• Journal of the Korean Chemical Society
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• v.48 no.3
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• pp.261-265
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• 2004

We investigated the order of local movement of functional groups (-C(=O)O) in a liquid crystalline (LC) oligomer (12-4) using 2D Raman correlation spectroscopy. The results suggest that the free carbonyl near the ethyl terminal group moved first, followed by the hydrogen-bonded group. The free carbonyl group between the biphenyl groups rarely moved. Interestingly, 2D sample-to-sample correlation spectroscopy (2D STSCS) revealed that some of the carbonyl modes started to move at far below (50$^{\circ}C$) the LC temperature (135$^{\circ}C$), countering conventional beliefs.

• Korean Journal of Materials Research
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• v.18 no.3
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• pp.128-136
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• 2008

Evaluation of the solid surface properties by an analysis of the liquid penetration rate into powder beds is very important in applications of powder products. The penetration rate is related the surface property in powder beds. In order to analyze the surface property of powders, the contact angle values of several powders were obtained using the Washbun equation and the Wicking method. The surface free energy value ${\gamma}S$ was divided into a polar component ${\gamma}S^p$ and a dispersion component ${\gamma}S^d$. Inorganic powders such as calcite were used as test samples. The effects of the particle size and the type of experimental liquid on the penetration rate were measured. It was confirmed that the surface free energy of the grinding sample is smaller than that of the classification sample.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.05a
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• pp.279-282
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• 2005

Composites comprising various volume fractions of crystalline nickel and bulk amorphous (BA) were produced by means of electroless coating of nickel on BA powder of $Cu_{54}Ni_6Zr_{22}Ti_{18}$ and subsequent spark plasma sintering (SPS) of coated BA powder. The flow curves of composites at various temperatures in the supercooled liquid region were determined by the uniaxial compression test with various strain rates. During compression at $450^{\circ}C$ with $\dot{\varepsilon}=2\times10^{-3}$, the monolithic BA sample and crystalline-BA composites displayed the superplastic deformation with $\varepsilon>1.4$. At temperatures above $460^{\circ}C$, the stress-strain curve of the monolithic BA sample depicted a sharp peak stress and a fellowing stress drop due to cracking, while those of the crystalline-BA composites displayed work-hardening up to the imposed strain. FEM analysis indicated that a fairly homogeneous strain state prevailed throughout the composite, while a higher level of stress was obtained in a harder BA.

• Food Science of Animal Resources
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• v.41 no.2
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• pp.335-342
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• 2021

Vitamin B12 deficiency may lead to serious health issues in both infants and adults. A simple analytical method involving sample pretreatment with enzyme, followed by cyanide addition under acidic conditions; separation on an immunoaffinity column; and high-performance liquid chromatography (HPLC) was developed for the rapid detection and quantitation of vitamin B12 in powdered milk. Detection limit and powdered milk recovery were determined by quantitative analysis. The limits of detection and quantitation were 2.71 and 8.21 ㎍/L, respectively. Relative standard deviations of the intra-day and inter-day precisions varied in the ranges of 0.98%-5.31% and 2.16%-3.90%, respectively. Recovery of the analysis varied in the range of 83.41%-106.57%, suggesting that the values were acceptable. Additionally, vitamin B12 content and recovery in SRM 1849a were 54.10 ㎍/kg and 112.24%, respectively. Our results suggested that the analytical method, including the sample pretreatment step, was valid. This analytical method can be implemented in many laboratory-scale experiments that seek to save time and labor. Therefore, this study shows that immunoaffinity-HPLC/ultraviolet is an acceptable technique for constructing a reliable database on vitamin B12 in powdered milk containing starch as well as protein and/or fat in high amounts.

• Analytical Science and Technology
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• v.20 no.1
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• pp.70-77
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• 2007

Twelve chlorophenols (CPs) were extracted by liquid phase microextraction (LPME) from the industrial waste-water and analyzed by GC/MS. To establish the optimal conditions, species of extraction solvent, sample amount, pH of sample, salting out effect, a number of sampling and plunger movement speed were investigated. As a result, the linearities of calibaration curves ranged from 0.9913 to 0.9999, while LODs and LOQs were from 0.05 to 10.0 ng/mL except 2,3,4,5-tetrachlorophenol and pentachlorophenol. Using this method, 4-chloro-3-methylphenol confirmed from waste water at the concentration of 784 ng/mL. The method can be applicable to detect chlorophenols from industrial waste-water.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.3
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• pp.180-187
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• 1999

Radiocarbon dating method using benzene liquid scintillation was performed on the oyster shell fragments which producted from the shell mounts at Hadong Mogdori in Kyeongsangnamdo. This paper described to the age dating method and compared to the result. The carbon in sample is synthesized to a benzene through the sample preparation, $SrCO_3$, $SrC_2$, $C_2H_2$ and $C_6H_6$ synthesizing process. Age dating is calculated by Wallac 1415 Liquid Scintillation Counter. The result of age dating is estimated to be $4905{\pm}112$ yr BP in Yosu Univ. which is a good agreement with the result in Shimane Univ. ($4912{\pm}123$ yr BP). Radiocarbon dating method using benzene liquid scintillation is a simple and economical in operation and establishment, it has a potential instrumentation in the university and research institute.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.92-100
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• 2000

One method to analyse acoustic modes is proposed to predict the characteristics of acoustic instability in liquid rocket engine. It is based on the similarity between transverse acoustic modes and adopts two-dimensional axisymmetric geometry. Using this method, the first tangential mode in the prototype combustor can be analysed through the analysis of the first radial mode in the model combustor with doubled chamber diameter. Sample numerical calculation is demonstrated applying this method to sample rocket engine and thereby acoustic instabilities of the engine are investigated. The present results show a good agreement with the previous findings. The numerical analysis based on the proposed method is cost-effective and serves as the first approximation to the true solution.

• Korean Journal of Veterinary Service
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• v.21 no.3
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• pp.261-266
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• 1998

A method for the determination of noboviocin in milk was presented by high performance liquid chromatography(HPLC). The novobiocin in the spiked sample was extracted with methanol and evaporated under vacuum. After evaporating, the residue was mixed with distilled water for 2$m\ell$, filtrates with 0.45$\mu\textrm{m}$ acrodisc was injected into HPLC. The results obtained were as follows ; 1. The calibration curve of novobiocin was showed constantly linear(r 0.999) in the range of 100~500ng/$m\ell$. 2. The mean recovery rate of novobiocin from the spiked milk sample were 88~98%. 3. The coefficients of variation were 2.6~5.8% 4. The lowest detectable limit of novobiocin was 25ppb.

• Journal of Korean Society on Water Environment
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• v.18 no.4
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• pp.365-370
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• 2002

This study aims to study the effect of HRT and influent concentration on swine wastewater treatment using UASB(Upflow Anaerobic Sludge Blanket). Sample was separately collected from the piggery farm; urine(liquid part) and solid part to compare their treatment characteristics. Reactors were used two UASB(3.2 L) in this research under constant temperature ($35^{\circ}C$). Their operating conditions were as follows; Run 1(UASB ; HRT 6-days, 1 cycle/d), Run 2(UASB ; HRT 3-days, 1 cycle/d). Biogas was collected and analyzed using GC(HP-6890). By comparing the results of Run 1 and Run 2, the effect of HRT was investigated. The treatment efficiency of Run 1 which had longer HRT was higher than that of Run 2 in both solid and liquid parts of piggery sample. Methane content in collected biogas is more than 80%.

• Journal of the Korean Institute of Telematics and Electronics
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• v.26 no.12
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• pp.1995-2000
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• 1989

The ion beam system of 20keV C-W (Cockroft Walton) type composed of the AuGe alloy LMIS(Liquid Metal Ion Source) has been designed and constructed. For the fabrication of the ohmic contact to the n-GaAs, the ion beam extracted from the AuGe alloy source was implanted into the n-GaAs, and it was measured by contact resistivity. The stable AuGe ion beam(2.5\ulcorner/cm\ulcorner was obtained at the extraction voltage of 14.5kV. The measurements of the contact resistivity were done by the TLM (Transmission Line Model) method and the specific contact resistivity was found to be 2.4x10**-5 \ulcornercm\ulcornerfor the implanted sample by the 1.9x10**20/cm**3 and the annealed sample at 30\ulcorner for 2 min.