• Journal of the Korean Chemical Society
• /
• v.7 no.2
• /
• pp.128-132
• /
• 1963

A study has been made on the applicability of gas-liquid partition chromatography to the qualitative and quantitative analysis of complex mixture of gaseous hydrocarbons. While phthalate columns are widely used for this $purpose^9$, they separates neither saturated hydrocarbons from the unsaturated nor n-butane from isobutene or butene-1, therefore combined columns such as phthalate and dimethylsulfolane have been used for the perfect separation of gaseous hydrocarbons. It is shown by this study, however, that hydrocarbons having $C_1$ through $C_4$ can be separated with a 2-meters tetraethyleneglycol dimethylether column except ethane from ethylene, and trans-from cis-2-butene especially operated at $15^{\circ}C$$ using helium as the carrier gas. The column effluents were in order of methane, (ethane, ethylene), propane, propylene, isobutane, n-butane, isobutylene, butene-1, (trans-& cis-2-butene, isopentane), (butadiene-1, 3, n-pentane). Two kinds of liquified petroleum gases in market are analysed qualitatively and quantitatively. The results indicate that use of this 2-meters TEGDE column permits the separation and identification of all the commonly encountered aliphatic gaseous hydrocarbons.

• Progress in Superconductivity and Cryogenics
• /
• v.22 no.4
• /
• pp.1-5
• /
• 2020

Heart consists of myocardium cells and the electrophysiological activity of the cells generate magnetic fields. By measuring this magnetic field, magnetocardiogram (MCG), functional diagnosis of the heart diseases is possible. Since the strength of the MCG signals is weak, typically in the range of 1-10 pT, we need sensitive magnetic sensors. Conventionally, superconducting quantum interference devices (SQUID)s were used for the detection of MCG signals due to its superior sensitivity to other magnetic sensors. However, drawback of the SQUID is the need for regular refill of a cryogenic liquid, typically liquid helium for cooling low-temperature SQUIDs. Efforts to eliminate the need for the refill in the SQUID system have been done by using cryocooler-based conduction cooling or use of non-cryogenic sensors, or room-temperature sensors. Each sensor has advantage and disadvantage, in terms of magnetic field sensitivity and complexity of the system, and we review the recent trend of MCG technology.

• Progress in Superconductivity and Cryogenics
• /
• v.24 no.2
• /
• pp.1-6
• /
• 2022

This paper reviews the literature that has been published since 1980s related to cryogenic refrigeration systems for quantum computing. The reason why such a temperature level of 10-20 mK is necessary for quantum computing is that the superconducting qubit is sensitive to even very small thermal disturbances. The entanglement of the qubits may not be sustained due to thermal fluctuations and mechanical vibrations beyond their thresholds. This phenomenon is referred to as decoherence, and it causes an computation error in operation. For the stable operation of the quantum computer, a low-vibration cryogenic refrigeration system is imperative as an enabling technology. Conventional dilution refrigerators (DR), so called 'wet' DR, are precooled by liquid helium, but a more convenient and economical precooling method can be achieved by using a mechanical refrigerator instead of liquid cryogen. These 'dry' DRs typically equip pulse-tube refrigerators (PTR) for precooling the DRs around 4 K because of its particular advantage of low vibration characteristic. In this review paper, we have focused on the development status of 4 K PTRs and further potential development issues will be also discussed. A quiet 4 K refrigerator not only serves as an indispensable precooler of DR but also immediately enhances the characteristics of low noise amplifiers (LNA) or other cryo-electronics of various type quantum computers.

• Progress in Superconductivity and Cryogenics
• /
• v.11 no.1
• /
• pp.16-19
• /
• 2009

Recently, for improvement of the magnetic field of high temperature superconductor (HTS) apparatus, many studies investigating on operating in the range of $20{\sim}65K$ with liquid helium or the conducting method using cryocooler is actively reviewed. Also, the cooling method using solid nitrogen as cryogen is being suggested. Since the nitrogen has very large specific heat in solid state, it is expected that it can enable long time operation without a continuous supply of cooling energy. However, there is still insufficient data on the characteristics of solid nitrogen such as thermodynamic properties and liquid-solid phase change. Especially, there was almost no study done on the electrical insulation properties of solid nitrogen so far. In this study, solid nitrogen to find the electrical characteristics was made by using cryocooler and cryostat, and investigated the flashover discharge and breakdown. The results of this study will be useful as a basic data for electrical insulation design of the HTS system using solid nitrogen as cryogen.

• Progress in Superconductivity and Cryogenics
• /
• v.26 no.1
• /
• pp.25-30
• /
• 2024

High-temperature superconducting rotors offer advantages in terms of output-to-weight ratio and efficiency compared to conventional phase conduction motors or generators. The rotor can be cooled by conduction cooling, which attaches a cryocooler, and by refrigerant circulation, which uses circulating liquid or gas neon, helium and hydrogen. Recent work has focused on environmental issues and on high-temperature superconducting motors cooled with liquid hydrogen that can be combined with fuel cells. However, to ensure smooth supply and return of the cryogenic cooling fluid, a cryogenic rotational coupling between the rotating and stationary parts is necessary. Additionally, the development of a sealing structure to minimize fluid leakage applicable to the coupling is essential. This study describes the design and performance evaluation of a non-contact sealing method, specifically a labyrinth seal, which avoids power loss and heat load caused by friction in contact sealing structures. The seal design incorporates a spiral flow path to reduce leakage using centrifugal force, and computational fluid dynamics (CFD) simulations were conducted to analyze the flow path and rotational speed. A performance evaluation device was configured and employed to evaluate the designed seal. The results of this study will be used to develop a cryogenic rotational coupling with supply and return flow paths for cryogenic applications.

• Nuclear Engineering and Technology
• /
• v.37 no.5
• /
• pp.401-422
• /
• 2005

We review here research and development progress achieved in US Plasma Chamber technology roughly over the last decade. In particular, we focus on two major programs carried out in the US: the APEX project (1998-2003) and the US ITER TBM activities (2003-present). The APEX project grew out of the US fusion program emphasis in the late 1990s on more fundamental science and innovation. APEX was commissioned to investigate novel technology concepts for achieving high power density and high temperature reactor coolants. In particular, the idea of liquid walls and the related research is described here, with some detailed examples of liquid metal and molten salt magnetohydrodynamic and free surface effects on flow control and heat transfer. The ongoing US ITER Test Blanket Module (TBM) program is also described, where the current first wall/blanket concepts being considered are the dual coolant lead lithium concept and the solid breeder helium cooled concepts, both using ferritic steel structures. The research described for these concepts includes both thermofluid MHD issues for the liquid metal coolant in the DCLL, and thermomechanical issues for ceramic breeder packed pebble beds in the solid breeder concept. Finally, future directions for ongoing research in these areas are described.

• Corrosion Science and Technology
• /
• v.15 no.3
• /
• pp.113-119
• /
• 2016

Corrosion science faces new challenges in various nuclear environments. Three main areas may be identified where increases of knowledge and understanding have been done and are still needed to face the technical needs: (i) the extension of the service time of nuclear power plants from 40 years, as initially planned, to 60 years and probably more as expected now, (ii) the prediction of long term behaviour of metallic materials in nuclear waste disposal where the corrosion processes have to be predicted over large periods of time, some thousands years and more, (iii) the choice of materials for use at very high temperatures as expected in Generation IV power plants in environments like gas (helium), supercritical water, liquid metals or salts. Service time extension, deep geological waste repositories and high temperature reactors sustain researches and developments to model corrosion phenomena at various scales, from atoms to components.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
• /
• 2002.02a
• /
• pp.378-381
• /
• 2002

The helium liquefier was installed for 7.5 T superconducting wiggler, which is a source of synchrotron radiation, in Pohang Accelerator Laboratory (PAL) in 1995. It is MODEL 1410 fabricated by LINDE (old PSI America) of which capacity is about 17 liter per hour in normal mode and 47 liter per hour with liquid nitrogen pre-cooling. In addition to SC wiggler, we are anticipating that some devices related to electron accelerator are to be upgraded with superconducting application in order to improve the quality of photon beam.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.49 no.4
• /
• pp.219-225
• /
• 2000

In this paper, we report the experimental setup and characterization of experimental results for the HTS antenna. The constructions of experimental setup must be fabricated, cautiously. We constructed the cryostat made of 3 stages which consists of radome, vacuum stage and helium refrigerator for the HTS antenna. The HTS antenna was mounted to cryostat and various characteristics were measured at room temperature and liquid nitrogen temperature, 77 K. Also the results for the HTS antenna and the gold antenna were compared in terms of reflection coefficient, E-plane and H-plane radiation pattern, input impedance, SWR and efficiency. It appeared that the HTS antenna was superior to gold counterpart over the all characteristics.

• Proceedings of the KIEE Conference
• /
• 1992.07b
• /
• pp.850-853
• /
• 1992

A cryogenic electron cyclotron resonance plasma etching system has been built to study wafer-temperature in the silicon etching characteristics. The wafer temperature was controlled from -150 to +30 $^{\circ}C$ during etching using the liquid nitrogen cooled helium gas. Although silicon was etched isotropically in $SF_6$ plasma at room temperatures, we found that it is possible to suppress the etch undercut in Si by reducing a substrate temperature without side wall passivation. In addition, the selectivity of silicon to photoresist was improved considerably at a low wafer temperature. Etch rates, anisotropy and selectivity to photo resist are measured as a function of the wafer temperature in the region of -125 $\sim$ 25$^{\circ}C$ and rf bias power of 20W $\sim$ 80W.