• 한국자동차공학회논문집
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• 제12권5호
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• pp.73-78
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• 2004

The liquid phase LPG injection (LPLi) system (the third generation technology) has been considered as one of the next generation fuel supply systems for LPG vehicles, since it has a very strong potential to accomplish the higher power, higher efficiency, and lower emission characteristics than the mixer type(the second generation technology) fuel supply system. To investigate the durability property of core part of injector in liquid phase LPG injection system, leakage test, SEM test of injectors and analysis of unvaporized fuel components with various LPG fuel qualities were tested. The experimental results showed that no serious problem in durability test using favorable LPG fuel quality, while high leakage amount due to the large scratches in the needle and nozzle of the injector were found using LPG fuel with highly containing olefin components, especially butadiene species.

• 한국세라믹학회지
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• 제35권12호
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• pp.1308-1315
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• 1998

Effects of particle size of alumina on densification behavior during liquid-phase sintering of alumina-talc system were investigated with emphasis on particle rearrangement process. In the case of using coarse alu-mina powder densiication of specimens was rapidly accelerated after formation of liquid phase due to easy particle rearrangement process with addition of talc and increase of sintering temperature. On the contrary when fine alumina powder was used premature densification of alumina matrix region formed before for-mation of liquid phase rigid skeleton structure and then it seemed to inhibit rearrangement process during crease of sintering temperature. As results the densification of specimens using coarse alumina powder was higher than that of the case of using fine one.

• 한국자동차공학회논문집
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• 제11권5호
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• pp.15-21
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• 2003

The liquid phase LPG injection engine is a new technology to make good use of LPG as a clean energy. However, it is difficult to precisely control air/fuel ratio in the system because of variation of fuel composition, change of temperature and flash boiling injection mechanism. This study newly suggests an injector control logic for liquid phase LPG injection systems. This logic compensates a number of effects such as variations of density, stoichiometric air/fuel ratio, injection delay time, injection pressure, release pressure which is formed by flash boiling of fuel at nozzle exit. This logic can precisely control air/fuel ratio with only two parameters of intake air flow rate and injection pressure without considering fuel composition, fuel temperature.

• 한국자동차공학회논문집
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• 제11권5호
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• pp.22-28
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• 2003

Flash boiling mechanism in the injector interferes with fine fuel metering in a liquid phase LPG injection engine. This study presents a mathematical model to precisely predict an injection quantity. A calibration procedure of injection quantity, which is very prompt and precise in measuring, is developed using a gas analyzer. According to this procedure, injection quantity can be obtained under various fuel compositions, temperatures and injection pressures. The release pressure of liquid phase LPG is estimated based on these experimental data. Although the release pressure is much lower than the saturation pressure, it is linearly proportional to the saturation pressure.

• 한국세라믹학회지
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• 제39권9호
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• pp.818-821
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• 2002

The grain boundary resistivity of a 1-mol%-$Al_2O_3$-dopedd CaO-Stabilized Zirconia(CSZ) specimen was determined by impedance spectroscopy using sub-millimeter-scale electrodes. At the initial stage of sintering, the grain-boundary resistivity of the specimen interior was observed to be higher than that of the surface. However, upon further sintering the boundary resistivity of the specimen interior became lower than that of the surface. The results were explained in terms of a redistribution of the intergranular liquid phase. The liquid phase was predicted to initially coagulate at the interior of the specimen then spread outward during sintering.

• Bulletin of the Korean Chemical Society
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• 제5권3호
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• pp.126-129
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• 1984

The reaction of aryl halides with phenoxides and alkoxides were investigated under phase transfer catalytic conditions. 2,4-Dinitro- and 4-nitrohalobenzenes reacted readily with phenoxides in NaOH(aq)-benzene in the presence of Bu4N+Br, affording the products quantitatively. Although the aryl halides did not react with alkoxides under the same condition, the reactions were completed within 2 hours at room temperature when conducted under solid-liquid phase transfenr catalytic condition. The reactivity of aryl halides was in the order, Ar = 2,4-dinitrophenyl > 4-nitrophenyl, and X = F > Cl, consistent with the SNAr mechanism. The reactivity of oxyanions increased with the change of reaction condition from liquid-liquid to solid-liquid phase transfer catalysis. The results were explained with the concentration and the degree of hydration of the anion in benzene.

• Korean Chemical Engineering Research
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• 제57권1호
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• pp.73-77
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• 2019

Isothermal (vapor + liquid) equilibrium data measurements were undertaken for the binary mixtures of (propylene oxide + 1-pentanol) system at three different temperatures (303.15, 318.15, and 333.15) K. The Peng-Robinson-Stryjek-Vera equation of state (PRSV EOS) was used to correlate the experimental data. The van der Waals one-fluid mixing rule was used for the vapor phase and the Wong-Sandler mixing rule, which incorporates the non-random two liquid (NRTL) model, the universal quasi-chemical (UNIQUAC) model and the Wilson model, was used for the liquid phase. The experimental data were in good agreement with the correlation results.

• 한국자기공명학회논문지
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• 제24권4호
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• pp.96-103
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• 2020

A new NMR method to monitor solvent-localized NMR signals in the two-phase liquid system is suggested. This method based on intermolecular single-quantum coherence (iSQC). Here, we exploited the feature of the local action of distant dipolar field (DDF) effect in order to filter out specific NMR signals dissolved in different solvents. This solvent specific iSQC spectroscopy was carried out on a model two-phase liquid system (D-glucose in water/palmitic acid in chloroform), and showed solvent-localized NMR signals. We believe our approaches might be useful in metabolic analysis such as two-phase liquid extraction scheme for labile chemical species.

• Archives of Pharmacal Research
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• 제26권10호
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• pp.880-885
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• 2003

Research in this paper focuses on the kinetic evaluation of swelling of the liquid crystalline phases of glyceryl monooleate (GMO). Swelling of the lamellar and cubic liquid crystalline phases of GMO was studied using two in vitro methods, a total immersion method and a Franz cell method. The swelling of the lamellar phase and GMO having 0 %w/w initial water content was temperature dependent. The swelling ratio was greater at $20^{\circ}^C than 37^{\circ}^C$ . The water uptake increased dramatically with decreasing initial water content of the liquid crystalline phases. The swelling rates obtained using the Franz cell method with a moist nylon membrane to mimic buccal drug delivery situation were slower than the total immersion method. The swelling was studied by employing first-order and second-order swelling kinetics. The swelling of the liquid crystalline phases of GMO could be described by second-order swelling kinetics. The initial stage of the swelling (t < 4 h) followed the square root of time relationship, indicating that this model is also suitable for describing the water uptake by the liquid crystalline matrices. These results obtained from the current study demonstrate that the swelling strongly depends on temperature, the initial water content of the liquid crystalline phases and the methodology employed for measuring the swelling of GMO.

• 한국추진공학회지
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• 제14권2호
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• pp.1-9
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• 2010

난류 유동장으로 분사되는 액체 제트의 액주 분열과 액적 미립화 현상에 관한 LES를 수행하였다. 기체상태의 공기 유동해석에 Eulerian 해법을 사용하고, 액적 추적을 위하여 Lagrangian 해법을 사용하여 기체-액체간 이상유동(two phase flow) 해석을 수행하였다. 액적 분열 과정 모사에 blob-KH 분열 모델을 적용하여 액주와 액적의 분열이 관찰되었다. 일정한 공기 유동 조건에서 액체 분사 속도 변화를 통한 액체-기체 운동량 플럭스 비의 변화에 따른 액체 제트의 침투깊이를 조사하였으며 실험결과와 유사함을 알 수 있었다. 분사 제트의 분열에 따라 유동장에 존재하는 액적의 분포를 Sauter 평균 입경(SMD)의 분석을 통해 수행하였다.