• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 1999.04a
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• pp.5-5
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• 1999

The Principal deficiency of the existing notion about the sintering-mixtures consists in the fact that almost no attention is focused on the Phenomenon of alloy formation during sintering, its connection with dimensional changes of powder bodies, and no correct ideas on the driving force for the sintering process in the stage of establishing chemical equilibrium in a system are available as well. Another disadvantage of the classical sintering theory is an erroneous conception on the dissolution mechanism of solid in liquid. The two-particle model widely used in the literature to describe the sintering phenomenon in solid state disregards the nature of the neighbouring surrounding particles, the presence of pores between them, and the rise of so called arch effect. In this presentation, new basic scientific principles of the driving forces for the sintering process of a two-component powder body, of a diffusion mechanism of the interaction between solid and liquid phases, of stresses and deformation arising in the diffusion zone have been developed. The major driving force for sintering the mixture from components capable of forming solid solutions and intermetallic compounds is attributed to the alloy formation rather than the reduction of the free surface area until the chemical equilibrium is achieved in a system. The lecture considers a multiparticle model of the mixed powder-body and the nature of its volume changes during solid-state and liquid-phase sintering. It explains the discovered S-and V-type concentration dependencies of the change in the compact volume during solid-state sintering. It is supposed in the literature that the dissolution of solid in liquid is realised due to the removal of atoms from the surface of the solid phase into the melt and then their diffusicn transfer from the solid-liquid interface into the bulk of liquid. It has been shown in our experimental studies that the mechanism of the interaction between two components, one of them being liquid, consist in diffusion of the solvent atoms from the liquid into the solid phase until the concentration of solid solutions or an intermetallic compound in the surface layer enables them to pass into the liquid by means of melting. The lecture discusses peculimities of liquid phase formation in systems with intermediate compounds and the role of the liquid phase in bringing about the exothermic effect. At the frist stage of liquid phase sintering the diffusion of atoms from the melt into the solid causes the powder body to grow. At the second stage the diminution of particles in size as a result of their dissolution in the liquid draws their centres closer to each other and makes the compact to shrink Analytical equations were derived to describe quantitatively the porosity and volume changes of compacts as a result of alloy formation during liquid phase sinteIing. Selection criteria for an additive, its concentration and the temperature regime of sintering to control the density the structure of sintered alloys are given.

• Journal of Korea Foundry Society
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• v.33 no.1
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• pp.22-31
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• 2013

In order to develop an aluminum alloy, that can combine high thermal conductivity and good castability and anodizability, aluminum alloys with low Si content, such as Al-(0.5~1.5)Mg-1Fe-0.5Si and Al-(1.0~1.5)Si-1Fe-1Zn, were designed. The developed aluminum alloys exhibited 170~190% thermal conductivity (160~180 W/mK), 60~85% fluidity, and equal or higher ultimate tensile strength compared with those of the ADC12 alloy. In each developed alloy system, the thermal conductivity decreased and the strength increased with the increment of Mg and Si, which are the significant alloying elements. The fluidity was in reverse proportion to the Mg content and in proportion to the Si content. The Al-(0.5~1.5)Mg-1Fe-0.5Si alloys exhibited better fluidity in thick-wall castings, while the Al-(1.0~1.5)Si-1Fe-1Zn alloys were better in thin-wall castability due to their lower surface energies. The fluidity behavior was complexly affected by the heat release for the solidification, viscosity, solidification range, and the type, quantity, and formation juncture of the main secondary phase.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.23 no.2
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• pp.152-156
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• 2014

Lightweight materials such as aluminum and magnesium have recently received much attention in the automotive industries because of environmental and fuel-efficiency concerns. Using the powder metallurgy (PM) process for these materials creates significant opportunities for the cost-effective manufacture of lightweight automotive parts. In the present study, an Al-Cu-Mg alloy was fabricated using conventional PM processes. Primarily, the effects of the alloying elements on the sintering characteristics and mechanical behavior after heat treatment were investigated. A microstructural analysis was performed using an optical microscope and a scanning electron microscope to investigate the behavior of liquid phase sintering, including the formation of precipitates. The dependence of the mechanical behavior on the alloying elements was evaluated based on the transverse rupture strength.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2000.04a
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• pp.81-86
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• 2000

To evaluate the possibility of the partial melting soldering. wettability of partial melted solders was measured using wetting balance. Off eutectic Sn-Pb allows are wettable in their partial melting zone. Especially, Pb rich alloys showed excellent wettability while wettability of Sn rich alloys were adequate or poor. It is found that wettability increases over $200^{\circ}C$ regardless of composition liquid fraction and phases of the original alloy Sn-7Ag alloy showed good wettability in their partial melting zone, while Sn-65Bi alloy was non-wettable under their melting points.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.1037-1038
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• 2006

The increasing demand of PM parts for automobile and aerospace applications has caused a strong development of the aluminium based metal matrix composites (MMCs).Aluminium alloys are one of most widely used materials as matrix in MMCs, both in research and development as well as in industrial applications. In the present work, the influence of the ceramic reinforcement addition to a 2xxx series aluminium alloy is studied. Several percentages of TiCN have been added to the Al-Cu alloy using PM techniques, in order to analyze its influence on the liquid phase sintering process and on the final properties of the material.

• Applied Chemistry for Engineering
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• v.8 no.1
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• pp.49-58
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• 1997

LCP/PA alloy was prepared by blending poly(${\varepsilon}-caprolactam$) (PA) with liquid crystal polyester, Vectra (LCP) having high elasticity and strength. The alloy prepared amorphous PA with more than 10 parts of thermotropic LCP had poor compatibility. To increase the compatibility of the alloy, compatibilizing agent, poly(glycinylmaleimide-co-methylmetacrylate)[poly(GMI-co-MMA)] copolymer was prepared by copolymerizing N-glycinylmaleimide(GMI) with methylmetacrylate(MMA). And then, it was blended with LCP and PA to produce LCP/PA alloy having an excellent compatibility. The compatibility characteristics of the alloy prepared from LCP and PA using the poly(GMI-co-MMA) was determined by measuring the thermal characteristics of glass transition temperature of nematic LCP, and rheological properties, and also high rate impact and flexual characteristics of the alloy were determined.

• Journal of Korea Foundry Society
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• v.23 no.5
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• pp.268-275
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• 2003

The mechanism of the hydrogen gas pore formation was investigated in Lost Foam Casting of Al-alloy by reduced pressure test and real casting. The hydrogen gas pick-up was affected by the formed gas during the decomposition of polystyrene in addition to the liquid product. It depended on pouring temperature and a proper temperature of metal front gave the minimum hydrogen pick-up. At a low pouring temperature, the hydrogen went into the melt mainly from entrapped liquid product of polystyrene but pores were formed from the gas as well as the liquid product at a high pouring temperature. The mold flask evacuation down to 710torr decreased the gas porosity down by around 0.4% vol%. The entrapped decomposition product of polystyrene in the melt was observed through the visualization of filling behavior of Al alloy-melt with the high speed camera.

• Korean Journal of Materials Research
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• v.17 no.4
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• pp.192-197
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• 2007

The effects of immersion time in the liquid nitrogen on the behavior of aluminum alloys used for the hydrogen storage tank of auto-mobile at cryogenic temperature were investigated. With increasing immersion time in the liquid nitrogen, the elongation of AI 5083 alloy at cryogenic temperature decreased because of non-uniform fracture of precipitates on the grain boundary, and the serration also occurred because of discontinuous slip due to rapid decreasing of the specific heat. The mechanical properties of AI 6061 alloy at cryogenic temperature were characterized by uniformed yield strength, tensile strength and elongation regardless of the immersion time in the liquid nitrogen. These mechanical properties of aluminum alloys at cryogenic temperature were interpreted by the strength of grain boundary and the slip deformation behavior.

• Structural Engineering and Mechanics
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• v.81 no.6
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• pp.691-703
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• 2022

To obtain the seismic response of lead-cored rubber, shape memory alloy (SMA)-rubber isolation Plate-shell Integrated Concrete Liquid-Storage Structure (PSICLSS), based on a PSICLSS in a water treatment plant, built a scale experimental model, and a shaking table test was conducted. Discussed the seismic responses of rubber isolation, SMA-rubber isolation PSICLSS. Combined with numerical model analysis, the vibration characteristics of rubber isolation PSICLSS are studied. The results showed that the acceleration, liquid sloshing height, hydrodynamic pressure of rubber and SMA-rubber isolation PSICLSS are amplified when the frequency of seismic excitation is close to the main frequency of the isolation PSICLSS. The earthquake causes a significant leakage of liquid, at the same time, the external liquid sloshing height is significantly higher than internal liquid sloshing height. Numerical analysis showed that the low-frequency acceleration excitation causes a more significant dynamic response of PSICLSS. The sinusoidal excitation with first-order sloshing frequency of internal liquid causes a more significant sloshing height of the internal liquid, but has little effect on the structural principal stresses. The sinusoidal excitation with first-order sloshing frequency of external liquid causes the most enormous structural principal stress, and a more significant external liquid sloshing height. In particular, the principal stress of PSICLSSS with long isolation period will be significantly enlarged. Therefore, the stiffness of the isolation layer should be properly adjusted in the design of rubber and SMA-rubber isolation PSICLSS.

• Journal of Powder Materials
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• v.29 no.6
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• pp.459-467
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• 2022

Soft magnetic powder materials are used throughout industries such as motors and power converters. When manufacturing Fe-based soft magnetic composites, the size and shape of the soft magnetic powder and the microstructure in the powder are closely related to the magnetic properties. In this study, Fe-Si-Al-P alloy powders were manufactured using various manufacturing process parameter sets, and the process parameters of the vacuum induction melt gas atomization process were set as melt temperature, atomization gas pressure, and gas flow rate. Process variable data that records are converted into 6 types of data for each powder recovery section. Process variable data that recorded minute changes were converted into 6 types of data and used as input variables. As output variables, a total of 6 types were designated by measuring the particle size, flowability, apparent density, and sphericity of the manufactured powders according to the process variable conditions. The sensitivity of the input and output variables was analyzed through the Pearson correlation coefficient, and a total of 6 powder characteristics were analyzed by artificial neural network model. The prediction results were compared with the results through linear regression analysis and response surface methodology, respectively.