• Title/Summary/Keyword: liquid water

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Is Liquid Water a Hot Quantum Fluid? Anomalies of Water in Thin Liquid Films and in Biological Systems

  • Yoon, Byoung-Jip
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1211-1214
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    • 2003
  • The anomalies that appear at every multiple of 15 ℃ in the viscosity of a thin liquid film of water and of water near solid interfaces are explained in this paper by comparing the thermal wavelength and molecular free volume of water, and quantum numbers are found. The possibility that these anomalies are related to the preferred and/or lethal temperatures of organisms is considered. The toxicity of heavy water (D₂O) can also be explained with this approach.

RHEOLOGICAL PROPERTIES OF OIL/WATER EMULSION AND OIL/LIQUID CRYSTAL/WATER SYSTEMS AND THEIR CONSUMER PERCEPTION IN HAIR CARE PRODUCTS

  • Kim, Chong-Youp;Hong, Jong-Eoun;Kim, Su-Hyun;Kang, Hak-Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.4 s.34
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    • pp.123-131
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    • 1999
  • Liquid crystal known as a rheological barrier to coalescence of oil droplets, increases emulsion stability, water-holding capacity and promotes active material penetration to skin. Some investigation for its rheological characteristics have been reported but its relations to consumer perception have been rarely published. In this study, oil/water emulsion and oil/liquid crystal/water systems were manufactured using the same composition or Behenyltrimethylammonium chloride/Cetostearyl alcohol/Lanolin oil. and rheological properties or each system were investigated with Cone and Plate rheometer. The formation of liquid crystalline phase was observed with polarized microscope and Differential Scanning Calorimeter. Continuous shear experiment, creep, yield and water holding capacity were measured for oil/water and oil/liquid crystal/water systems. The results were compared with sensory evaluations. Oil/liquid crystal/water system showed higher,viscosity at the same shear rate. higher viscoelasticity and higher yield stress than oil/water system. These properties were expected to show good spreadability and excellent richness without waxiness in hair can: products of creme type. This expectation was consistent with the results of sensory experiments. Water-holding capacity was evaluated by measuring residual water of specimens at specific temperature and relative humidity. Oil/liquid crystal/water system was proved to have higher ability to hold water in comparison with oil/water system. The results indicated that oil/liquid crystal/water system was of benefit to rheological properties creme type hair care products.

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PHEOLOGICAL PROPERTIES OF OIL/WATER EMULSION AND OIL/LIQUID CRYSTAL/WATER SYSTEMS AND THEIR CONSUMER PERCEPTION IN HAIR CARE PRODUCTS

  • Kim, Chongyoup;Jongeoun Hong;Kim, Suhyun;Hakhee Kang
    • Proceedings of the SCSK Conference
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    • 1999.10a
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    • pp.123-131
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    • 1999
  • Liquid crystal known as a rheological barrier to coaleseence of oil dorplets. increases. emulsion stability, water-holding capacity and promotes active material penetration to skin. Some investigation for its rheological characteristics have been reported but its relations to consumer perception have been rarely published. In this study oil/water emulsion and oil/liquid crystal/water systems were manufactured using the same composition of Behenyltrimethylammonium chloride/Cetostearyl alcohol/Lanolin oil. and rheological properties of each system were investigated with Cone and Plate rheometer. The formation of liquid crystalline phase was observed with polarized microscope and Differential Scanning Calorimeter. Continuous shear experiment, creep yield and water holding capacity were measured for oil/water and oil/liquid crystal/water systems. The results were compared with sensory evaluations. Oil/liquid crystal/water system showed higher viscosity at the same shear rate, higher viscoelasticity and higher yield stress than oil/water system. These properties were expected to show good spreadability and excellent richness without waxiness I hair care products of creme type. This expectation was consistent with the results of sensory experiments. Water-holding capacity was evaluated by measuring residual water of specimens at specific temperature and relative humidity, Oil/liquid crystal/water system was proved to have ability to hold water in comparison with oil/water system. The results indicated that oil/liquid crystal/water system was of benefit to rheological properties creme type hair care products.

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A Study on the Research of Analytical Method for 1,4-Dioxane in Water (1,4-Dioxane의 분석방법 연구)

  • Park, Sun-Ku;Kim, Tae-Ho;Rim, Yeon-taek;Myung, Nho-Il
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.549-563
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    • 2005
  • The study was carried out to develop and standardize the analytical method of 1,4-dioxane in water. The National Institute of Environmental Research in Korea has monitored for 1,4-dioxane in water since 1998 and it has been detected in environmental water occasionally. But the environmental pollution and analytical method in water is not well known over the world. The trace analytical method at low-${\mu}/L$ level is prerequisite in order to evaluate the residue of 1,4-dioxane in water. Evaluation of the method was demonstrated by comparing and analyzing with liquid-liquid extraction, solid-phase extraction and purge & trap technique. As a result of experiment by standard solutions and raw samples, the precision and accuracy for three methods were obtained within error rate of about 10%. Therefore, three methods were standardized as official monitoring method in Korea. Also, a convenient and simple liquid-liquid extraction method for the analysis of 1,4-dioxane in water was developed by combined with gas chromatography/mass spectrometry and applied to the water samples in Korea

Combined Microwave Radiometer and Micro Rain Radar for Analysis of Cloud Liquid Water

  • Yang, Ha-Young;Chang, Ki-Ho;Kang, Seong-Tae
    • Journal of Integrative Natural Science
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    • v.6 no.1
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    • pp.12-15
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    • 2013
  • To combine the micro rain radar and microwave radiometer cloud liquid water, we estimate the cloud physical thickness from the difference between the MTSAT-1R cloud top height and cloud base height of visual observation of Daegwallyeong weather station, and the cloud liquid water path of micro rain radar is obtained by multiplying the liquid water content of micro rain radar and the estimated cloud physical thickness. The trend of microwave radiometer liquid water path agrees with that of the micro rain radar during small precipitation. We study these characteristics of micro rain radar and microwave radiometer for small precipitation to obtain the combined cloud water content of micro rain radar and microwave radiometer, constantly operated regardless to the rainfall.

Pesticide Analysis in Drinking Water by SPE Method (SPE법에 의한 음료수중 농약성분)

  • 김형석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.2
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    • pp.59-66
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    • 1995
  • According to the population increase and industrialization, the drinking water source, Han River and other sources, are contaminated by industrial wastewater, domestic sewage, and agricultural discharges. Among the contaminants, and toxic substances, pesticides is most interesting items (or human health Our drinking water has some problems of THMs, Fe, odor, etc., $o many people use groundwater or bottled water. But sometimes there are many reports about groundwater contamination owing to the agricultural chemicals, waste disposal, industrial wastewater. In America, there are about 45,000 groundwave supply company and in korea about 20% of total population are using groundwave as drinking water source. In America, studies about SEE is increasing Instead of liquid- liquid extraction method, because of many advantages of SEE methods. Author tried to investigate SPE methods in the spiked water samples to compare with liquid- liquid extraction method and got the following results. The amount of organic solvents which are used In SPE method is less than 1/10 compared with liquid- liquid method, the analytical duration time is shortened, and the ethyl acetate was good fluent among several organic solvents.

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Development of Automatic Analysis System for Water Repellency of Packaging Paper -Automatic Measurement of Water Repellency Based on KS M 7057- (포장지의 발수도 자동 해석 시스템 개발 -KS M 7057에 근거한 발수도 자동 측정-)

  • 김철환;최경민;강진기;박종열
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.1
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    • pp.7-12
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    • 2003
  • The test results for water repellency of paper and paperboard according to KS M 7057 can readily be influenced by an operator's bias. In order to discard such bias, the automatic analysis program of water repellency was developed based on different shape features of a liquid trace formed on a specimen. That is, the shape of a liquid track flowing down on the specimen with an angle of $45^{\circ}$ was evaluated according to width variation between head and tail of the trace($S_{Hr}$), uniformity of a liquid flow($S_{d}$), length of long traces($L_{SHr}$), eccentricity of liquid traces($E_{i}$), and then was recognized as a specific degree of water repellency. Finally, the automatic analysis system of water repellency based upon KS M 7057 made it possible to readily measure water resistance of paper and paperboards classified into R0 to R10.

CFD Analysis on Two-phase Flow Behavior of Liquid Water in Cathode Channel of PEM Fuel Cell (PEM 연료전지 공기극 유로에서 물의 가동에 대한 CFD 해석)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu
    • New & Renewable Energy
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    • v.3 no.4
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    • pp.8-15
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    • 2007
  • Liquid water in flow channel is an important factor that limits the steady and transient performance of PEM fuel cells. A computational fluid dynamics study based on the volume-of-fluid [VOF] multi-phase model was conducted to understand the two-phase flow behavior of liquid water in cathode gas channels. The liquid water transport in $180^{\circ}{\Delta}$ bends was investigated, where the effects of surface characteristics (hydrophilic and hydrophobic surfaces], channel geometries (rectangular and chamfered corners], and air velocity in channel were discussed. The two-phase flow behavior of liquid water with hydrophilic channel surface and that with hydrophobic surface was found very different; liquid water preferentially flows along the corners of flow channel in hydrophilic channels while it flows in rather spherical shape in hydrophobic channels. The results showed that liquid water transport was generally enhanced when hydrophobic channel with rounded corners was used. However, the surface characteristics and channel geometries became less important when air velocity was increased over 10m/s. This study is believed to provide a useful guideline for design optimization of flow patterns or channel configurations of PEM fuel cells.

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A Numerical Model for Heat and Mass Transfer Processes within a Vertical Tube GAX Absorber (수직원관형 GAX 흡수기 내부의 열 및 물질전달과정에 대한 수치모델)

  • 천태식;정은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.102-111
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    • 2000
  • A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

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Correlation of Liquid-Liquid Equilibrium of Four Binary Hydrocarbon-Water Systems, Using an Improved Artificial Neural Network Model

  • Lv, Hui-Chao;Shen, Yan-Hong
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.370-376
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    • 2013
  • A back propagation artificial neural network model with one hidden layer is established to correlate the liquid-liquid equilibrium data of hydrocarbon-water systems. The model has four inputs and two outputs. The network is systematically trained with 48 data points in the range of 283.15 to 405.37K. Statistical analyses show that the optimised neural network model can yield excellent agreement with experimental data(the average absolute deviations equal to 0.037% and 0.0012% for the correlated mole fractions of hydrocarbon in two coexisting liquid phases respectively). The comparison in terms of average absolute deviation between the correlated mole fractions for each binary system and literature results indicates that the artificial neural network model gives far better results. This study also shows that artificial neural network model could be developed for the phase equilibria for a family of hydrocarbon-water binaries.