• Resources Recycling
• /
• v.12 no.2
• /
• pp.11-20
• /
• 2003

Limestone mine waste was used as a aggregate far permeable concrete. Void ratio, continuous void ratio, coefficient of permeability, compressive strength and flexural strength of concrete were measured and then the relationship between porosity and strength properties was investigated. Void ratio, continuous void ratio and strength properties of permeable concrete were greatly influenced by the grain size of aggregate and void filling ratio in comparison with the containing ratio of limestone mine waste. Furthermore, void ratio showed a good relation with continuous void ratio, and porosity of permeable concrete indicated a good relation with strength properties also. The coefficient of permeability of permeable concrete using limestone waste was over 0.2 cm/sec and was excellent result in comparison with normal concrete. Therefore, it could be expected that the limestone mine waste would be utilized as aggregate for pavement concrete, green concrete and water resource specie concrete in the results of this study.

• Explosives and Blasting
• /
• v.24 no.2
• /
• pp.75-82
• /
• 2006

Most of limestone mines in Korea have been developed by a open-cut mining method in consideration of a deposited condition of ore, ore recovery, safety, economic efficiency, etc.. But it has produced environmental problems such as dust flying, blasting noise & vibration, and spoil of farmlands due to slope failure of waste rock mass caused by access road construction, fragmentation & crush of rocks, blasting, transportation, and mineral processing. In this study, it has been suggested for measures to reduce mine hazards caused by open- cut mining of limestone nines.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2005.10a
• /
• pp.59-61
• /
• 2005

In Korea, hundreds of abandoned and closed coal and metallic mines are present in the steep mountain valleys due to the depression of the mining industry since the late 1980s. From these mines, enormous amounts of coal waste were dumped on the slopes, which causes sedimentation and acid mine drainage (AMD) to be discharged directly into streams causing detrimental effects on soil and water environments. A limestone slurry by-product (lime cake) is produced from the Solvay process in manufacturing soda ash. It has very fine particles, low hydraulic conductivities ($10^{-8}{\sim}10^{-9}cm/sec$), high pH, high EC due to the presence of CaO, MgO and $CaCl_2$ as major components, and traces of heavy metals. Due to these properties, it has potential to be used as a neutralizer for acid-producing materials. A field plot experiment was used to test the application of lime cake for reclaiming coal wastes. Each plot was 20 x 5 m (L x W) in size on a 56% slope. Treatments included a control (waste only), calcite ($CaCO_3$), and lime cake. The lime requirement (LR) for the coal waste to pH 7.0 was determined and treatments consisted of adding 100%, 50%, and 25% of the LR. The lime cake and calcite were also applied in either a layer between the coal waste and topsoil or mixed into the topsoil and coal waste. Each plot was hydroseeded with grasses and planted with trees. In each plot, surface runoff and subsurface water were collected. The lime cake treatments increased the pH of coal waste from 3.5 to 6, and neutralized the pH of the runoff and leachate of the coal waste from 4.3 to 6.7.

• Korean Journal of Soil Science and Fertilizer
• /
• v.47 no.6
• /
• pp.540-546
• /
• 2014

Acid mine drainage sludge (AMDS) has been classified as mine waste and generally deposited in land. For this reason, studies have been conducted to examine the possibility of recycling AMDS as an amendment for heavy metal stabilization in soil. The main objective of this study was to evaluate heavy metal stabilization efficiency of AMDS comparing with the widely used lime stone. Also, optimum mixing ratio was evaluated for enhancing heavy metal stabilization. AMDS and limestone were mixed at the ratio of 0:100, 25:75, 50:50, 75:25, and 100:0 with five different heavy metal solutions ($100mg\;L^{-1}$ of $NaAsO_2$, $CdCl_2$, $CuCl_2$, $Pb(NO_3)_2$, and $ZnSO_4{\cdot}7H_2O$). The amendments were added at a rate of 3% (w/v). In order to determine the stabilization kinetics, samples were collected at different reaction time of 0, 1, 2, 4, 8, 16, 32, 64, 128, 256, 512, 1024 minutes. The heavy metal stabilization by AMDS was faster and higher than those of limestone for all examined heavy metals. While limestone showed only 20% of arsenic (As) stabilization after 1,024 minutes, 96% of As was stabilized within 1 minute by AMDS. The highest effect on the stabilization of heavy metal (loid) was observed, when the two amendments were mixed at a ratio of 1:1. These results indicated that AMDS can be effectively used for heavy metal stabilization in soil, especially for As, and the optimum mixing ratio of AMDS and lime was 1:1 at a rate of 3% (w/v).

• 한국지구물리탐사학회:학술대회논문집
• /
• 2001.09a
• /
• pp.75-89
• /
• 2001

There are 334 coal mines and about 900 metal mines abandoned. The environmental problems such as acid mine drainage from adits etc. and the subsidence has occurred in the abandoned mines. In addition, soil has been contaminated by tailings. According to analysis of mine drainages, some of them from adits in the abandoned coal and metallic mines were acidic and polluted by heavy metals. Especially, water quality of coal mine drainages were different by areas. Treatment of mine drainage by conventional chemical treatment has the drawback because the operating cost is very expensive. The treatment system used in mine drainage is the natural treatment system such as anoxic limestone drain in adits and the constructed wetland. The method of reclamation for abandoned waste rocks and tailings impoundments are mainly landfilling.

• Journal of Korea Soil Environment Society
• /
• v.3 no.1
• /
• pp.31-44
• /
• 1998

The geochemical experiments were carried out to investigate a removal effect of heavy metals in abdndoned metallic mine wastes, and to conceive a treatment techniques of them. In order to prevent contamination, experiment appature was made of acrylic acid resin and polyethylene which resist to acid and alkali. Experiment models are devided into four groups based on the system environments, distribution patterns and a kind of filling materials. The first group is background model(model I ) which is filled with waste only and opened to air. The second one is four layer group which is subdivided into two models, opened and closed systems, and the third mix group which is subdivided into three models based on mixing ratio of filling materials and system environment like a layered group. The forth is composed of two layer model, lower one composed of waste and upper one limestone chips. Solution drained from Model Ishows a high contents of heavy metals on the all terms of experiments. Among the models, however, the closed mix model V and Ⅶ show the most effective removal of heavy metals liberated from wastes. Models having different mixing ratios of filling materials on closed systems does not affect in heavy metal removal effect. But, the distribution patterns of filling materials affect very much on removal effect of heavy metals. The closed models with same constitution ratios and distribution patterns of filling materials show more and less effective removal to the open models.

• Tunnel and Underground Space
• /
• v.20 no.6
• /
• pp.475-490
• /
• 2010

The analysis of slope stability was performed from seven sites among total eleven sites of waste rock which are divided into two objects (mullock-pile and rock mass) according to the location of dumping-dropping point in L limestone Mine. The analysis of circular failure using Bishop's simplified method and the finite element method for mullock-pile slopes were adopted. For rock mass slopes, identification of failure modes on stereonet projection was determined, thereby limit equilibrium analysis was applied to obtain the safety factor of slopes and the finite element method was used to understand overall behavior of slope. Phi-c reduction method was used to calculate the safety factor of slopes through the finite element method. In mullock-pile slope of zone D and rock slopes of zone F and G, the assurance of slope stability was difficult, and the plans to assure the stability of slopes were proposed on the basis of the analysis of slopes at disposal sites of waste rock. Therefore, the method of piling with waste rock by dozer pushing after dumping for mullock-pile slope of zone D is required, and the method of piling after moving to the place which has no fault zone for rock slope of zone F and G is recommended.

• Journal of the Korean Geotechnical Society
• /
• v.21 no.9
• /
• pp.35-44
• /
• 2005

Recently, underground cavities such as limestone cavity and abandoned mine give rise to a lot of damage in SOC facilities. But there are many difficult problems such as delay of the working terms and enormous economic losses in finding a new method and changing construction design. In this study, a new filling material for underground cavities was developed using the stone-dust classified as industry waste polluting environment. As a result of test, filling material properties was that a compressive strength was $34{\~}60\;kgf/cm^2$, a change ratio in length was $0.268{\~}0.776\%$ and water absorption was $34.3{\~}46.9\%$. Also as a result of suspended mass test and pH test, it was confirmed that the developed filling material has a characteristic of non-separating in water and it was an environmentally friendly material.

• Journal of the Korean GEO-environmental Society
• /
• v.16 no.5
• /
• pp.27-33
• /
• 2015

Manganese in sludge precipitated during water treatment might be soluble again in effluent from sludge thickener. If that happens, the manganese concentration of effluent from water treatment plant will exceed the limit for clean reservation. In this study the influence of pH on Mn concentration of effluent from sludge thickener of water treatment plant was investigated. When the pHs of sludge solutions increased with alkaline materials such as NaOH, KOH, CaO, $Ca(OH)_2$, $CaCO_3$, the Mn concentrations of sludge solutions decreased under the limit. The Mn concentration of effluent from sludge thickener could be controlled with waste limestones from beneficiation process at limestone mine as an alkaline material.

• Resources Recycling
• /
• v.5 no.4
• /
• pp.25-31
• /
• 1996

The wastes ot l~mestone mines have been cause the extrar.ngance of the valuablz m e r a l s and destruction of the environment. Therefore, \\-c tied ta separation of calcite illid clay from the limestone mine wastes by rotntmg screen type separator made by ourselves in order to recyding such us a raw matcriala for cement maimfacture. CaO amtents in the separated coarse products increased from 37.36 wt% to 42+2 wt% at the condition ihat water content in wastes was lzss than 6wt%, the passing time of specimen in &amber was 15 semnds and the rotation speed was 6OLl qm. A process in order lo separate wastes effectively to having wide range aI part~dcs ize was cstablishcd and CaO contents of coarsc products through this process increased to 46.85 wt%. Tbis rcsult is insuEiicient to directly rcusing as a raw malerials for cement. However, it is supposed that coarse products would be able to be reuscd as a raw materials uf cement, if only it rs sclected dolomite in wastes, and really it may be possible in fields Othenvise, undcrsize products(less than 20 mm) would be able to recycling as a raw of cement bccause chcmicrl campasitions of thosc is kept almost constant v&cs on the overall process.