This experiment was conducted to investigate the distribution and compositions of clay mineral and to replenish the soil classification system in Korea. Soil layer samples were collected from 26 residuum and colluvium soil series out of 390 soil series in Korea, and then analyzed for soil physical and chemical characteristics, mineral and chemical compositions of clay in B horizon soils. Major clay minerals of residuum and colluvium were illite and chlorite in soils originated from the sedimentary rock such as limestone, shale, sandstone and conglomerate; quartz and kaolin in soils originated from rhyolite, neogene deposits, porphyry and tuff; and kaolin and quartz in the soils originated from granite, granite gneiss and anorthosite. Clay minerals in Korean soils were divided into 4 groups: mixed mineral group(MIX) mainly contained with illite, kaolin and vemiculite; kaolin group(KA) with kaolin and illite; chlorite group(CH) with chlorite and illite; and smectite group(SM) with kaolin, illite and smectite. The most predominant clay mineral group was kaolin group(KA) with kaolin and illite; an mixed mineral group(MIX) with illite, kaolin and vemiculite. Cation exchange capacity (CEC) of clay was low in the soils mainly composed with MIX and KA groups and silica-alumina molar ratio of clay was high in the soils composed with SM group
The purpose of this study was to assess the applicability of acid mine drainage sludge (AMDS) pellets for the arsenic (As) stabilization and to suggest an evaluation method for arsenic stabilization efficiency in soil around abandoned coal mines. The soil samples were collected from the agricultural field around Ham-Tae, Dong-Won, Dong-Hae, and Ok-Dong coal mine. The As concentration in soil was exceeding the criteria of soil pollution level, except for Ham-Tae coal mine. The AMDS pellets are more appropriate to use by reducing dust occurrence during the transport and application process than AMDS powder. In addition, AMDS pellets were maintained the As stabilization efficiency. The application of AMDS pellets for the As stabilization in soil was assessed by column experiments. The AMDS pellets were more effective than limestone and steel slag, which used as the conventional additives for the stabilization process. The As extraction by $0.43M\;HNO_3$ or $1M\;NaH_2PO_4$ solution were appropriate evaluation methods for evaluation of As stabilization efficiency in the soil.
This study reports on the genesis and mineralogical characteristics of the clay minerals in the soils derived from the five major parent rocks of granite, granite-gneiss, limestone, shale, and basalt in Korea. The investigation on the mineralogical aspects of primary and secondary minerals of the rocks and coarse fractions in the soils have been already reported. In this report, the identification of clay minerals in the soil clay fractions was done through the analyses of chemical, X-ray diffraction, and thermal methods. The studies showed clearly that much of the clay minerals was evolved by the weathering of primary minerals and some were further developed by the transformation of secondary minerals. Cation exchange capacity(CEC) of the clay fractions increased with higher amotunts of vermiculite, chlorite, and illite, however, decreased with higher hydroxy octahedral sheet within the interlayer spaces of vermiculite even if dominant clay with vermiculite. Feldspars in the granite and granite-gneiss might be completely transformed to kaolin mineral, Illite, chlolrite, and vermiculite formed by the alteration of micas, amphibole, augite, and primary chlorile seem to be subsequently transformed to the mixed layer minerals such as illite/vermiculite, illite/chlorite, and chlorite/vermiculite. These weathering products may be ultimately transformed into kaolin minerals. The smectite minerals in the clay fractions of the soils developed on the limestone are considerably present and they seem to be formed directly by the precipitation from high Mg solution and/or by the transformation of vermiculite from micas and chlorite in the parent materials. Abundant presence of illite in the soil clays developed on the shale is considered to have inherited from the fine particles and more resistant hydrous muscovite. The weathering sequences of the hydrous muscovite were as follows according to the degree of soil development ; hydrous muscovite ${\rightarrow}$ illite/vermiculite mixed layer(Inceptisols, Daegu series) and hydrous muscovite ${\rightarrow}$ illite/vermiculite mixed layer ${\rightarrow}$ vermiculite ${\rightarrow}$ kaolin mineral(Alfisols, Buyeo series). The plagioclase in the basalt might be mostly weathered to kaolin minerais. The augite in the basalt is likely to be transformed through progressive stage of weathering, augite ${\rightarrow}$ chlorite ${\rightarrow}$ chlorote/vermiculite mixed layer ${\rightarrow}$ vermiculite ${\rightarrow}$ kaolin. Another weathering sequence of augite could be expected, augite ${\rightarrow}$ chlorite ${\rightarrow}$ illite by the presence of illite and illite/vermiculite mixed layer in the clay fractions. Vermiculite and gibbsite were quantified from thermogravimetry(TG) and kaolin minerals, from both TG and differerential thermal analysis (DTA). Vermiculite in Jangseong series from the limestone was the dominant clay mineral of 21.7 percent and had a range in the order of 9.2 percent in Buyeo series to 5.4 percent in Daegu series from the shale. The rest soils ranged from 8.8 to 28.3 percent. Kaolin minerals were the dominant clay mineral of 32.7 percent in Asan series from the granite-gneiss and Gueom series of 32.0 percent from the basalt. The soils from the limestone ranged from 9.4 to 14.9 percent. The rest soils ranged from 8.9 to 28.6 percent. Gibbsite were 3.9 and 2.3 percent for Weoljeong and Chahang series from the granite, respectively. In Asan and Cheongsan series from the giranite-gneiss were 1.4 and 4.5 percent, respectively, and 3.6 percent in Jangpa series from the basalt.
Journal of the Korean association of regional geographers
/
v.1
no.1
/
pp.93-101
/
1995
Nam Khane watershed, in the Northern Laos, consists of limestone plateau surrounded with steep slope(above 1000m), wide piedmont hill land(300-700m) and narrow alluvial plain. Opium on the plateau and up-land rice on the hill-side are cultivated for each, but its shifting agricultural activity, which degrades the forest and soil, has caused the serious environmental problems. MOS-1 satellite image and 40 points of soil samples are analyzed to identify the distribution of the shifting cultivation and to evaluate the environmental problems for Nam Khane watershed. The land use classification map is presented on the photo 2, and the value of each land use area by elevation level and soil property are showed on the table 2 and 3, respectively. Excessive agricultural activity of shifting cultivation in the Nam Khane watershed not only decreased the forest area, but also changed the primary forest of tree into secondary woodland of shrub. On the phase of soil property, it accelerated the soil and gully erosion, and acidification. To solve these environmental problems, the most important step is to settle the agriculture from shifting cultivation to permanent cropping.
The lime-soil mixture on tomb barrier (LSMB) is a type of tomb in Joseon Dynasty, which made with so-called 'Sammul' (three material compound) that mixture of lime, fine sand and yellow ocher. This study divided the tombs of the Gungri Site from Joseon Dynasty with layered wall and integrated wall according to the manufacturing types, and investigated on the basis of analysis to material characteristics and making techniques. Analytical samples were classified with lime-soil mixtures and soils, and interpreted the mixing characteristics of Sammul based on types of tomb barrier. The tomb barrier which is directly effect to control the inner environment was made with high content of lime. But the finishing or bottom layer were made with low content of lime. Overall the LSMB with integrated wall has higher content of lime and physical property than the LSMB with layered wall. The soil which was compounded as a Sammul and collected near the Gungri Site had similar with mineralogical and geochemical characteristics. Therefore, it is presumed that the fine sand and yellow ocher that made as a Sammul, were used with soil that was distributed around the site. Meanwhile, large scale limestone quarry is distributed near the site. Especially, Gungri Site has a possibility of material supply through water transport, due to the sea route from Asan bay is connected near the site. Thus, there is the possibility of transportation of lime materials from nearby quarry.
Journal of The Geomorphological Association of Korea
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v.19
no.2
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pp.81-98
/
2012
This research aims 1) to analyse the spatial occurrence of red soils, in Korea 2) to predict their spatial distribution using terrain analyses, and 3) to interpret results from the perspective of pedogeomorphological processes. Red soils (often called red-yellow soils) in Korea are frequently found on welldrained plains and gently sloping areas. These soils are widely believed paleo-soils that were formed under hot and humid climatic conditions in the past. The spatial distribution of red soils was derived from the soil map of Korea, and a DEM based soil prediction was developed, based on a continuity equation to depict water and material flows over the landscape. About 64.5% of the red soil occurrence can be explained by the prediction. Close examinations between surveyed and predicted red soil maps show few distinctive spatial features. Granitic erosional plains at the inland of Korea show comparatively low occurrence of red soils, which might indicate active geomorphological processes within the basins. The occurrence of red soils at limestone areas is more abundant than that of the predicted, indicating the influence of parent materials on the formation of red soils. At and around lava plateau at Cheulwon and Youncheon, the occurrence of red soils is underestimated, which might partly be explained by the existence of loess-like surface deposits. There are also distinctive difference of prediction results between northern and southern parts of Korea (divided by a line between Seosan and Pohang). The results of this research calls for more detailed field-based investigations to understand forming processes of red soils, focusing on the spatial heterogeneity of pedological processes, the influence of parent materials, and difference in uplift patterns of the Korean peninsula.
As urban infrastructure is aging, the possibility of accidents due to the failures or breakdowns of infrastructure increases. Especially, aging underground infrastructures like sewer pipes, waterworks, and subway have a potential to cause an urban ground sink. Urban ground sink is defined just as a local and erratic collapse occurred by underground cavity due to soil erosion or soil loss, which is separated from a sinkhole in soluble bedrock such as limestone. The conventional measurements such as differential settlement gauge, inclinometer or earth pressure gauge have a shortcoming just to provide point measurements with short coverage. Therefore, these methods are not adequate for monitoring of an erratic subsidence caused by underground cavity due to soil erosion or soil loss which occurring at unspecified time and location. Therefore, an alternative technology is required to detect a change of underground physical condition in real time. In this study, the feasibility of a novel magnetic resonance based monitoring method is investigated through laboratory tests, where the changes of path loss (S21) were measured under various testing conditions: media including air, water, and soil, resonant frequency, impedance, and distances between transmitter (TX) and receiver (RX). Theoretically, the transfer characteristic of magnetic field is known to be independent of the density of the medium. However, the results of the test showed the meaningful differences in the path loss (S21) under the different conditions of medium. And it is found that the reflection coefficient showed the more distinct differences over the testing conditions than the path loss. In particular, input reflection coefficient (S11) is more distinguishable than output reflection coefficient (S22).
An, Jong-Man;Lee, Hyun-Ju;Kim, Ki-Ho;Lee, Yong-Bok;Choi, Sang-Il
Journal of Soil and Groundwater Environment
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v.16
no.2
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pp.52-60
/
2011
Although facilities for the passive treatment of AMD (Acid Mine Drainage) are currently operating in Korea, their removal efficiency for heavy metals is relatively low in average (only 80%). Passive treatment system is composed of oxidation tank, SAPS (Successive Alkalinity Producing System), and wetland. In the treatment system adopted in korea, SAPS (Successive Alkalinity Producing System) plays a major role to remove about 65% of heavy metals through a precipitation. However, the efficiency of SAPS is limited due to the use of mushroom compost (MC) as a organic material and of limestone as a neutralizer. Therefore, this research was performed to search for alternative organic materials through the field test. We tested two types of mixed organic materials: 1) cow manure and spent oak (herein, CO) and 2) cow manure and sawdust (herein, CS). For comparison mushroom compost (herein, MC) was also tested. The result showed that the average Fe removal efficiency was 91.38% with CO, 85.19% with CS, and 91.58% with MC. Thus, CO can be effectively used as an alternative of MC in the SAPS system for heavy metals removal.
In order to compare species-specific calcium metabolism, we collected 127 species belonging to 40 different families grown on various habitats including saline, limestone, wetland during the 1996 vegetation period, and analyzed their inorganic ion contents. Plants investigated were divided into 5 groups according to their physiological properties: 1) Chenopodiaceae, Aizoaceae, Caryophyllaceae, Portulacaceae and Phytolaccaceae of Centrospermales and Polygonaceae (Polygonales had a little water-soluble $Ca^{2+}$ but contained high contents of insoluble $Ca^{2+}$ particularly as Ca-oxalate (Chenopodiaceae type), 2) Some plant species such as Rosaceae produced oxalate in amounts insufficient to precipitate all incoming $Ca^{2+}$ and thus contained a surplus of dissolved $Ca^{2+}$ (Rosaceae type), 3) The contents of water-soluble $Ca^{2+}$ in plant species of Crassulaceae. Plantaginaceae, Asclepiadaceae, and Zygophyllaceae were equal to or greater than those of K ($K/Ca{\leq}1$; Crassulaceae type), and 4) K/Ca ratios of Compositae were significantly fluctuated depending on species and soil $Ca^{2+}$ level of their habitats (Compositae type). 5) Certain monocots (Gramineae, Cyperaceae, Juncaceae), in contrast to the dicotyledonous plant families mentioned above, showed a very distinct type of calcium metabolism, that is, the K/Ca ratios of 8~10 were maintained indifferently in the species and their habitat types (Graminae type). These results plants within the same taxon have similar physiological aspects as weel as morphological attributes. To understand calcium metabolism of certain plant species, therefore, it is desirable to approach on the basis of physiological concept (calciotroph or calciophobe) rather than the ecological one (calcicole or calcifuge).
Journal of The Geomorphological Association of Korea
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v.24
no.4
/
pp.75-89
/
2017
Sinkholes are key karst landforms that primarily evolve through the dissolution of limestone, and it posing a significant threat to roads, buildings, and other man-made structures. This study aims to analyze the area susceptible to sinkhole development using GIS and to identify potential danger area from sinkholes. Eight sinkhole related factors (slope angle, distance to caves, distance to faults, bedrock lithology, soil depth, drainage class, distance to mines, and distance to traffic routes) were constructed as spatial databases with sinkhole inventory. Based on the spatial database, sinkhole susceptibility maps were produced using nearest neighbor distance and frequency ratio models. The maps were verified with prediction rate curve and area under curve. The result indicates that the nearest neighbor distance and frequency ratio models predicted 95.3% and 94.4% of possible sinkhole locations respectively. Furthermore, to identify potential sinkhole danger area, the susceptibility map was compared with population distribution and land use map. It has been found that very highly susceptible areas are along Osipcheon and southeast southwest part of Hajang-myeon and south part of Gagok-myeon of Samcheok-si. Among those areas, it has been identified that potential sinkhole danger areas are Gyo-dong, Seongnae-dong, Jeongna-dong, Namyang-dong and Dogye-eup. These results can be useful in the aspects of land use planning and hazard prevention and management.
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