• 제목/요약/키워드: line complex

검색결과 1,198건 처리시간 0.024초

Luminescence and Crystal-Field Analysis of Europium and Terbium Complexes with Oxydiacetate and 1,10-Phenanthroline

  • Kang, Jun-Gill;Kim, Tack-Jin
    • Bulletin of the Korean Chemical Society
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    • 제26권7호
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    • pp.1057-1064
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    • 2005
  • Photoluminescence (PL) spectra of Eu(III) and Tb(III) complexes with mixed oxydiacetate (ODA) and 1,10-phenanthroline (phen) ligands and with homoleptic ODA reveal characteristic line-splitting at 10 K, depending on the site-symmetry of the lanthanide ion in the complex. The energy-level schemes of the $^7F_J$ states and the emitting levels for Eu(III) and Tb(III) ions have been proposed by simulating the line splitting in the framework of crystal-field Hamiltonian. The sets of refined crystal-field parameters for the experimentally determined sitesymmetry satisfactorily reproduce the experimental energy-level schemes. In addition, the PL quantum yield and the decay time were determined at room temperature. The PL quantum yields of [$Eu(ODA){\cdot}(phen){\cdot}4H_2O]^+$ and [Tb$(ODA){\cdot}(phen){\cdot}4H_2O]^+$ in the crystalline state (Q = 17.7 and Q = 56.6%, respectively) are much greater than those of [Eu($ODA)_3]^{3-}and\;[Tb(ODA)_3]^{3-}$(Q = 1.1 and Q = 1.3, respectively), due to the energy transfer from phen to the lanthanide ion. In the aqueous state, the relaxation of the phen moiety due to the solvent results in the reduction of the quantum yield and the shortening of the lifetime.

HSVA 두 탱커 선형에 대한 점성유동 계산 (Numerical Calculation of Viscous Flows for Two HSVA Tankers)

  • 곽영기
    • 한국해양공학회지
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    • 제13권2호통권32호
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    • pp.138-146
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    • 1999
  • The viscous flow around a ship hull is calculated by the use of RANS(Reynolds-averaged Navier-Stokes) solver. Reynolds stresses are midelled by using the k-${epsilon}$ turbulence model and the law is applied near the body. Body fitted corrdinates are introduced for the treatment of the complex boundary of the ship hull form and the governing equations in the physical domain transformed into ones in the computational domain. The transformed equations are numerically solved by an employment of FVM(Finite Volume Method). SIMPLE(Semi-Implicit Pressure Linked Equation) method is adopted in the calculation of pressure and the solution of the sidcretized equation is obtained by the line-by-line method with the use of TDMA(Tri-Diagonal Matrix Algorithme). To assure the proprietty of this computing method, HSVA tanker and Dyne hull are calculated ar both model and ship scale Reynolds number. Their reaults of pressure distributions on fore and aft body, axial velocity contours and transverse velocity velocity vectors and viscous resistance coefficients are compared with other's experiments and calculations.

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충적토사지반에서의 도심터널 설계 및 시공 (Design and Construction Case of Urban Tunnel in Alluvial Soil)

  • 장석부;허도학;문상조;김도수
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 세계 도시지반공학 심포지엄
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    • pp.829-834
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    • 2009
  • Alluvial soil is one of the most difficult grounds for tunneling works due to the insufficient ground strength and excessive ground water inflow. Dduk island in Seoul has a wide alluvium developed by two rivers, Han and Jung-Ryang. Subway tunnel of $\bigcirc\bigcirc$ line planed across Dduk island has highly poor ground conditions due to small cover and deeply developed alluvium. Moreover, much part of this tunnel is located parallel to the bridge foundations of another railway with a small horizontal distance. Original design was done in 2002 and construction has been in progress. During the construction, tunnel design has been partly changed and adjusted for the complex ground condition and the demand from related organizations. This paper intend to introduce the urban tunnel design and construction in alluvial soils. This line could be divided three sections(A, B, C) according to ground and adjacent conditions. Section A is featured by mixed tunnel faces consisted with alluvial soils and weathered or weak rocks. The feature of section B is that tunnel underpasses near the bridge foundations of another subway. Lastly, section C with a very short length is the most difficult construction conditions due to the small cover, poor ground, obstacles on and underneath ground surface.

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통신과 방송망을 이용한 독서출판물 쌍방향 방송 시스템 구성방안 (Interactive Transmission System Composition Using Internet and Broadcasting Network for the e Book Publications)

  • 강명구
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2002년도 춘계종합학술대회
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    • pp.243-248
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    • 2002
  • 디지털 기술의 발전과 컴퓨터의 등장으로 인쇄 출판 시스템과 서적 형태도 불가피하게 변화를 수반하게 되었다. 종이 책 대신 전용단말기를 이용하여 서적 내용물을 디지털 정보로 배송하는 전자책의 등장이 그것이다. 시스템적으로 볼 때 독서와 출판은 분리된 상태이다. 이를 파악하기 위해서는 온라인주문과 판매 서비스와 디지털 서적 내용물을 온라인으로 전송하는 망 연통 서비스 시스템 구성이 필요하다. 이 논문은 이와 같은 난점을 해결하기 위한 독서출판 방식에 대하여 기술한 것이다. 이는 방송과 통신, 그리고 컴퓨터와 인터넷이 복합적으로 융합된 시스템이라 할 수 있다.

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분류자 시스템을 이용한 인공개미의 적응행동의 학습 (Learning of Adaptive Behavior of artificial Ant Using Classifier System)

  • 정치선;심귀보
    • 한국지능시스템학회:학술대회논문집
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    • 한국퍼지및지능시스템학회 1998년도 추계학술대회 학술발표 논문집
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    • pp.361-367
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    • 1998
  • The main two applications of the Genetic Algorithms(GA) are the optimization and the machine learning. Machine Learning has two objectives that make the complex system learn its environment and produce the proper output of a system. The machine learning using the Genetic Algorithms is called GA machine learning or genetic-based machine learning (GBML). The machine learning is different from the optimization problems in finding the rule set. In optimization problems, the population of GA should converge into the best individual because optimization problems, the population of GA should converge into the best individual because their objective is the production of the individual near the optimal solution. On the contrary, the machine learning systems need to find the set of cooperative rules. There are two methods in GBML, Michigan method and Pittsburgh method. The former is that each rule is expressed with a string, the latter is that the set of rules is coded into a string. Th classifier system of Holland is the representative model of the Michigan method. The classifier systems arrange the strength of classifiers of classifier list using the message list. In this method, the real time process and on-line learning is possible because a set of rule is adjusted on-line. A classifier system has three major components: Performance system, apportionment of credit system, rule discovery system. In this paper, we solve the food search problem with the learning and evolution of an artificial ant using the learning classifier system.

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Thyristor전력변환기-전동기계의 무효전력의 처리에 관한 연구

  • 유철로
    • 전기의세계
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    • 제31권1호
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    • pp.50-58
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    • 1982
  • As a method for improving the power factor and the waveform of ac line current drawn by ac to dc converters, converters of pulse-width control type with forced commutation circuits have been developed in recent years. However, these converters have rather complex commutation circuits which contain auxiliary thyristors in addition to the main thyristors, and their performance is not satisfactory. This paper proposes a new pulse-width controlled ac to dc converter, and analyses its commutation mechanism and its input and output characteristics. The proposed converter circuit consists of a usual thyristor bridge circuit with series diodes to which reactors and diodes are added. This circuit dose not contain auxiliary thyristors, and in this sense it is simpler than the previous converter circuits of pulse-width control type. Since the main thyristors of the converter can be forcedly turned off several times in a half cycle of source voltage, a pulse-width modulation control is possible in order to improve the current waveform as well as the power factor on ac line side. As to dc output side it is shown that the adjustable range of output voltage is wide and the voltage regulation is good due to a rapid reversal of voltage across the commutating capacitors by LC resonance during commutation period. It is also shown that the regenerative operation of the converter is possible.

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단상 유도동기전동기의 기동 특성 개선을 위한 회전자 바 형상 설계 (The Design of Rotor Bars of Single-Phase Line-Start Permanent Magnet Motor for Improving Starting Characteristics)

  • 이철규;권순효;양병렬;권병일
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제54권8호
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    • pp.370-376
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    • 2005
  • The single-phase induction motor is simple and durable, but the efficiency is low. Therefore, electric motors like HLDC and LSPM(line-start permanent magnet motor) that use the permanent magnet have been studied. The most advantages of single-phase LSPM is having the same stator as the stator of the single-phase induction motor and permanent magnets are just inserted in the squirrel cage rotor of the single-phase induction motor. But the characteristics of single-phase LSPM synchronous motor has very complex characteristics until the synchronization and if the design is not suitable, the single-phase LSPM synchronous motor cannot be synchronized. We designed a single-phase LSPM using the same stator and winding as the conventional single-phase induction motor, but newly designed the permanent magnets considering air gap magnetic flux density. The transient characteristics of the single-phase LSPM is not good because of a magnetic breaking torque, however, it can be improved by redesigning the rotor bars. We are proposed the design method of rotor bar for the single-phase LSPM to start softly and to make synchronization easily.

3호선 실제선로 조건에서의 레일경좌 변화에 따른 철도차량 주행안전성 해석 (Running Safety Analysis of Railway Vehicle depending on Rail Inclination Change on Actual Track of Subway Line No.3 in Seoul)

  • 김태건;이희성
    • 한국안전학회지
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    • 제31권3호
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    • pp.130-135
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    • 2016
  • It is very hard to analyze the train derailment safety quantitatively at the curved section because of the diversified affect parameters including the complex interaction between wheel and rail, the train conditions such as the shape of wheel, suspension system, the track conditions such as the radius of curve, cant, transition curve, and the operation conditions, etc. Two major factors related to the running safety of railway vehicle are classified as the railway vehicle and the track condition. In this study, when the railway vehicle passing through curves of actual track condition of subway line NO.3 in seoul ($Yeonsinnae{\leftrightarrow}Gupabal$), the effect that has influence on running safety depending on rail inclination. The analysis result of 1/40 rail inclination condition is more favorable on running safety than other rail inclination conditions because derailment coefficient and wheel unloading ratio are the lowest.

모의 변압기의 VHF/UHF PD 스펙트럼 분석 (Spectrum Analysis of VHF/UHF PD in Simulated Transformer)

  • 김덕근;김종서;임용배;임장섭;문채주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마
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    • pp.50-54
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    • 2000
  • Recently, the HFPD measurement testing is widely used in partial discharge measurement of HV machines because HFPD measurement testing receives less influence of external noise and has a merit of good sensitivity. Also HFPD testing is able to offer the judgement standard of degradation level of HV machine and can detect discharge signals in live-line. Therefore it is very useful method compare to previous conventional PD testing method and effective diagnosis method in power transformer that requires live-line diagnosis. But partial discharges have very complex characteristics of discharge pattern so it is required continuous research to development of precise analysis method. In recent, the study of partial discharge is carrying out discover of initial defect of power equipment through condition diagnosis and system development of degradation diagnosis using HFPD(High Frequency Partial Discharge) detection. In this study, simulated transformer is manufactured and HFPD occurred from transformer is measured with broad band antenna in real time, the degradation grade of transformer is analyzed through produced patterns in simulated transformer according to applied voltages.

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획의 방향 코드 조합에 의한 오프라인 필기체 숫자 인식 (Off-line Handwritten Digit Recognition by Combining Direction Codes of Strokes)

  • 이찬희;정순호
    • 한국정보과학회논문지:소프트웨어및응용
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    • 제31권12호
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    • pp.1581-1590
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    • 2004
  • 본 논문은 한 가지 특징 요소로서 획 방향 코드들만을 사용하는 강건한 오프라인 필기체 숫자 인식 방법을 제안한다. 이 방법은 입력된 숫자 이미지에 대하여 일반적인 8방향 코드를 생성하고 이 코드들의 조합을 다층 신경망에 학습하고 각 숫자를 인식하게 한다. 8방향 코드들은 다양하게 표현된 숫자들의 자기구성 그래프(SOG*:Improved Self-Organizing Graph) 세선화 결과에 의해 만들어지고 이 코드의 사용은 2개 이상의 특징점들을 처리하는 기존의 복합적인 단계들을 단순화시킨다. 실험결과는 모든 숫자 데이타베이스의 어떤 이미지들에 대해서도 인식률이 일관성 있게 98.85% 이상임을 보여준다.