• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2008.10a
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• pp.215-217
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• 2008

Crystallization behavior of the bulk metallic glass (BMG) during compression and tension was studied in the supercooled liquid region (SLR). Rod samples of the BMG alloy were produced by consolidating gas atomized powders of $Cu_{54}Zr_{22}Ti_{18}Ni_6$ using spark plasma sintering. The crystallization behavior in these samples was examined by tackling changes in thermal property during heating the samples in DSC. The present BMG alloy was firstly decomposed and then crystallized during annealing in the SLR. The phase decomposition from the original amorphous phase was retarded by the compressive stress, while it was accelerated by the tensile stress.

• Journal of Korea Foundry Society
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• v.22 no.5
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• pp.245-251
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• 2002

Cast AZ91 and extruded AM50 alloys were isothermally heated as solid/liquid coexistent temperatures, and semi-solid formed into sheets. Mold filling ability of semi-solid slurry with different liquid fractions was investigated in relation to process variables such as injection speed and mold temperature. Relatively uniform distribution of solid particle size and liquid fraction were observed throughout the semi-solid formed sheet. AZ91 alloy sheets were also manufactured by conventional die casting and compared with the semi-solid formed. It was found that the surface was more smooth and the dimensional accuracy was higher in case of the semi-solid formed.

• Journal of Korea Foundry Society
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• v.9 no.1
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• pp.73-79
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• 1989

Microstructural characteristics of Al-3.63wt.%Pb hyper-monotectic alloy rapidly-solidified by melt spinning were examined. Possibility of forming a planar liquid -solid interface during rapid solidification of this alloy was also considered with a morphological stability theory, and a mechanism of forming banded structure observed at the bottom parts of melt-spinned specimens was considered as well. Application of the absolute stability criterion predicts the liquid-solid interface of the primary aluminium phase to be able to maintain a planar interface during the early stage of rapid solidification. Formation of banded structure was supposed to be resulted from the release of latent heat during solidification, which affect the stability of a planar liquid-solid interface.

• Journal of Welding and Joining
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• v.18 no.5
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• pp.90-97
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• 2000

Effect of alloy elements on joinability of insert metal for liquid phase diffusion bonding of heat resistant alloys was investigated in this study. Also, optimum chemical composition of insert metal was explained using interpolation method. The insert metals utilized was commercial Ni-base amorphous foils and newly developed Ni-base filler metals with B, Si and Cr in this study. Melting point and critical interlayer width(CIW) decreased with increasing additional amount of B, Si and Cr, melting point lowering element of the insert metal. Optimized chemical composition of insert metals could be estimated by interpolation method. The optimum amount of B, Si, Cr addition into the insert metal were found to be about 3%, 4% and 3%, respectively. The measured characteristic values, melting point, microhardness in the bonded interlayer and CIW of the insert metals were the almost identical to ones of the calculated results by interpolation method.

• Journal of the Korean Electrochemical Society
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• v.18 no.3
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• pp.102-106
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• 2015

The performance of Li-B alloy as anode for molten salt electrolysis was firstly investigated. The crystalline phase of the prepared Li-B alloy was identified as $Li_7B_6$. The potential profile of Li-B alloy anode was monitored during the electrodeposition of $Nd^{3+}$ onto an LCC (liquid cadmium cathode) in molten LiCl-KCl salt at $500^{\circ}C$. The potential of Li-B alloy was increased from -2.0 V to -1.4 V vs. Ag/AgCl by increasing the applied current from 10 to $50mA{\cdot}cm^{-2}$. It was found that not only the anodic dissolution of Li to $Li^+$ but also the dissolution of the atomic lithium ($Li^0$) into the LiCl-KCl eutectic salt was observed, following the concomitant reduction of $Nd^{3+}$ by the $Li^0$ in Li-B alloy. It was expected that the direct reduction could be restrained by maintaining the anode potential higher that the deposition potential of neodymium.

• Journal of Korea Foundry Society
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• v.13 no.3
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• pp.248-258
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• 1993

A semi-solid alloy in which solid and liquid phase are co-existing is obtained by stirring of A17075 molten metal. A semi-solid alloy is dependent on the corresponding temperature within the solid-liquid range, and the process parameters should be controlled accurately to obtain the homogeneous semisolid alloy. The fabrication possibility of fiber-reinforced aluminum alloy containing $Al_2O_3$ short fibers with vigorous agitation of short fibers were obtained by control of stirring time, solid fraction and impeller speed in extrusion billet fabrication processes. The microstructure to extrusion billet fabricated by low pressure casting was investigated for fiber dispersion state. The relationship between the extrustion force and velocity at hot extrustion, the flow strain and extrusion ratio were theoretically described. The surface defects with lubricants and without lubricant after hot extrusion were investigated. The composites materials after hot extrusion were measured by vickers hardness with extrusion ratio. It has become clear that the secondary working such as hot extrusion was very useful to obtained improved the mechanical properties of metal matrix composites.

• Journal of Korea Foundry Society
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• v.25 no.1
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• pp.30-35
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• 2005

The structures and mechanical property of the unidirectionally solidified Al-Co eutectic alloy were investigated. Al-Co eutectic alloy was unidirectionally solidified with growth rates(R) between I cm/hr and 10 cm/hr in the induction furnace maintaining the thermal gradient (G) at solid-liquid interface, $32^{\circ}C$/cm. The eutectic microstructure was varied with the growth condition(G/R ratio). When the G/R ratio was larger than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a lamellar structure was formed, But the G/R ratio was smaller than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a colony structure was formed. It was found that the interlamellar spacing(${\lambda}$) was dependent on the growth rate(R) with the relationship, ${\lambda}^{2}{\cdot}R=constant$. The microhardness of this eutectic alloy increased with increase in the growth rate.

• Korean Journal of Materials Research
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• v.13 no.9
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• pp.619-624
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• 2003

This paper describes a method to control Mn and Fe contents in recycled AZ91D ingots, based on the mutual solubility of Mn and Fe in AZ91 alloy melts. For this purpose, Fe solubility with the change of Mn content and temperature was investigated in the homogenized and re-precipitated liquid AZ91 alloy. The increase of the amount of Mn added to the melt resulted in the decrease of Fe content. The data obtained in this study was adopted to the pilot plant for recycling of the scrap. As a result, Mn and Fe contents measured in the recycled ingot were in good agreement with ASTM B93 standard.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.577-582
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• 2002

The solidification cracking susceptibilities of AI-Mg-Si alloy laser welds were assessed using the self-restraint tapered specimen crack test. The cracking susceptibility of 6061 and 6082 Al-Mg-Si alloy laser welds was substantially reduced when the filler wire containing high Si such as Al-12 wt.% Si (4047A) was used. The amount of eutectic was observed to affect the solidification cracking of Al-Mg-Si alloy laser welds. Abundant eutectic seems to heal the cracking and reduces the cracking susceptibility, while an initial increase in eutectic liquid leads to the increased cracking tendency.

• Journal of Powder Materials
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• v.3 no.3
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• pp.196-200
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• 1996

The dispersion of WC grains Into the interior of an eutectic liquid has been studied by superimposing the eutectic WC-85wt.%Co liquid on the top surface of presintered WC-l0wt.%Co alloy compacts. The heavy WC grains diffused into the interior of liquid from the WC-l0wt.%Co compacts. According to increasing the treating temperatures and times, the dispersion distance from WC-l0wt.%Co substrates increased. The fine WC grains diffused into the liquid faster than the coarse WC grains. The high microstructural stability of WC-Co alloys having the heavier WC grains dispersed in a lighter Co-rich liquid was attributed to Brownian motion of WC grains in liquid. The motion of WC grains in the liquid appears to be same with the colloid(the disperse phase) in a dispersing medium. The dihedral angle of 0 degree of WC-Co at. toy seems one of key parameters, which enables the WC-Co alloys to have high structural stability without settling the WC grains during liquid phase sintering.