• 한국대기환경학회지
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• 제30권5호
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• pp.461-476
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• 2014

Continuous Water-Soluble Organic Carbons (WSOC) by the Particle Into Liquid Sampler - Total Organic Carbon (PILS-TOC) analyzer were measured at the Seoul intensive monitoring site from June 17 through July 5 in 2014. In addition, the 24 hour integrated PM2.5 collected by Teflon and Quartz filters were analyzed for water soluble ions by Ion chromatography (IC), WSOC by TOC from water extracts, organic carbon (OC), elemental carbon (EC) by carbon analyzer using the thermal optical transmittance (TOT) method, and mass fragment ions (m/z) related to alkanes and PAHs (Poly Aromatic Hydrocarbons) by Gas Chromatography-Mass Spectrometer-Thermal Desorption (GC/MS-TD). Based on the statistical analysis, four different Carbonaceous Thermal Distributions (CTDs) from OCEC thermal-gram were identified. This study discusses the primary and secondary sources of WSOC based on the Classified CTD, organic mass fragments, and diurnal patterns of WSOC. The results provide knowledge regarding the origins of WSOC and their behaviors.

• 한국분무공학회지
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• 제10권3호
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• pp.1-8
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• 2005

The purpose of this study is to investigate the internal structure of the impinged diesel spray at various experimental conditions. To examine the effect of various factors on the development of a diesel spray impinging on the wall, experiments were conducted at the various Injection pressures, wall distances from the nozzle tip and angles of wall inclination. The PIV system consists of a double pulsed Nd:YAG laser was utilized to analyze the internal flow structure of impinged diesel sprays. The velocity fields from the PIV system were compared with the results measured by the phase Doppler particle analyzer(PDPA)system. The results show that internal flow pattern of the impinged spray was similar with the results from the PDPA system. The radial velocity of the impinged spray was increased with the increase in the injection pressure and near the nozzle-wall distance. The generation of vortex was also promoted with the Increase in angles of wall inclination.

• 한국분무공학회지
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• 제3권4호
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• pp.8-15
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• 1998

The spray characteristics of emulsified fuel of W/O type has been experimentally investigated. The mixture of light oil and water by using ultrasonic energy adding system is used as the emulsified fuel. The SMD of sprayed droplet of emulsified fuel is measured by using the particle size analyzer. Major parameters of the present experimental study are the volume fraction of water in emulsified fuel, $0\sim30%$ by 5%, injection pressure, $10kg_f/cm^2\sim18kg_f/cm^2$ by $2kg_f/cm^2$, and the measurement distance, $10\sim100mm$, between injection nozzle tip and analyzer beam. Compared with light oil, the SMD of emulsified fuel is larger gradually by increasing the volume fraction of water in emulsified fuel, heightening injection pressure and increasing the spray distance. Also, In considering the fact that the pattern of drop size distribution of emulsified fuel is alike that of light oil, the real time spray in coincidence with making emulsified fuel by adding ultrasonic energy can stabilize spray pattern without modificating the injection system used by now.

• 한국축산시설환경학회지
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• 제13권2호
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• pp.113-120
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• 2007

본 시험은 근적외선분광법을 이용한 돈분뇨 액비의 질소, 인산, 칼리, 수분 및 유기물의 분석 가능성을 구명하고, 이를 활용한 분석기의 개발을 목적으로 수행하였으며, 그 결과는 다음과 같다. 1. 돈분뇨 액비시료는 $400{\sim}2,500nm$ 대역의 근적외선을 시료에 투과하여 측정하였으며, 동일시료에 대한 습식분석 결과, N, $P_2O_5,\;K_2O$, 수분 및 유기물 함량은 각각 1,555mg/l, 302mg/l, 240mg/l, 98.8%, 0.53%로 조사되었다. 2. 근적외선 분광광도법을 이용한 분석에서 N, $P_2O_5,\;K_2O$, 수분 및 유기물에 대한 RSQ ($r^2$, R, Coefficient of determination)는 각각 0.9190, 0.9749, 0.5046, 0.9883 및 0.9777이었고 SEC(Standard Error of Calibration)는 2.1649, 0.5019, 1.9252, 0.1180 및 0.0789였다. 3. 액비에 대한 이화학적 습식분석과 NIR 흡수스펙트럼 측정결과를 비교 분석하여 돈 분뇨 액비에 포함된 질소, 인산, 칼리, 수분 및 유기물 함량을 실시간으로 분석하고 액비 성분량을 자동 계산할 수 있는 알고리즘을 도입한 액비분석 프로그램을 작성하였다. 4. 액비 성분분석 시작기는 근적외선(NIR : Near InfraRed)을 받아들여 실시간으로 액비성분의 흡수율을 측정하는 광검출장치(NIR Spectrometer), 근적외선 Light Source로부터 나오는 빛을 반사시키는 반사경, 액비성분 분석용 시료를 넣어 측정하는 Cell Mount, $400{\sim}2,500nm$ 대역의 가시광선-근적외선을 방출하는 Tungsten halogen lamp, NIR Spectrometer와 Tungsten halogen lamp로 전압을 입력시켜 주는 Power Supply Module 및 전체를 Black Anodizing한 외형으로 구성되었다. 5. 실험결과, 칼리를 제외한 액비내 모든 성분이 광을 흡수하는 강도는 성분의 농도에 비례하였으며 원시 스펙트럼의 중첩 제거 및 빛의 산란보정을 통해 액비의 질소, 인산성분, 수분 및 유기물 함량을 측정하는데 효과적으로 이용할 수 있을 것으로 사료되며, 분광분석법을 이용한 액비성분 분석기 개발이 완료되면 현장에서 신속하고 정확한 분석이 가능할 것으로 판단된다.

• 공업화학
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• 제26권4호
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• pp.445-451
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• 2015

주사슬에 메소젠기와 유연격자로써 옥타메틸렌기를 포함하고 있는 반 유연성 액정중합체가 용액 중축합반응에 의하여 합성되었다. 중합체의 메소젠기는 에스터와 케톤, 에터, 설파이드, 메틸렌, 설폰, 또는 아이소프로필리덴기들에 의해 결합된 4개의 방향족고리로 되어 있다. 본 논문에서는, 메소젠기의 가운데 연결기가 중합체의 물성에 미치는 영향에 대하여 고찰하였다. 합성된 중합체의 구조와 성질은 $^1H$-NMR, FT-IR, DSC, TGA, XRD, POM에 의하여 조사되었으며, 그 결과에 의하면, 굽은 구조의 연결기를 가지고 있는 중합체들은 낮은 열전이온도, 좁은 액정상 온도구간, 약한 액정성, 그리고 유기용매에 대한 좋은 용해성을 보여 주었고, 벌크한 연결기를 갖는 중합체들은 무정형 중합체로서 높은 유리전이온도($T_g$)를 나타내었다.

• 한국응용과학기술학회지
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• 제21권2호
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• pp.140-147
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• 2004

An aqueous solution of a commercial liquid synthetic detergent for kitchen use was photodecomposed in the presence of titanium dioxides powder under an atmosphere of air at room temperature. Titanium dioxides were prepared by sol-gel method from titanium iso-propoxide at different R ratio($H_2O$/titanium iso-propoxide) and calcined at $500^{\circ}C$. All titanium dioxides were characterized by XRD, BET surface area analyzer and UV-VIS spectrometer. The surface area of titanium dioxides prepared at R ratio=6 appeared higher volume about 20% than commercial $TiO_2$ catalysts. XRD patterns of titania particles were observed mixing phase together with rutile and anatase type. Titanium dioxides prepared by sol-gel method show higher activity about 6% than commercial $TiO_2$ catalysts on the photocatalytic degradation of a commercial liquid synthetic detergent for kitchen. The concentration of the detergent decreased to about 90% of its initial value at illumination times of 2 hour. Illumination for 30 minutes decreased the concentration of oxygen to about one-fifth of the initial value.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.202-206
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• 2009

고속회전 연료분사시스템의 분무특성을 연구하였다. 분무특성에 영향을 주는 직렬식 분무오리피스의 직경을 각각 1mm, 2mm, 3mm, 4mm, 5mm와 분무오리피스 수를 3개, 6개, 12개로 변화시켜가며 분무특성 연구를 수행하였다. PDPA 측정 시스템을 이용하여 분무입자의 크기와 속도, 분무분포 등을 측정하였고, 고속카메라를 이용하여 분무가시화를 수행하였다. 실험결과, 분무오리피스로부터 분출된 단일 액주의 길이는 회전속도에 의해 제어되며, 분무입자의 크기(SMD)는 분무오리피스의 직경과 수가 증가함에 따라 작아지는 경향을 보였다. 결국 분무입자의 크기를 제어하는 기본 메커니즘은 분무 오리피스내의 액막의 두께에 의해 결정됨을 알 수 있었다.

• Journal of Mechanical Science and Technology
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• 제17권12호
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• pp.2053-2065
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• 2003

The current trend in automotive finishing industry is to use more electrostatic rotating bell (ESRB) need space to their higher transfer efficiency. The flow physics related with the transfer efficiency is strongly influenced by operating parameters. In order to improve their high transfer efficiency without compromising the coating quality, a better understanding is necessary to the ESRB application of metallic basecoat painting for the automobile exterior. This paper presents the results from experimental investigation of the ESRB spray to apply water-borne painting. The visualization, the droplet size, and velocity measurements of the spray flow were conducted under the operating conditions such as liquid flow rate, shaping airflow rate, bell rotational speed, and electrostatic voltage setting. The optical techniques used in here were a microscopic and light sheet visualization by a copper vapor laser, and a phase Doppler particle analyzer (PDPA) system. Water was used as paint surrogate for simplicity. The results show that the bell rotating speed is the most important influencing parameter for atomization processes. Liquid flow rate and shaping airflow rate significantly influence the spray structure. Based on the microscopic visualization, the atomization process occurs in ligament breakup mode, which is one of three atomization modes in rotating atomizer. In the spray transport zone, droplets tend to distribute according to size with the larger drops on the outer periphery of spray. In addition, the results of present study provide detailed information on the paint spray structure and transfer processes.

• 한국광학회지
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• 제15권6호
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• pp.527-530
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• 2004

회전검광자방식 편광분석방법을 이용하여 LCD (liquid crystal display) 편광판에 부착되어 있는 보상판의 느린축이 편광판의 투과축 대비 틀어진 각도를 0.1도 이내로 정밀하게 측정할 수 있는 방법을 제안하였다. 본 방법을 이용하면 보상판을 LCD 편광판과 접합하는 공정에서 발생하는 광축정렬의 오차를 줄일 수 있고 궁극적으로 LCD의 화질을 일정하게 유지, 관리하는데 기여할 수 있을 것으로 기대된다.

• 한국분무공학회지
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• 제20권1호
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• pp.35-42
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• 2015

This study is to investigate the spray behavior of DME-LPG blended fuels in common rail injection system for diesel engines. The visualization experiment was performed to analyze the macroscopic spray behavior of test fuels. In addition, the experiment using BOS(Background Oriented Schlieren) method is performed to compare liquid phase and gas phase. The test fuels are injected in high pressure chamber. The ambient pressure of high pressure chamber was formed by nitrogen gas. Spray tip penetration, spray cone angle and spray area were measured using high speed camera. SMD(Sauter Mean Diameter) and spray particle velocity were measured using the PDPA(Phase Doppler Particle Analyzer) system to analyze the microscopic properties of test fuels. The results of this experiment showed that spray tip penetration, spray cone angle and spray area of DME-LPG fuels are similar to those of DME fuel. When compared to results of experiment using BOS, significant differences of spray tip penetrations, spray cone angle and spray area are showed because of gas phase. The results of experiment using BOS method showed higher values. SMD of DME-LPG blended fuels is smaller than that of DME fuel. Velocity of DME-LPG blended fuels is faster than that of DME fuel.