• Title/Summary/Keyword: linearization of inhibition model

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Estimation of Nitrite Concentration in the Biological Nitritation Process Using Enzymatic Inhibition Kinetics

  • GIL, KYUNG-IK;EUI-SO CHOI
    • Journal of Microbiology and Biotechnology
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    • v.12 no.3
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    • pp.377-381
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    • 2002
  • Recently, interests to remove nitrogen in the nitritation process have increased because of its economical advantages, since it could be a short-cut process to save both oxygen for nitrification and carbon for denitrification compared to a typical nitrification. However, the kinetics related with the nitritation process has not yet been fully understood. Furthermore, many useful models which have been successfully used for wastewater treatment processes cannot be used to estimate effluent nitrite concentration for evaluating performance of the nitritation process, since the process rate equations and population of microorganisms for nitrogen removal in these models have been set up only for the condition of full nitrification. Therefore, the present study was conducted to estimate an effluent nitrite concentration in the nitritation process with a concept of enzymatic inhibition kinetics based on long-term laboratory experiments. Using a nonlinear least squares regression method, kinetic parameters were accurately determined. By setting up a process rate equation along with a mass balance equation of the nitrite-oxidizing step, an effluent nitrite concentration in the nitritation process was then successfully estimated.

Development of the pH Inhibition Model Adapting Pseudo Toxic Concentration (CPT) Concept for Activated Sludge Process (의사독성농도 (CPT) 개념을 도입한 활성슬러지 공정 pH 저해 모델 개발)

  • Ko, Joo-Hyung;Jang, Won-Ho;Im, Jeong-Hoon;Woo, Hae-Jin;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2037-2046
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    • 2000
  • It has been reported that the inhibition effect of pH on activated sludge follows noncompetitive inhibition kinetics. However. the noncompetitive inhibition kinetic equation can not be directly applied to pH inhibition because of the difficulty in quantification of pH in terms of inhibitor concentration. So, many empirical equations have been developed to describe the pH inhibition effect especially for acidic condition. In this research. the pseudo toxic concentration ($C_{PT}$) concept model to quantify pH inhibition effect on activated sludge was proposed and compared to other existing models. The $C_{PT}$ concept model can explain the reduction of the maximum specific growth rate (${\mu}_{max}$) caused by the pH inhibition more accurately than any other models, at a wide range of pH. The only model parameter. $K_I$ can be easily estimated by Lineweaver-Burk linearization method.

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