• 제목/요약/키워드: liquid-phase

검색결과 4,291건 처리시간 0.039초

LPG 액상분무의 분열 및 혼합특성 (Characterization of Liquid Phase LPG Sprays within Airflow Fields)

  • 최재준;최동석;남창호;배충식
    • 한국자동차공학회논문집
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    • 제10권5호
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    • pp.90-97
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    • 2002
  • The interaction between airflow and liquid phase LfG (Liquefied Petroleum Gas) sprays was investigated in a steady flow system embodied in a wind tunnel to simulate the variety of flow inside intake port of LPG engines with liquid injection system. The spray developments in flowing fields with the mean velocities of 5.4, 21.5 and 42.4m/s were identified by spray visualization techniques such as Mie scattering and shadowgraph. The microscopic visualization using a telescopic lens system was performed to investigate the shape and size of liquid droplets in the spray. PDA measurement was used to get 1-dimensional velocity and diameter of liquid droplets. The fast co-flows make the spray field be compact and be lead upward to the injection direction. SMD of the spray was smaller at the fast flowing field. Spray width got bigger and SMD of the spray was smaller with higher injection pressure.

산업폐수중 유화액막에 의한 크롬(VI)의 분리 (Separation of Chromium(VI) Ion in Industrial Waste Water throunh Liquid Surfactant Membrane)

  • 초민승;강안수;우인성;이영순
    • 한국안전학회지
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    • 제4권1호
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    • pp.15-24
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    • 1989
  • The transport of Chromium(Vl) ion from waste water throughl the liquid surfactant membrane containing tri-n-octylamine as a carrier, was analyzed by a slab model and was investigated through experiments. For the experiment of membrane stability, concentrations of surfactant and liquid parafnn oil were analyzed. Extraction euperiments were carried out to observe the effect of system variables, such as stirring speed, concentration of carrier, and NaOH in internal aqueous phase, and concentrations of H$_2$SO$_4$and initial chromium(VI) ion in external aqueous phase at $25^{\circ}C$. It is concluded that the most stable formation of liquid membrane emulsion was obtained when surfactant concentration is above 3 wt. % and liquid parafnn oil concentration is 50 vol. %. The transport of chromium(VI) ion in bacth extractor increased with increasing carrier concentration, the volume ratio of emulsion to external aqueous phases, and initial concentration of chromium(VI) ion under the optimum stirring speed of chromium(VI) ion below 2 ppm. The theoretical equation on the transport of chromium(Vl) ion agreed well with the experimental results.

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Investigation on the Sintering Behavior of P/M Al-Zn-Mg-Cu Alloy

  • Shahmohammadi, M.;Simchi, A.;Danninger, H.;Arvand, A.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.536-537
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    • 2006
  • In the present work, the sintering behavior of high strength Al-5.6Zn-2.5Mg-1.6Cu (in wt.%) alloy compacts prepared from elemental powders was investigated. Microstructural evaluation was accompanied by XRD and DSC methods in order to determine the temperature and chemical composition of the liquid phases formed during sintering. It was found that three transient liquid phases are formed at 420, 439 and 450 $^{\circ}C$. Microstructural study revealed the progressive formation of sintered contacts due to the presence of the liquid phases, although the green compact expands as a result of the melt penetration along the grain boundaries. While Zn melts at ${\sim}420\;^{\circ}C$, the intermetallic phases formed between Al and Mg were found to be responsible for the formation of liquid phase and the dimensional change at higher temperatures.

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열경화성 액정 에폭시 수지의 액정상 변화를 포함한 시간-온도-전이 다이어그램 (Time-Temperature-Transition Diagrams with Liquid Crystalline Phase Changes of Liquid Crystalline Epoxy)

  • 조승현
    • Composites Research
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    • 제37권3호
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    • pp.215-218
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    • 2024
  • Diglycidyl ether of 4,4'-dihydroxy-α-methylstilbene (DGE-DHMS)에 aniline을 2:1의 비율로 첨가한 액정에폭시올리고머인 DD-A를 합성하고 촉매성 경화제인 1-Methyl Imidazole을 이용하여 경화시키며 겔화 및 유리화 시간을 측정하여 액정 변화가 포함된 Time-Temperature-Transition Diagram을 작성하였다. 경화제의 농도가 높아질수록 겔화 및 유리화 시간이 감소함을 확인할 수 있었고 유리화 곡선은 전형적인 S-형태를 보였다.

점성액체 기포탑에서 탑의 직경이 기포, wake 및 연속액상 체류량에 미치는 영향 (Effects of Column Diameter on the Holdups of Bubble, Wake and Continuous Liquid Phase in Bubble Columns with Viscous Liquid Medium)

  • 임대호;장지화;강용;전기원
    • Korean Chemical Engineering Research
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    • 제49권5호
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    • pp.582-587
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    • 2011
  • 점성액체 기포탑에서 기포, wake 및 연속액상들의 체류량 특성을 고찰하였다. 기포탑의 직경(0.051, 0.076, 0.102 and 0.152 m ID), 기체 유속(0.02~0.16 m/s) 그리고 연속액상의 점도(0.001~0.050 $Pa{\cdot}s$)가 기포, wake 및 연속액상의 체류량에 미치는 영향을 검토하였다. 기포, wake 그리고 연속액상들은 이중 전기 저항탐침방법에 의하여 성공적으로 구별할 수 있었다. 압축된 여과공기와 물 또는 CMC 수용액을 각각 기체와 연속액상으로 사용하였다. 기포탑에서 기포와 wake 상들을 연속적으로 검침하기위해 자료수집장치(DT 2805 Lab Card)와 컴퓨터를 사용하였다. 탐침 써키트로부터 수집된 아날로그 자료는 디지털 자료로 변환되었으며, 이들 자료를 이용하여 기포탑에서 상승하는 단일기포 뿐만이 아니라 다중기포들의 후면에서 wake 상을 검침할 수 있었다. 기포와 wake 상의 체류량은 각각 기포탑의 직경과 연속액상의 점도가 증가함에 따라 감소하였으나 연속액상의 체류량은 증가하였다. 그러나, 기포와 wake의 체류량은 각각 기체 유속이 증가함에 따라 증가한 반면 연속액상의 체류량은 감소하였다. wake 상 체류량에 대한 기포 체류량의 비율은 기포탑의 직경 또는 기체의 유속이 증가함에 따라 감소한 반면 연속액상의 점도가 증가함에 점성액체 기포탑에서 기포, wake 그리고 연속액상의 체류량은 본 연구의 실험범위에서 다음과 같은 실험변수의 상관식으로 나타낼 수 있었다. ${\varepsilon}_B=0.043D^{-0.18}U_G^{0.56}{\mu}_L^{-0.13}$, ${\varepsilon}_W=0.003D^{-0.85}U_G^{0.46}{\mu}_L^{-0.10}$, ${\varepsilon}_C=1.179D^{0.09}U_G^{-0.13}{\mu}_L^{0.04}$.

용융금속 교반공정을 통한 고Fe 함유 A356 합금의 미세조직 개질 (Microstructural Modification of High-Fe Containing A356 Alloy by Liquid Metal Shearing Process)

  • 김봉환;이상목
    • 한국주조공학회지
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    • 제31권6호
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    • pp.354-361
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    • 2011
  • The liquid metal shearing device was constructed and assembled with a commercial high-pressure die-caster in order to induce intensive turbulent shearing force on molten aluminum alloys. The effect of the liquid metal shearing on the microstructure and tensile properties of A356 alloys was investigated with the variation of iron content. The experimental results show that dendritic primary ${\alpha}$-Al phase was effectively modified into a equiaxed form by the liquid metal shearing. It was also found that the needle-like ${\beta}$-AlFeSi phase in a Fe containing A356 alloy was changed into a blocky shape resulting in the improved mechanical properties. Based on the mechanical properties, it was suggested that the iron content in A356 alloy could be more widely tolerated by utilizing the liquid metal shearing HPDC process.

Mechanism of Formation of Three Dimensional Structures of Particles in a Liquid Crystal

  • West, John L.;Zhang, Ke;Liao, Guangxun;Reznikov, Yuri;Andrienko, Denis;Glushchenko, Anatoliy V.
    • Journal of Information Display
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    • 제3권3호
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    • pp.17-23
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    • 2002
  • In this work we report methods of formation of three-dimensional structures of particles in a liquid crystal host. We found that, under the appropriate conditions, the particles are captured and dragged by the moving isotropic/nematic front during the phase transition process. This movement of the particles can be enhanced significantly or suppressed drastically with the influence of an electric field and/or with changing the conditions of the phase transition, such as the rate of cooling. As a result, a wide variety of particle structures can be obtained ranging from a fine-grained cellular structure to stripes of varying periods to a course-grained "root" structures. Changing the properties of the materials, such as the size and density of the particles and the surface anchoring of the liquid crystal at the particle surface, can also be used to control the morphology of the three-dimensional particle network and adjust the physical properties of the resulting dispersions. These particle structures may be used to affect the performance of LCD's much as polymers have been used in the past.

식물세포배양으로부터 파클리탁셀 회수를 위한 초음파를 이용한 액-액 추출 (Ultrasound-Assisted Liquid-Liquid Extraction for Recovery of Paclitaxel from Plant Cell Cultures)

  • 하건수;김진현
    • Korean Chemical Engineering Research
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    • 제54권2호
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    • pp.229-233
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    • 2016
  • 본 연구에서는 식물세포배양액으로부터 파클리탁셀을 효율적으로 회수하기 위하여 초음파를 이용한 액-액 추출 공정을 개발하였다. 액-액 추출을 위한 최적의 초음파 파워와 조업 시간은 주어진 하층(메틸렌 클로라이드 층)/상층(메탄올 농축액 층) 비(25%, v/v)에서 각각 250W와 15 min임을 알 수 있었다. 최적 조건 하에서 초음파를 이용한 액-액 추출 공정의 경우 단 1 회 추출로 대부분의 파클리탁셀을 하층(메틸렌 클로라이드 층)으로부터 회수(~92%) 가능하였다. 또한 무기염 첨가에 의한 초음파 상승효과로 인하여 액-액 추출을 위하여 적절한 무기염 농도와 초음파 파워가 요구됨을 알 수 있었다.

Lyotropic Behaviors of a Phospholipid-based Lamella Liquid Crystalline Phase Hydrated by Propylene Glycol as a Polar Solvent: Correlation of DSPC vs PG Concentration

  • Jeong, Tae-Hwa;Oh, Seong-Geun
    • Bulletin of the Korean Chemical Society
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    • 제28권1호
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    • pp.108-114
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    • 2007
  • The lyotropic behaviors to form the structure of distearoylphosphatidylcholine (DSPC)-based liquid crystal (LC) hydrated by only propylene glycol (PG) without water were examined by differential scanning calorimetry (DSC), X-ray diffractions (XRD), polarized microscope (PM) and transmission electron microscope (TEM). By increasing the amount of PG instead of water, it showed the phase transition to be gradually changed from anisotropic structures to other structures more close to isotropic ones and their appearance to be changed from solid-like states to liquid-like ones with more fluidity. Below 50% w/w PG, the mixtures of DSPC and PG resulted in no direct observation of LC structure through PM because they were very close to solid-states. From 55% w/w to 90% w/w of PG, the dense lamella crystalline structures were observed through PM, and their thickness and area decreased as the content of PG increased. Measured by DSC with heating process, the main phase transition from α -lamella phase to isotropic phase appeared from 52.89 °C to 47.41 °C to show linearly decreasing behaviors because PG affects the hydrophobic region of DSPC-based lamella phase. The repeating distance of the lamella phase and the interlayer distance between bilayers were calculated with XRDs and the average number of bilayers related to the thickness in LC structure was approximately estimated by combining with TEM results. The WAXS and DSC measurements showed that all of PG molecules contributed to swelling both the lipid layer in the edge region of lamella phase close to phosphate groups and the interlayer between bilayers below 90% w/w of PG. The phase and thermal behaviors were found to depend on the amount of PG used by means of dissolving DSPC as a phospholipid and rearranging its structure. Instead of water, the inducement of PG as a polar solvent in solid-lamella phase is discussed in terms of the swelling effect of PG for DSPC-based lamella membrane.

합성 고분자물질 A611P를 첨가한 기액 2상 수직상향의 유동특성에 관한 실험적 연구 (Experimental study on the flow characteristic by the co-polymer A6l1P additive in gas-liquid two-phase vertical up flow)

  • 차경옥;김재근;양회준
    • 설비공학논문집
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    • 제10권4호
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    • pp.398-410
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    • 1998
  • Two-phase flow phenomena are observed in many industrial facilities and make much importance of optimum design for nuclear power plant and the liquid transportation system. The particular flow pattern depends on the conditions of pressure, flow velocity, and channel geometry. However, the research on drag reduction in two-phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction and void fraction by polymer addition in the two-phase flow system. We find that the polymer solution changes the characteristic of two-phase flow. The peak position of local void friction moves from tile wall of the pipe to the center of the pipe when polymer concentration increase. And then we predict that it is closely related with the frau reduction.

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