phase on the formation of defects in the ferroelectric smectic-$C^{\ast}$ ($SmC^{\ast}$) phase is investigated with x-ray scattering technique. The study is based on thin parallel-aligned surface stabilized ferroelectric liquid crystal cells with two different alignment conditions, high pretilt $SiO_x$, alignment and low pretilt polyimide films. It is found that defects observed in the $SmC^{\ast}$ phase have much more profound dependence on the layer changes and chevron formation in the SmA phase than in the $SmC^{\ast}$ phase. We find that thermal layer expansion with decreasing temperature in the SmA phase suppresses the formation of defects observed in the SmC phase.

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Investigations of the Phase Behavior of N-dodecanocyl-N-methyl amido polyol carboxyl alkyl ether/N-dodecanocyl-N-alkyl Glucamine/Water System (N-도데카노실-N-메틸 아미도 폴리올 카르복시 알킬 에테르/(N-도데카노실-N-알킬 글루카민)/물계에서의 상거동 관찰)

  • Kang, Yun-Seog;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.23-28
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    • 1997
  • The phase diagram for the surfactant mixture system of N-dodecanocyl-N-methyl amido polyolcarboxyl alkyl ether(DGC)/N-dodecanocyl-N-alkyl glucamine(DG)/water was studied usingpolarized microscopy, differential scanning calorimetry(DSC) and rheological measurements respectively. Using polarized microscopy, the textures of liquid crystal phases obtained at various surfactantconcentrations were investigated as a function of surfactant concentration and temperature, and phasetransitions between anisotropic liquid crystal phases and isotropic liquid phase were examined usingDSC measurements. Viscoelastic properties of surfactant solutions determined between hexagonal andlamellar liquid crystal phase by rheological measurements were approximately consistent with the resultsobtained by polarized microscopy and DSC. In the study for the phase of DGC/DG(5:5 mol ratio)/water system. It could be found that the hexagonal liquid crystal phase appeared at 25${\sim}$60wt% ofsurfactant, the cubic liquid crystal phase at 50${\sim}$65wt% and the lamellar crystal phase at above 70wt%.

Alternative chromatographic method for the assay test of terbutaline and salbutamol using ionic liquid assisted aqueous mobile phase

  • Mai, Xuan-Lan;Choi, Yusung;Truong, Quoc-Ky;Nguyen, Thi-Ngoc-Van;Han, Sang Beom;Kim, Kyeong Ho
    • Analytical Science and Technology
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    • v.33 no.4
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    • pp.169-176
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    • 2020
  • Separation of basic compounds using reverse phase chromatography on a silica-based stationary phase represents a major challenge, because of the interaction between the cationic sites of the basic compounds with the anionic silanols of the stationary phase. This study presents a simple, reliable, and organic solvent - free liquid chromatographic method for the determination of terbutaline and salbutamol, in which a room temperature ionic liquid (RTIL) is used as mobile phase additive. We investigated various mobile phase parameters affecting the retention of the two compounds, such as types and concentration of RTILs and, pH of the mobile phase were investigated. The developed method was validated according to International Conference on Harmonization (ICH) guidelines and successfully applied effectively to determine salbutamol sulfate in pharmaceutical preparations.

Novel Phase States in Highly Charged Colloidal Suspensions

  • Terada Y.;Muramoto K.;Tokuyama M.
    • 한국전산유체공학회:학술대회논문집
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    • 2003.10a
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    • pp.19-20
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    • 2003
  • Brownian-dynamics simulation on highly charged colloidal suspensions is performed by employing Tokuyama effective force recently proposed. The radial distribution function suggests that there exist three novel phases, a gas phase, a liquid droplet phase, and a face-centered cubic (FCC) crystal droplet phase, depending on the minimum values of that potential. The dynamics of droplet growth is also investigated both in liquid droplet phase and in crystal droplet phase. Thus, different types of characteristic growth stages are found.

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Enhancement of Pulsed-Laser Ablation by Phase Explosion of Liquid (액체의 상폭발 과정에 의한 펄스 레이저 용발률의 증진)

  • Kim, Dong-Sik;Lee, Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.11
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    • pp.1483-1491
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    • 2001
  • Enhancement of pulsed-laser ablation by an artificially deposited liquid film is presented. Measurements of ablation rate, ablation threshold, and surface topography arc performed. Correlation between material ablation and photoacoustic effect is examined by the optical beam deflection method. The dependence of ablation rate on liquid-film thickness and chemical composition is also examined. The results indicate that photomechanical effect in the phase explosion of liquid is responsible for the enhanced ablation. The low critical temperature of liquid induces explosive vaporization with localized photoacoustic excitation in the superheat limit and increases the ablation efficiency. Experiments were carried out utilizing a Q-swiched Nd:YAG laser at near-threshold laser fluences with negligible plasma effect (up to ∼100 MW/cm$^2$).

Pore Filling Theory of Liquid Phase Sintering and Microstrcture Evolution (액상소결의 기공채움 이론과 미세구조 발달)

  • 이성민
    • Journal of Powder Materials
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    • v.6 no.1
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    • pp.81-87
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    • 1999
  • Based on the pore filling theory, the microstructure evolution during liquid-phase sintering has been analyzed in terms of interrelationship between average grain size and relative density. For constant liquid volume fraction, the microsturucture trajectories reduced to a single curve in a grain size(x)-density(y) map, regardless of grain growth constant. The slope of curves in the map was inversely proportional to average pore size, while it increased fapidly with liquid volume fraction. Increase in pore volume fraction retarded the densification considerably, but showed marginal effect on the slope. The activation energy of densification was predicted to be the same as that of grain growth as long as the liquid volume fraction is constant for any temperature range studied. The present analyses on microstricture evolution may demonstrate the usefulness of pore filling theory and provide a guideline for process optimization of liquid-phase sintering.

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Flow Characteristics of Vertical Upward Gas-Liquid Two-Phase Flow (수직상향 기액이상류의 유동특성)

  • Choi Bu-Hong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.4
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    • pp.377-383
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    • 2005
  • This paper deals with the flow characteristics of air-water two-phase flow in a vertical tube of 10mm I.D. and 600mm in length at an adiabatic condition. The obtained experimental data were covered with the liquid superficial velocity ranging from 0.095m/s to 2.56m/s. and the gas superficial velocity ranging from 0.032m/s to 21.08m/s. The effects of the gas and liquid superficial velocity on the flow pattern transitions, frictional pressure drop, and film thickness and gas-liquid interface roughness were also examined. It was found that the film thickness increased and the liquid film wave length was more longer with the liquid superficial velocity $j_L$ increasing at $j_G$ constant. It was also showed that the frictional pressure drops were experienced in three regions. namely increasing region(bubbly flow), decreasing region (Taylor bubble and slug flows) and re-increasing region (annular flow).

Dissolution and Reprecipitation Behavior of TiC-TiN-Ni Cermets During Liquid-Phase Sintering

  • Yoon, Choul-Soo;Shinhoo Kang;Kim, Doh-Yeon
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.124-128
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    • 1997
  • An attempt was made to understand the dissolution and reprecipitation behavior of the constituent phases such as TiC, TiN, and Ti(CN) in TiC-TiN-Ni system. During the liquid-phase sintering the TiC phase was found to dissolve preferentially in Ni binder. The solid-solution phase, Ti(CN), formed around the TiN phase, resulting in a core/rim structure. This result was reproduced when large TiC particles were used with fine TiN particles. The path for the microstructural change in TiC-TiN-Ni system was largely controlled by the difference in the interfacial energy of each phase with the liquid binder phase. The results were discussed with thermodynamic principles.

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