• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.603-608
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• 2008

A simple equation to find a optimum speed of desiccant rotor is presented in this theoretical study. Usually the determination of optimum speed of desiccant rotor requires tedious and lengthy procedures by solving governing differential equations with many complicated parameters. The determining equation of optimal rotating speed is derivated from governing differential equations with three linearization assumptions, which simplify temperature profile linear along the desiccant rotor depth, psychrometric chart within a proper range, and relative humidity-sorption capacity relation. This study shows that the dominant parameters of optimal rotating speed of desiccant rotor are NTU, flow velocity, desiccant rotor depth, and temperature different between dehumidification and regeneration. The comparison shows the good agreement between complicated calculation results and simple theoretical equation prediction.

• 설비공학논문집
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• 제22권9호
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• pp.620-627
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• 2010

This paper presents a feasibility study of a fresh air load reduction system by using an underground double floor space. The fresh air is introduced into the double slab space and passes through the opening bored into the footing beam. The air is cooled by the heat exchange with the inside surface of the double slab space in summer, and heated in winter. This system not only reduces sensible heat load of the fresh air by heat exchange with earth but also reduces latent heat load of the fresh air by ad/de-sorption of underground double slab concrete. In this paper, we investigated the correlation between outdoor air temperature and outlet air temperature in the system. In conclusion, from the results of the high correlation we proposed a equation of regression for the outlet air temperature in the system by using linear regression analysis.

• 한국토양비료학회지
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• 제31권3호
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• pp.266-270
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• 1998

밭토양의 수용성 인산농도의 예측방법을 개발 할 목적으로 토양특성이 다양한 40개 토양에 대하여 0.01 M $CaC1_2-P$와 유효인산 및 인산흡수능 등과의 관계를 검토한 결과, 직선회귀관계에서 0.01 M $CaC1_2-P$와의 결정계수는 유효인산이 $0.479^{**}$, 부영양화인산이 $0.281^{**}$이었으며 토양의 인산흡수능중에는 인산흡수량이 $-0.465^{**}$, 인산흡수계수가 -$-0.056^{NS}$이었다. 0.01 M $CaC1_2-P$와 독립 변수인 유효인산과 인산흡수능을 함께 고려한 2차 다항 회귀관계로 보면 결정계수가 $0.745^{**}$로 향상되었고 독립변수로 유효인산과 인산흡수계수를 함께 고려하면 결정계수가 $0.566^{**}$ 이었으며 유효인산/인산흡수량의비를 독립변수로 하여 만든 지수함수식(指數函數式)에서는 결정계수가 0.818로 크게 향상되었다.

• 한국결정학회지
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• 제4권2호
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• pp.54-62
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• 1993

Cd2+ 이온으로 이온교환된 제올라이트 A를 650℃에서 2 ×10-6 T orr의 진공하에서 탈수한 구조 (a:l2.189(2)A)와 이 결정에 요오드가 흡착된 구조 (a:l2.168(2) A)를 21℃에서 입방공간군 Pm3m를 사용하여 단결정 X-선회절법으로 해석하고 정밀화하였다. 탈수한 가In-A의 구조 는 Full-rmoix 최소자승법 정밀화 계산에서 I > 3σ(I)인 186개의 독립반사를 사용하여 최종오차인자를 Rl:0.057, Ra:0.003 까지 정밀화 계산하였고, 이 결정을 요오드로 흡착시킨 구조는 181 개의 독립 반사를 사용하려 Rl = 0.082, R2 : 0.085가지 정밀화시켰다. 두 결정에서 단위세포당 6개의 Cd2+ 이온은 서로 다른 2개의 3회 회전축상에 위치 하고 있었다. 요오드가 흡착된 구조에서 4개의 Cd2+ 이온 은 0(3)의 (111) 평면에서 큰 동공쪽으로 약 0.68(1) A 들어간 I3- 이온이 결합하고 있고 나머지 2개의 Cd2+ 이온은 0(3)의 (111) 평면에서 소다라이트 동공 깊숙히 약 0.68(1) A 들어간 자리에 위치 하고 있다. 단위세포당 약 4개의 I이온이 큰 동공내에 흡착되었다. 각각의 I-는 6-링 Cd2+와 골조의 8-링 산소에 다리를 놓고 있으며 0(1)-I(1)-I(2) 각도는 172(1)˚로써 거의 선형이고 약한 전 하이동 착물을 골조의 8-링 산소와 이루고 있다. 큰 동공 내에 존재하는 I이온은 부분적으로 탈수된 효In-A에서 요오드 증기와 물분자가 반응하여 H+이온과 I-이온이 생성된 후 다시 I이온과 l2 분자와 반응하여 생성되었을 것이다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제9권4호
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• pp.24-31
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• 2004

유류오염토양을 건설재료로 재활용할 수 있는 방안으로써 Cold Mix Asphalt(CMA) 처리를 제시하였고 디젤 및 디젤화합물로 오염된 토양의 CMA 처리특성을 고찰하였다. 양이온성 또는 음이온성 또는 비이온성 계면활성제를 함유하고 있는 5가지 아스팔트 이멀젼을 이용해서 디젤 오염토양의 처리능을 고찰한 결과 첨가된 계면활성제의 차이에 의한 성능의 차이는 확연하게 드러나지 않았으나, 토양과의 친밀성 및 흡착계수를 고려하여 Lauryl Dimethyl Benzyl Ammonium Chloride (LDBAC)를 포함한 이멀젼을 오염토양 처리에 적합한 아스팔트 이멀젼으로 선정하였다. 아스팔트 이멀젼 LDBAC에 의한 세가지 디젤화합물의 처리능은 docosane, pentadecane, undecane의 순으로 높은 것으로 나타났다. 아스팔트 이멀젼 LDBAC를 이용하여 CMA처리된 토양에 대한 용출실험결과 비교적 고농도인 10,000 mg/kg 의 디젤로 오염된 토양도 CMA처리 가능함을 확인하였다. 공시체로부터 디젤의 용출은 초기 4일까지는 확산에 의한 거동을 보여 주었고 그 이후로는 용출속도가 감소하여 총 용출가능양의 $50\%$ 이상이 유출되었다고 판단되는 depletion의 거동을 보여 주었다. CMA처리된 오염토양으로부터 3가지 디젤화합물의 총용출량은 undecane > pentadecane > docosane의 순서로 높은 것으로 나타났으며, pentadecane의 경우 CMA 처리시 양생속도가 상대적으로 더딘 것으로 밝혀졌다.

• 한국의류학회지
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• 제24권3호
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• pp.422-428
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• 2000

At present, analytical methods available for determining the amount of cationic surfactants(DSDMAC) on the fabrics are spectrophotometric method based on formation and extraction of the colored ion pair with anionic dye, radiochemical analysis and HPLC analysis. This study presents new analytical methods based on the formation of cationic surfactant(DSDMAC)-disulfine blue complex on the cotton fabric. Test methods for determining the amount of DSDMAC-disulfine blue complex on the cotton fabrics are measuring the reflectance of the colored fabric and the absorbance of the methanol solution of DSDMAC-disulfine blue complex extracted from dyed cotton fabric. Linear relationships between the K/S value of the fabric treated with DSDMAC followed by disulfine blue and the amount of DSDMAC sorbed by cotton fabric were obtained. Thus, the amount of DSDMAC sorbed by cotton fabric can be determined by K/S value of the fabric. DSDMAC-disulfine blue complex on the cotton fabric was extracted with methanol. The amount of DSDMAC sorbed by cotton fabric was estimated by measuring the absorbance of the methanol solution extracted from dyed cotton fabric.

• Advances in environmental research
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• 제7권1호
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• pp.53-71
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• 2018

Waste glass disposal causes environmental problems in the cities. To find a suitable green environmental solution for this problem low cost adsorbent in this study was prepared from waste glass. An effective new green adsorbent was synthesized by hydrothermal treatment of waste glass (WG), followed by acidic activation of its surface by HCl (WGP). The prepared adsorbent was characterized by scanning electron microscopy (SEM), X-ray fluorescence (XRF), X-ray diffraction (XRD), and BET surface measurement. The developed adsorbent was used for the removal of heavy metals (Cd, Cu, Fe, Pb and Zn) from well water. Batch experiments were conducted to test the ability of the prepared adsorbent for the removal of Cd, Cu, Fe, Pb and Zn from well water. The experiments of the heavy metals adsorption by adsorbent (WGP) were performed at different metal ion concentrations, solution pH, adsorbent dosage and contact time. The Langmuir and Freundlich adsorption isotherms and kinetic models were used to verify the adsorption performance. The results indicated high removal efficiencies (99-100%) for all the studied heavy metals at pH 7 at constant contact time of 2 h. The data obtained from adsorption isotherms of metal ions at different time fitted well to linear form of the Langmuir sorption equation, and pseudo-second-order kinetic model. Application of the resulted conditions on well water demonstrated that the modified waste glass adsorbent successfully adsorbed heavy metals (Cd, Cu, Fe, Pb and Zn) from well water.

• Environmental Engineering Research
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• 제19권1호
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• pp.107-113
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• 2014

Small sized manganese dioxide particles are immobilized onto the surface of sand by the wet impregnation process. The surface morphology of the solid, i.e., immobilized manganese dioxide natural sand (IMNS) is performed by taking scanning electron microscope images and characterized by the X-ray diffraction data. The specific surface area of the solid is obtained, which shows a significant increase in the specific surface area obtained by the immobilization of manganese dioxide. The $pH_{PZC}$ (point of zero charge) is found to be 6.28. Further, the IMNS is assessed in the removal of As(III) and As(V) pollutants from aqueous solutions under the batch and column operations. Batch reactor experiments are conducted for various physicochemical parametric studies, viz. the effect of sorptive pH (pH 2.0-10.0), concentration (1.0-25.0 mg/L), and background electrolyte concentrations (0.0001-0.1 mol/L $NaNO_3$). Further, column experiments are conducted to obtain the efficiency of IMNS under dynamic conditions. The breakthrough data obtained by the column experiments are employed in non-linear fitting to the Thomas equation, so as to estimate the loading capacity of the column for As(III) and As(V).

• Nuclear Engineering and Technology
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• 제34권3호
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• pp.218-231
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• 2002

Using a three-dimensional numerical code, B3R developed for nuclide transport of an arbitrary length of decay chain in the buffer between the canister and adjacent rock in a high- level radioactive waste repository by adopting a finite difference method utilizing the control- volume scheme, some illustrative calculations have been done. A linear sorption isotherm, nuclide transport due to diffusion in the buffer and the rock matrix, and advection and dispersion along thin rigid parallel fractures existing in a saturated porous rock matrix as well as diffusion through the fracture wall into the matrix is assumed. In such kind of repository, buffer and rock matrix are known to be important physico-chemical harriers in nuclide retardation. To show effects of buffer and rock matrix on nuclide transport in HLW repository and also to demonstrate usefulness of B3R, several cases of breakthrough curves as well as three- dimensional plots of concentration isopleths associated with these two barriers are introduced for a typical case of decay chain of $^{234}$ Ulongrightarrow$^{230}$ Thlongrightarrow$^{226}$ Ra, which is the most important chain as far as the human environment is concerned.

• Food Science and Biotechnology
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• 제16권1호
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• pp.154-158
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• 2007

Adsorption isotherms for chaga mushroom powder as influenced by particle size were investigated using a gravimetric technique. Samples were equilibrated in desiccators containing sulfuric acid solutions of known water activity (0.11-0.93), then placed in temperature-controlled chambers for approximately ten days. Equilibrium moisture content (EMC) of chaga mushroom powder increased with water activity in all samples. EMC was slightly greater in the samples comprised of smaller particle size, however there was no marked difference in appearance between the three samples. The chaga mushroom powder exhibited Type II behavior. When the BET model was used to determine mean monolayer values, 0.077, 0.077, and 0.070 $H_2O/dry$ solid was observed for <250, 250-425, and $425-850\;{\mu}m$ sized samples, respectively, however mean monolayer values were 0.121, 0.111, and 0.101 $H_2O/dry$ solid, respectively, when the GAB model was used. The experimental EMC values were related to the computed values from Henderson's model. The coefficient of determination and standard error for the linear regression were 0.997 and 0.003, respectively.