• 전력전자학회:학술대회논문집
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• 전력전자학회 2019년도 전력전자학술대회
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• pp.459-460
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• 2019

The performance dynamics of battery is very sensitive to operating conditions (i.e temperature, load current, and state of charge). A model developed based on certain conditions may perform well under the similar conditions but can not accurately predict the performance for changing conditions. Thus, a generalized model is needed which can accurately emulate the battery dynamic behavior under all conditions. In addition, the components of the model should relate to the physicochemical processes that occur inside the battery. Electrochemical impedance curve shows better visible reflection of the processes inside battery as compared to voltage curve. The model trained for parameterization using neural network has better generalization than simple curve fitting. Thus, this study proposes recurrent neural network based parameterization of the Lithium ion battery model followed by impedance based identification.

• 한국세라믹학회지
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• 제53권3호
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• pp.282-287
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• 2016

This study involves enhancing the performance of the $Na(Li,Ti)O_2$ system as an Na-ion battery anode with the addition of Mg, which partially replaces Li ions. We perform both computational and experimental approaches to achieve a higher reversible capacity and a faster transport of Na ions for the devised system. Computational results indicate that the $Na(Li,Mg,Ti)O_2$ system can provide a lower-barrier path for Na-ion diffusion than can a system without the addition of Mg. Experimentally, we synthesize various $Na_z(Li_y,Mg_x,Ti)O_2$ systems and evaluate their electrochemical characteristics. In agreement with the theoretical study, Mg addition to such systems improves general cell performance. For example, the prepared $Na_{0.646}(Li_{0.207}Mg_{0.013}Ti_{0.78})O_2$ system displays an increase in reversible capacity of 8.5% and in rate performance of 13.5%, compared to those characteristics of a system without the addition of Mg. Computational results indicate that these improvements can be attributed to the slight widening of the Na-$O_6$ layer in the presence of Mg in the $(Li,Ti)O_6$ layer.

• 반도체디스플레이기술학회지
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• 제21권3호
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• pp.114-118
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• 2022

The stabilized all-solid-state battery structure indicate a fundamental alternative to the development of next-generation energy storage devices. Existing liquid electrolyte structures severely limit battery stability, creating safety concerns due to the growth of Li dendrites during rapid charge/discharge cycles. In this study, a low-dimensional graphene quantum dot layer structure was applied to demonstrate stable operating characteristics based on Li+ ion conductivity and excellent electrochemical performance. Transmission electron microscopy analysis was performed to elucidate the microstructure at the interface. The low-dimensional structure of GQD-based solid electrolytes has provided an important strategy for stable scalable solid-state lithium battery applications at room temperature. This study indicates that the low-dimensional carbon structure of Li-GQDs can be an effective approach for the stabilization of solid-state Li matrix architectures.

• 전기화학회지
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• 제13권4호
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• pp.246-250
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• 2010

In this study, nano-crystallized $Al_2O_3$ was coated on the surface of $LiFePO_4$ powders via a novel dry coating method. The influence of coated $LiFePO_4$ upon electrochemical behavior was discussed. Surface morphology characterization was achieved by transmission electron microscopy (TEM), clearly showing nano-crystallized $Al_2O_3$ on $LiFePO_4$ surfaces. Furthermore, it revealed that the $Al_2O_3$-coated $LiFePO_4$ cathode exhibited a distinct surface morphology. It was also found that the $Al_2O_3$ coating reduces capacity fading especially at high charge/discharge rates. Results from the cyclic voltammogram measurements (2.5-4.2 V) showed a significant decrease in both interfacial resistance and cathode polarization. This behavior implies that $Al_2O_3$ can prevent structural change of $LiFePO_4$ or reaction with the electrolyte on cycling. In addition, the $Al_2O_3$ coated $LiFePO_4$ compound showed highly improved area-specific impedance (ASI), an important measure of battery performance. From the correlation between these characteristics of bare and coated $LiFePO_4$, the role of $Al_2O_3$ coating played on the electrochemical performance of $LiFePO_4$ was probed.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 1998년도 제1회 총회 및 추계학술발표회
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• pp.83-83
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• 1998

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2003년도 전지기술심포지움
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• pp.121-140
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• 2003

• 전력전자학회지
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• 제24권5호
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• pp.36-39
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• 2019

• 전기전자학회논문지
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• 제24권4호
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• pp.1098-1103
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• 2020

본 논문은 리튬 이온 이차 전지의 전기적 실험 및 전기화학적 모델링을 통한 배터리 수명 상태(SOH)의 추정 방법을 다룬다. 배터리 전기적 노화 실험을 통하여 실제 배터리 수명 상태를 확인하기 위하여 전류 적산법을 사용한다. 전기적 실험에서 도출한 내부저항 값을 사용하여 SOH를 추정하며, 전기화학 모델링에서 사이클 수의 증가에 따른 SEI Layer의 변화를 통해 SOH를 추정한다. 실제 배터리 수명 상태를 포함한 세 가지 방법의 SOH 추정 방법에 가중치를 적용하여 새로운 SOH를 도출하며, 이는 전류적산법을 사용하여 구한 실제 값과의 오차를 줄여주어 추정 성능을 높인다.

• 전력전자학회논문지
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• 제21권2호
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• pp.175-181
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• 2016

In the conventional E-bike, a 42 V/10 A Li-ion battery drives a 24 V/10 A BLDC motor via a 6-switch PWM DC/AC inverter. The major problems of the conventional battery-fed motor drive systems are listed as follows. To charge the battery, an external battery charger (adapter) is required, which degrades the portability of E-bike users. In addition, given the high-frequency operation of the motor drive inverter, the switching losses are significant, which degrades the whole power efficiency. High-voltage batteries (42 V) require a complex battery management system (BMS), which degrades the reliability of the battery pack. In this paper, an embedded boost-converter battery charger for E-bikes is proposed. The variable output boost converter, which converts 16.8 V battery voltage to the required variable voltage of the inverter input, can use a low-voltage battery and thus improve the reliability of batteries. By varying the inverter input voltage via boost converter, a DC link voltage control method can be applied to reduce the switching frequency of the inverter, which improves the whole power efficiency. Given that the function of a flyback charger is integrated in the proposed boost converter, the portability of the E-bike user can be maximized by excluding an external adapter. The validity of the proposed circuit will be confirmed by operation mode analysis and simulation. Moreover, experimental results of integrative charger using Li-ion battery and 200 W motor test will be showed with a prototype sample as well.

• 한국표면공학회지
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• 제57권2호
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• pp.115-124
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• 2024

In advancing Li-ion battery (LIB) technology, the solid electrolyte interface (SEI) layer is critical for enhancing battery longevity and performance. Formed during the charging process, the SEI layer is essential for controlling ion transport and maintaining electrode stability. This research provides a detailed analysis of how vinylene carbonate (VC) influences SEI layer formation. The integration of VC into the electrolyte markedly improved SEI properties. Moreover, correlation analysis revealed a connection between electrolyte decomposition and battery degradation, linked to the EMC esterification and dicarboxylate formation processes. VC facilitated the formation of a more uniform and chemically stable SEI layer enriched with poly(VC), thereby enhancing mechanical resilience and electrochemical stability. These findings deepen our understanding of the role of electrolyte additives in SEI formation, offering a promising strategy to improve the efficiency and lifespan of LIBs.