• Elastomers and Composites
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• 제56권3호
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• pp.136-151
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• 2021

Biomass lignin, a waste produced during the paper and bio-ethanol production process, is a cheap material that is available in large quantities. Thus, the interest in the valorization of biomass lignin has been increasing in industrial and academic areas. Over the years, lignin has been predominantly burnt as fuel to run pulping plants. However, less than 2% of the available lignin has been utilized for producing specialty chemicals, such as dispersants, adhesives, surfactants, and other value-added products. The development of value-added lignin-derived co-products should help make second generation biorefineries and the paper industry more profitable by valorizing lignin. Another possible approach towards value-added applications is using lignin as a component in plastics. However, blending lignin with polymers is not simple because the polarity of lignin molecules results in strong self-interactions. Therefore, achieving in-depth insights on lignin characteristics and structure will help in accelerating the development of lignin-based products. Considering the multipurpose characteristics of lignin for producing value-added products, this review will shed light on the potential applications of lignin and lignin-based derivatives on polymeric composite production. Moreover, the challenges in lignin valorization will be addressed.

• Journal of the Korean Wood Science and Technology
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• 제25권2호
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• pp.21-26
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• 1997

Lignin viscous material was prepared from acetosolve lignin by phenolation and heat treatment. The yield of phenolation was about 160% with p-toluene sulfonic acid(2% of acetosolve lignin) as catalyzer. Phenolated lignin has a good spinnability and thermosetting property by $300^{\circ}C$ treatment with vaccum. Acetosolve lignin carbon fiber has $20{\pm}5$ m diameter and $68.2{\pm}10\;kg/mm^2$ tensile strength. The yield of carbon fiber based on acetosolve lignin was 31%.

• 펄프종이기술
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• 제37권5호통권113호
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• pp.50-55
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• 2005

In previous report, we investigated the impact of hexeneuronic acid and some residual extractiveson lignin determination. These non-lignin components severely interfered lignin content determination which also affect on the oxygen delignification comparison between aspen and pine unbleached kraft pulps. Very different pattern was observed whether based on uncorrected conventional kappa number or based on corrected kappa number in oxygen delignification comparison. Lower kappa number aspen pulps showed poor response to oxygen delignification when kappa number was used as lignin determination method but better response with using the acid lignin method. Phenolic hydroxyl group in kraft pulps were also compared based on uncorrected or corrected kappa numberfor lignin content. Based on uncorrected kappa number, lower kappa number oxygen-delignified pulps had lower phenolic hydroxyl group. However, lower kappa number oxygen-delignified pulps showed much higher phenolic hydroxyl group based on the corrected lignin content. For accurate comparison for residual lignin properties from different pulps, lignin determination should be corrected from non-lignin components contribution to lignin.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.257-263
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• 2006

This paper examines the physico-chemical properties and structural features of thio lignin and alcohol lignin preparations extracted from fast-growing poplar wood. The lignin preparations were characterized using UV, IR and alkaline nitrobenzene oxidation methods. The yield was higher in thiolignin due to its preparation from wood under drastic alkaline conditions and almost the total amount of alkaline degraded lignin was precipitated except acid soluble lignin. In case of ethanol lignin, structural modifications were comparatively less and form a cream colored lignin more or less similar to its original natural color. The methoxyl values were higher due to syringyl unit present in hard wood lignin in addition to guaicyl unit present in soft wood. The higher values of methoxyl content of isolated lignin revealed that it was built up of high syringyl units. The elementary analysis, methoxyl group and hydroxyl groups were presented by $C_{9}$ formula indicated that it was made up of phenyl propane monomers. Nitrobenzene oxidation of thio lignin and ethanol lignin yield more or less the chromatograms of similar pattern, except difference in relative percentage. The ultra violet spectra of lignins were quite similar, irrespective of the source and method of isolation. Infrared spectroscopy studies of poplar deltoides, thio and ethanol lignin shown different absorption bands which have been utilized for structural investigations.

• Journal of the Korean Wood Science and Technology
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• 제24권3호
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• pp.45-50
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• 1996

Wood chips of oak(Quercus mongolica) and larch(Larix leptolepis) were treated with low pressure steaming explosion. Main components of exploded wood were separated with hot water and methanol extraction. Crude lignin separated from those extractives were purified and those chemical characteristics were investigated. And also, lignin adhesive was prepared from crude lignin and studied those chemical characteristics. The results can be summarized as follows ; 1. The purified lignin by Bj$\ddot{o}$kman's method from crude lignin is about 30% in exploded oak wood and is about 11% in exploded larch wood as a low amount. 2. The phenolic hydroxyl groups in the purified lignins are little higher than those of MWL and molecular weight distributions of the purified lignins are some lower than that of MWL. 3. Alkaline nitrobenzene oxidation products are very low in the clude lignin but those are increased in the purified lignin 4. The gravity of lignin resins(1.15 and 1.13) are a little lower than that of phenol resin(1.16) and the compressive shearing strength of lignin resins are higher than those of phenol resin.

• 펄프종이기술
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• 제35권3호
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• pp.74-78
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• 2003

The structural property of phenolic and non-phenolic lignin has an effect on the reaction rate of lignin by oxygen and chlorine dioxide respectively. Moreover, the undesirable degradation of cellulose followed by lignin degradation is influenced by chemical charge and reaction time. In this paper, several lignin model compounds were used to illuminate the interaction of oxygen and chlorine dioxide by varying the position of O and D(OD, DO, ODO and DOD), and gas chromatography method was used to investigate the degradation of lignin by determining the content of methoxyl groups in lignin. It was shown that structural properties of lignin models were more influential on the degradation and demethylation of lignin than the above combination. Combination of oxygen and chlorine dioxide, however, was more effective in degradation of lignin than only one stage, and three stages than two stages.

• KSBB Journal
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• 제15권1호
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• pp.22-26
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• 2000

Kraft Lignin which is produced abundantly in pulp industry, was chemically degraded into small oligomers and polymerized using horseradish peroxidase. Lignin acidolysis was optimized by controlling reaction time and HCI concentration. Acidolyzed lignin was polymerized and copolymers of acidolyzed lignin and phenol or p-cresol were synthesized. 70% of kraft lignin was degraded after acidolysis. Number average molecular weight of all lignin polymers were from 8,500 to 14,000 and did not show large difference. Differential scanning calorimeter analysis showed that acidolyzed lignin did not show any melting temparature under $300^{\circ}C$, which indicates that newly synthesized lignin polymers can be used in industry under mild condition.

• 펄프종이기술
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• 제36권5호
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• pp.62-68
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• 2004

The amount of non-lignin components in unbleached and oxygen-delignified kraft pulps and their impact on lignin determinations was investigated. The lignin analyses investigated were kappa number and Klason lignin in conjunction with acid-soluble lignin. The species investigated were loblolly pine, and aspen. The non-lignin components that impacted on lignin determination were residual extractives and hexenuronic acid in unbleached and oxygen-delignified kraft pulps. In the hardwoods, significant amounts of extractives remained after kraft pulping and oxygen delignification. These residual extractives in the hardwood pulps had an impact on the lignin determination, more so on the acid lignin method than kappa number. Hexenuronic acid only impacts on kappa number determination both softwood and hardwood pulps, not on acid lignin. Hexeneuronic acid contributed as lignin content more in aspen than pine pulps, and more in oxygen-delignified than unbleached kraft pulps. Impact of hexenuronic acid on should be corrected both softwood and hardwood pulps for accurate kappa number.

• 한국의류학회지
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• 제41권3호
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• pp.517-526
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• 2017

The biodegradation and water absorption properties of lignin/poly(vinyl alcohol) (PVA) nanofibrous webs are investigated. Lignin/PVA nanofibrous webs containing 0, 50, and 85wt% of lignin were prepared via an electrospinning process to observe the effect of the lignin concentration on the biodegradability and water absorption properties of lignin/PVA nanofibrous webs. The morphology of the materials was examined by field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). To understand the wetting behavior and hydrophilic nature of the electrospun lignin/PVA nanofibrous webs, the water absorbency, contact angle, and water uptake were examined. The enzymatic degradation of lignin/PVA nanofibrous webs was investigated using laccase by measuring total organic carbon (TOC) concentration over a course of 50 days. Water drops were absorbed immediately into all of the specimens. The water uptake of lignin/PVA nanofibrous webs increased as the amount of PVA in the lignin/PVA hybrid webs increased. The enzymatic degradation experiment indicated that the inherent biodegradability of lignin was retained after its transformation into nanofibers. Our findings imply that blending these two types of polymers is promising because it can lead to the development of a new range of multifunctional materials such as antimicrobial absorbent nanotextiles based on sustainable biopolymers.

• Journal of the Korean Wood Science and Technology
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• 제15권4호
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• pp.26-31
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• 1987

맹종죽, 왕대, 솜대 Dioxane Lignin의 UV, IR spectrum의 특징(特徵)을 조사(調査)하여 본 바, 그 결과(給果)를 요약하면 다음과 같다. 1. UV spectrum에 있어서는 일반적(一般的)인 Lignin spectrum과 같이 Maximum peak, Shallow minium peak, Minimum peak의 3개소(個所)를 보였는데 Max. peak는 210nm 부근(附近), Shallow peak는 260-270nm에, Minimum peak는 280nm부근(附近)에 있었다. 2. 280nm부근(附近)의 Minimum peak는 Lignin이 갖는 특징적(特徵的)인 peak로서 일반(一般) 침엽수재(針棄樹材) Lignin이나 활엽수(闊葉樹) Lignin과는 달리 282-285nm에서 흡광도(吸光度)가 꼭 같아 아주 완만한 peak 를 보여 주었다. 3. IR spectrum에 있어서는 방향핵(芳香核) 흡수대(吸收帶)는 $1550cm^{-1}$ 부근(附近)에 있고 1040-$1130cm^{-1}$부근(附近)과 1230-$1275cm^{-1}$에서의 Spectrum 형태(形態)는 활엽수(闊葉樹)에 가깝고 침엽수재(針葉樹材) Lignin의 spectrum과는 상반되는 모습을 보여 주었다.