• Title/Summary/Keyword: liquid analyzer

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The Analysis of Free Amino Acids in Tobacco (잎담배 중 유리 아미노산 분석)

  • Lee, Jeong-Min;Min, Hey-Jung;Jang, Gi-Chul;Hwang, Keon-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.32 no.2
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    • pp.70-76
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    • 2010
  • A simple and sensitive automatic amino acid analyzer method for the determination of free amino acids in tobacco was described. Sample preparation consisted of a single step of extraction with 0.1 mol HCl at ambient temperature in 60 min by sonication, followed by filtration of an aliquot. Automated amino acid analyzer was used to construct a post-column ninhydrin reaction unit to monitor amino acids separated by liquid chromatography using a series of eluting buffers. By optimization of sample preparation, separation of 19 amino acids was achieved. Limits of quantitation was 0.01 mg/g, coefficients of variation ranged from 0.5 % to 8.9 % and recoveries range from 85 % to 106 %. The method was applied to the analysis of amino acids contents of tobacco leaves in different varieties.

Atomization Characteristics of a Double Impinging F-0-0-F Type Injector with Four Streams for Liquid Rockets

  • Kang, Shin-Jae;Rho, Byung-Joon;Oh, Je-Ha;Kwon, Ki-Chul
    • Journal of Mechanical Science and Technology
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    • v.14 no.4
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    • pp.466-476
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    • 2000
  • This paper presents atomization characteristics of a double impinging F -0-0- F type injector with four streams. A phase Doppler particle analyzer was employed to measure the droplet-size and water was used as the inert simulant liquid instead of reactive propellant liquids. The droplet mean diameter (SMD) and size distribution were measured to investigate the effects of the momentum ratio and pressure drop variations. This experimental results can be used during the preliminary design stage of a impinging stream type injector for liquid rockets.

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Atomization Characteristics of the High Speed Rotating Injection System with Single Column Orifice (단열식 오리피스를 적용한 고속회전 분무노즐의 미립화 특성)

  • Jang, Seong-Ho;Choi, Seong-Man
    • Journal of ILASS-Korea
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    • v.14 no.3
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    • pp.97-102
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    • 2009
  • The spray characteristics of the high speed rotating fuel injection system were studied. The five variants of rotating fuel nozzle were used by spray test. The diameter of single column injection orifices are varied from 1 mm, 2 mm, 3 mm, 4 mm and 5 mm. We constructed high speed rotating test rig and measured droplet size by PDPA (Phase Doppler Particle Analyzer) system. Also spray was visualized by using high speed camera. In the test results, we could understand that length of liquid column from the injection orifice is mainly controlled by the rotational speeds. SMD is decreased with increasing injection orifice diameter and rotational speeds. Furthermore, from the comparison to the theoritical calculation, we confirmed that SMD is influenced by the liquid film thickness which is formed inner surface of injection orifice.

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Development of Flow Rate Model of a Liquid Phase LPG Injector (액상 LPG 인젝터의 유량 모델 개발)

  • 조성우;민경덕
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.5
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    • pp.22-28
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    • 2003
  • Flash boiling mechanism in the injector interferes with fine fuel metering in a liquid phase LPG injection engine. This study presents a mathematical model to precisely predict an injection quantity. A calibration procedure of injection quantity, which is very prompt and precise in measuring, is developed using a gas analyzer. According to this procedure, injection quantity can be obtained under various fuel compositions, temperatures and injection pressures. The release pressure of liquid phase LPG is estimated based on these experimental data. Although the release pressure is much lower than the saturation pressure, it is linearly proportional to the saturation pressure.

DEVELOPMENT ON ENHANCED LEAKED FUEL RECIRCULATION DEVICE OF LPLi ENGINE TO SATISFY SULEV STANDARD

  • Myung, C.L.;Kwak, H.;Park, S.
    • International Journal of Automotive Technology
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    • v.7 no.4
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    • pp.407-413
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    • 2006
  • The liquefied petroleum gas(LPG), mixture of propane and butane, has the potential to reduce toxic hydrocarbon emissions and inhibit ozone formation due to its chemical composition. Conventional mixer systems, however, have problems in meeting the future lower emission standards because of the difficulty in controlling air-fuel ratio precisely according to mileage tar accumulation. Liquid Phase LPG injection(LPLi) system has several advantages in more precise fuel metering and higher engine performance than those of the conventional mixer type. On the other hands, leakage problem of LPLi system at the injector tip is a main obstacle for meeting more stringent future emission regulations because these phenomena might cause excessive amount of THC emission during cold and hot restart phase. The main focus of this paper is the development of a leaked fuel recirculation system, which can eliminate the leaked fuel at the intake system with the activated carbon canister. Leaked fuel level was evaluated by using a fast response THC analyzer and gas chromatography. The result shows that THC concentration during cold and hot restart stage decreases by over 60%, and recirculation system is an effective method to meet the SULEV standard of the LPLi engine.

Phase Doppler Measurements and Probability Density Functions in Liquid Fuel Spray (연료분무의 위상도플러 측정과 확률밀도함수의 도출)

  • 구자예
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.4
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    • pp.1039-1049
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    • 1994
  • The intermitternt and transient fuel spray have been investigated from the simultaneous measurement of droplet sizes and velocities by using Phase/Doppler Particle Analyzer(PDPA). Measurement have been done on the spray axis and at the edge of the spray near nozzle at various gas-to-liquid density ratios(.rho./sub g//.rho./sub l/) that ranges from those found in free atmospheric jets to conditions typical of diesel engines. Probability density distributions of the droplet size and velocity were obtained from raw data and mathematical probability density functions which can fit the experimental distribations were extracted using the principle of maximum likelihood. In the near nozzle region on the spray axis, droplet sizes ranged from the lower limit of the measurement system to the order of nozzle diameter for all (.rho./sub g/ /.rho./sub l/) and droplet sizes tended to be small on the spray edge. At the edge of spray, average droplet velocity peaked during needle opening and needle closing. The rms intensity is greatly incresed as the radial distance from the nozzle is increased. The probability density function which can best fit the physical breakage process such as breakup of fuel drops is exponecially decreasing log-hypebolic function with 4 parameters.

Factors Affecting Z-direction Penetration of PVAm Solution into Paper (PVAm 용액의 종이 두께 방향 침투에 영향하는 인자들)

  • Choi, Do-Chim;Won, Jong Myoung;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.104-111
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    • 2015
  • Factors influencing penetration of PVAm solution into paper during impregnation were investigated with ultrasonic Penetration Evenness Analyzer (PEA). Paper structure was varied by changing basis weight, freeness of pulp, calendering, and filler addition, and hydrophobicity of paper was varied by adding AKD. In addition, the viscosity of PVAm solution was varied by changing the concentration of PVAm solution. Important factors influencing penetration of PVAm solution into paper were found to be the pore structure and the hydrophobicity of paper, and the viscosity of PVAm solution. Pore structure of paper could be controlled by refining degree and filler addition and hydrophobicity of paper could be controlled by internal sizing. Denser structure of paper, higher hydrophobicity and higher liquid viscosity slowed down the penetration of PVAm solution into paper.

Analysis of Printed Image Depending on Mixing Ratios of Softwood and Hardwood fibers Using Image Analyzer and CLSM (화상분석기와 CLSM을 이용한 침.활엽수 섬유의 배합비에 따른 인쇄화상 분석)

  • 이장호;박종문
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.3
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    • pp.25-31
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    • 2002
  • The purpose of this study was to analyze how the fiber properties and mixing ratio of softwood and hardwood pulp affect on roundness of printed image. Softwood pulp and hardwood pulp were refined to 400 and 600ml CSF by Valley beater and handsheets of 70 g/$m^2$ basis weight were made at different mixing ratios of hardwood and softwood pulp. The roundness, dot area, and shape of the printed dot were measured by Image Analyzer. The depths and shapes of the acridine orange penetration into paper were measured by CLSM. With higher mixing ratio of hardwood pulp, the paper showed higher air-permeability and better formation, especially at lower freeness. The roundness of the printed image became better and the dot size became smaller when the amount of hardwood pulp increased. Penetration depth of acridine orange by CLSM became greater and roundness increased to real circle when the amount of hardwood pulp increased. It was thought that higher mixing ratio of hardwood fibers resulted in efficient penetration by better formation with uniform micro-pore distribution and it increased roundness. It was thought that fiber properties and mixing ratio affected the structure of paper and the shape of the printed dot. This study showed that the measurement of depth of the liquid penetration into paper without destruction and contact was feasible. Moreover, this method showed that the shape of the liquid penetration was measurable.

Analysis of the Spray Distribution Characterization of Impinging Jet Injectors for Liquid Rockets Using PLIF Technique (PLIF 기법을 이용한 액체로켓용 충돌분사 인젝터의 분무분포 특성 해석)

  • 정기훈;윤영빈;황상순
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.1
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    • pp.36-45
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    • 2000
  • Most researches for impinging jet spray have been focused on under-standing the breakup mechanism of a liquid sheet formed by the collision of jets and modeling the spray breakup using experimental data. For this reason, there have been few studies on the characteristics of the spatial spray distribution which affects significantly the combustion efficiency. Hence, we measured the radial distribution of fuel massflux using a like-doublet type injector. Instead of PDPA(Phase Doppler Particle Analyzer) which has been used only for the point measurement of the drop size of spray, PLIF(Planar Laser Induced Fluorescence) technique was developed lot the 2-D measurement of the massflux distribution of spray Indirect photography technique was also used to verify PLIF data.

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Spray Characteristics of Air-assisted Vortex Nozzle at Low Pressure Condition (공기보조식 와류 노즐의 저압 분무특성)

  • Kim, Woojin;Subedi, Bimal;Choi, Jang-Soo
    • Journal of ILASS-Korea
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    • v.20 no.2
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    • pp.82-87
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    • 2015
  • A nozzle with vortex generator was used to develop the low pressure nozzle with high atomization performance and the nozzle atomized the liquid by centrifugal shear forces. In order to analyze the atomization characteristics, a shadowgraphy method was used and the measurement of droplet size was performed by using laser diffraction analyzer. The liquid injection pressure was fixed as 0.03 bar which is very low pressure and the gas injection pressures were changed from 0 bar to 2.0 bar. As a result, the breakup was achieved at the air injection pressure of 0.25 bar and over. The nozzle with the orifice diameter of 0.4 mm and the orifice gap of 0.25 mm presented small droplet diameters under 50 at the air injection pressure of 0.75 bar.