• Journal of Energy Engineering
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• v.26 no.1
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• pp.62-67
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• 2017

Limestone is an important commodity in Philippines. Limestone has numerous uses that range from agricultural applications to building materials to medicines. Many limestone products require rock with specific physical and chemical characteristics. Most limestone is biochemical in origin meaning the calcium carbonate in the stone originated from shelled oceanic creatures. In this paper, we reported the natural sources of limestone, geological formation of limestone and the oyster shell waste in Cebu, Bantayan, Philippines were reported. Due to the mining or quarrying in Cebu, Bantayan, in a limestone area poses the threat of groundwater pollution (since limestone is a porous geologic formation with a high transmissivity). The other environmental issue is oyster shell waste. The oyster shell waste is the major source of limestone. We developed and applied appropriate technologies for the extraction of limestone from oyster shell waste and utilizes as high value added material.

• Journal of Energy Engineering
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• v.27 no.3
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• pp.48-56
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• 2018

The shell waste biomineralization process has known a tremendous metamorphosis and also the nanostructure with the identification of matrix proteins in oyster shells. However, proteins are represented in minor shell components and they are the major macromolecules that control biocrystal synthesis. Aragonite and calcite were derived from molluscan shells and evaluated the source of carbonate minerals and it helps for the formation of limestone. The oyster shell wastes are large and massive. The paleoecological study of oyster beds has discovered a near-shore and thin Upper Rudeis formation with storm influence during the accumulation of oysters with highly altered by disarticulation, bioerosion, and encrustation. It is possible even in the Paleozoic mollusks provided sufficient carbonate entirely to the source of microcrystalline of limestone. The present review is to discuss paleoecologically a number of oyster shell beds accumulated and sediment to form the different types of limestone during the Middle Miocene time.

• Journal of Energy Engineering
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• v.29 no.3
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• pp.42-49
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• 2020

Precipitated Calcium Carbonate (PCC) can be utilized in energy-effective paper production. Limestone is a raw material for synthesizing PCC. Since the PCC production yield depends on the physicochemical properties of the limestone, a basic investigation of the raw limestone is required. This study provides a brief review of the origin of limestone, limestone distribution characteristics, and limestone deposits in Korea and Vietnam. Most limestones in Korea were formed in the Paleozoic era. On the other hand, limestones in Vietnam have various ages from the Precambrian to the Triassic. Limestone is the most largely produced mineral in Korea, but Vietnam has 5 times more amount of limestone reserves than Korea.

• 한국석유지질학회:학술대회논문집
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• autumn
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• pp.63-65
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• 2001

The Chosen Supergroup (Cambro-Ordovician), mid-east Korea consists mainly of shallow marine carbonates and contains a variety of limestone conglomerates. These conglomerates largely comprise oligomictic, rounded lime-mudstone clasts of various size and shape (equant, oval, discoidal, tabular, and irregular) and dolomitic shale matrices. Most clasts are characterized by jigsaw-fit (mosaic), disorganized, or edgewise fabric and autoclastic lithology. Each conglomerate layer is commonly interbedded with limestone-dolomitic shale couplets and occasionally underlain by fractured limestone layer, capped by calcareous shale. According to composition, characteristic sedimentary structures, and fabric, limestone conglomerates in the Hwajol, Tumugol, Makkol, and Mungok formations of Chosen Supergroup can be classified into 4 types: (1) disorganized polymictic conglomerate (Cd), (2) horizontally stratified polymictic conglomerate (Cs), (3) mosaic conglomerate (Cm), and (4) disorganized/edgewise oligomictic conglomerate (Cd/e). These conglomerates are either depositional (Cd and Cs) or diagenetic (Cm and Cd/e) in origin. Depositional conglomerates are interpreted as storm deposits, tidal channel fills, or transgressive lag deposits. On the other hand, diagenetic conglomerates are not deposited by normal sedimentary processes, but formed by post-depositional diagenetic processes. Diagenetic conglomerates in the Chosen Supergroup are characterized by autoclastic and oligomictic lithology of lime-mudstone clasts, jigsaw-fit (mosaic) fabric, edgewise fabric, and a gradual transition from the underlying bed (Table 1). Autoclastic and oligomictic lithologies may be indicative of subsurface brecciation (fragmentation). Consolidation of lime-mudstone clasts pre-requisite for brecciation may result from dissolution and reprecipitation of CaCO3 by degradation of organic matter during burial. Jigsaw-fit fabric has been considered as evidence for in situ fragmentation. The edgewise fabric is most likely formed by expulsion of pore fluid during compaction. The lower boundary of intraformational conglomerates of depositional origin is commonly sharp and erosional. In contrast, diagenetic conglomerate layers mostly show a gradual transition from the underlying unit, which is indicative of progressive fragmentation upward (Fig. 1). The underlying fractured limestone layer also shows evidence for in situ fragmentation such as jigsaw-fit fabric and the same lithology as the overlying conglomerate layer (Fig, 1). Evidence from the conglomerate beds in the Chosen Supergroup suggests that diagenetic conglomerates are formed by in situ subsurface fragmentation of limestone layers and rounding of the fragments. In situ subsurface fragmentation may be primarily due to compaction, dewatering (upward-moving pore fluids), and dissolution, accompanying volume reduction. This process commonly occurs under the conditions of (1) alternating layers of carbonate-rich and carbonate-poor sediments and (B) early differential cementation of carbonate-rich layers. Differential cementation commonly takes place between alternating beds of carbonate-rich and clay-rich layers, because high carbonate content promotes cementation, whereas clay inhibits cementation. After deposition of alternating beds and differential cementation, with progressive burial, upward-moving pore fluid may raise pore-pressure in the upper part of limestone layers, due to commonly overlying impermeable shale layers (or beds). The high pore-pressure may reinforce propagation of fragmentation and cause upward-expulsion of pore fluid which probably produces edgewise fabric of tabular clasts. The fluidized flow then extends laterally, causing reorientation and further rounding of clasts. This process is analogous to that of autobrecciation, which can be analogously termed autoconglomeration. This is a fragmentation and rounding process whereby earlier semiconsolidated portions of limestone are incorporated into still fluid portions. The rounding may be due mainly to immiscibility and surface tension of lime-mud. The progressive rounding of the fragmented clasts probably results from grain attrition by fluidized flow. A synthetic study of limestone conglomerate beds in the Chosen Supergroup suggests that very small percent of the conglomerate layers are of depositional origin, whereas the rest, more than $80\%$, are of diagenetic origin. The common occurrence of diagenetic conglomerates warrants further study on limestone conglomerates elsewhere in the world.

• Economic and Environmental Geology
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• v.10 no.1
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• pp.19-35
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• 1977

The study area is located in between Hacheonri and Weolgulri, Jecheon-gun where the formations of Okcheon group and Chosun group come in contact and the stratigraphy and geological age of the Okcheon group have been debated among previous workers. The dolomitic limestone which distributed at Cheongam and Dumusil is clarified as the Hyangsanri dolomite formation and the quartzite distributed at Cheongam and Howeunri as Taehyangsan quartzite formation. The newly named Soorumsan schist interbedded in the Great Limestone Series was previously classified Seochangri formation. It is also classified that the formation formerly named as Seochangri was divided into newly named Manji schist which seems to be correlated to Kemyeongsan and Munjuri formation. The formation formerly named as Buknori is clarified as Hwanggangri formation. The Samtaesan formation has been clarified as the lower and upper limestone beds which belong to the Great Limestone Series. The area divided into two groups, that is, Okcheon system of Pre-cambrian age occupies western part and the Great Limestone Series of Chosun system of Cambro-Ordovician age eastern part of this area. Okcheon system consists in ascending order of Manji schist, Hyangsanri dolomite, Taehyangsan quartzite, Munjuri schist, and Hwanggangri formation of meta-tillite. The Great Limestone Series of Chosun group consists in ascending order of lower limestone, Soorumsan schist, Hoosanri quartzite and upper limestone formations. Busan augen gneiss seems to be igneous origin. Unmetamorphosed shale interbed can be traced in the Soorumsan schist. Previous study (Kims, 1974) reveals that meta-volcanic rocks are distributed from south to north along contact zone of the Okcheon and Chosun groups, and it has been confirmed that the meta-volcanics crop out continuously from the adjacent southern quardrangle into the southern part of the area studied, intruding along the fault zone between the Okcheon and Chosun groups which seems to be upthrust as in the area south. This evidence coincides with Kims' work (1974) which states that the Precambrian Okcheon group is largely overturned and thrusted over the Chosun group.

• Economic and Environmental Geology
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• v.13 no.2
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• pp.104-116
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• 1980

The Ulsan mine is one of the largest contact metasomatic magnetite and scheelite deposits in the southeastern part of Korea. Mineralization at the Ulsan mine is localized along the contact between upper Cretaceous volcanic rocks and age unknown limestone which were intruded by 58 m.y. -old biotite-horndlende granite. General zonal sequence of skarn toward crystalline limestone from limestone-volcanics contact is grandite, grandite-salite and salite zones. On the otherhand volcanics origin skarns exhibits zonal sequences toward hornfels from boundary with limestone is garnet, garnet-epidote, and epidote zone. Compositions of garnets and clinopyro xenes are determined by the X-ray diffraction and reflective indecies. Local brecciation of these early skarns were followed by formation of the later skarn as zoned patches, breccia fillings and cross-cutting veins. Paragenetic sequence of late skarn minerals which is exhibited in the zoned patches and veins is an overlapping progression with time from andradite through hedenbergite or actinolite, quartz to calcite deposition. Magnetite metallization followed early formed skarns and pyrite pyrrhoite, sphalerite, galena, tennantite, scheelite and arsenopyrite deposition were simultaneously with hedenbergite, quartz and calcite of late skarn. Filling temperatures of fluid inclusions in calcites range from $160^{\circ}$ to $280^{\circ}C$.

• Journal of the Mineralogical Society of Korea
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• v.18 no.2
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• pp.135-144
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• 2005

In the high-Ca limestone zone of the Pungchon Formation of the Lower Chosun Supergroup, cryptocrystalline alterations with reddish brown color occur as fissure-fillings or coatings, which was originated from the upper formation, i. e., the Hwajeol Formation. The precipitates result in degradation and contamination of the high-Ca limestone ore in grade and quality, showing characteristic occurrence and mineral composition typical of suggesting a supergene origin. Chalcedonic quartz, kaolinite, illite, goethite and hematite are constituting a characteristic authigenic mineral assemblage and, in places, smectite is less commonly included in the weathering product. In addition to these authigenic phases, some detrital minerals such as mica and orthoclase constituting relatively coarser grains are also rarely present in the supergene alterations. A rather complex clay facies consisting of kaolinite, illite and smectite in the alterations seems to correspond to the typical clay composition of the reported residual pedogenic soils by limestone weathering. The cryptocrystalline weathering product is partly altered to stilbite, a characteristic hydrothermal zeolite, in places, by the hydrothermal contact of late stage. The time of formation and infiltration of the supergene alterations seems to correspond to the stage just after the epithermal alteration of the Pungchon Limestone, i. e., an early Jurassic age. The supergene alteration, which may imply the stage of uplifting, weathering and erosion of the Chosun Supergroup, appears to have undergone at an oxygen-rich environment in descending water of meteoric origin by means of a chemical leaching and diffusion.

• Journal of the speleological society of Korea
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• no.7
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• pp.3-8
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• 1998

There are some 1,000 natural caves in Korea. Most caves on the mainland are made of limestone, whereas most of the caves on Cheju Island are volcanic in origin. The caves on Cheju, in particular, are internally renowned for their huge size and scientific value. By contrast, the caves on the mainland are not as big, but their unique shapes and formations still attract the attention of international speleologists.(omitted)

• Journal of the speleological society of Korea
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• no.8
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• pp.3-10
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• 1998

There are some 1,000 natural caves in Korea. Most caves on the mainland are made of limestone, whereas most of the caves on Cheju Island are volcanic in origin. The caves on Cheju, in particular, are internationally renowned for their huge size and scientific value. By contrast, the caves on the mainland are not as big, but their unique shapes and formations sti1l attract the attention of international speleologists.(omitted)

• Economic and Environmental Geology
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• v.35 no.5
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• pp.429-436
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• 2002

Core samples, drilled in the middle region of Bavaria, were analyzed to study the characteristics of organic matter in the Upper Jurassic Solnhofen limestone of southern Germany. The core (48$^{\circ}$53'N, 1-1$^{\circ}$19'E) contains Upper Jurassic Solnhofen strata ranging from the upper part of the Geisental Formation throughout the Solnhofen Formation to the lower part of the Mornsheim Formation. In the core, the Upper Jurassic lithologies consist of platy limestone, bedded limestone and massive limestone often interbedded with some chert layers. Geochemical variations (Carbon, Nitrogen and Total Organic Carbon) and Rock-Eval pyrolysis parameters (S$_2$ peak and Hydrogen Index) indicate that the organic matter in the Upper Jurassic limestone is mostly of marine origin. Particularly, the relation-ship of Hydrogen Index and S$_2$ as a function of Total Organic Carbon suggests that the upper formation of the core (Mornsheim Formation) was more influenced by terrigenous influx than the Solnhofen and Geisental Formations.