• Title/Summary/Keyword: leather finishing

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Effect of Coated Polypyrrole Content on the Properties of Polypyrrole Coated Fabrics (폴리피롤 코팅 직물의 성질에 미치는 폴리피롤 함량의 영향)

  • Son, Seong-Ho;Lee, Young-Hee;Lee, Dong-Jin;Kim, Sung Yeol;Kim, Han-Do
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.92-100
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    • 2016
  • To chemically prepare polypyrrole(pPy) coated fabrics(silk, cotton and nylon fabrics), the fabrics were first soaked in 0.4M oxidant $FeCl_3$/0.06M dopant anthraquinone-2-sulfonic acid solution for 5min at room temperature, and subsequently soaked in a 0.4M monomer pyrrole aqueous solution for 5min at room temperature. The content(wt%) of coated pPy in the coated fabrics was controlled by the number of treatments(these two steps). This study examined the effect of the number of treatments/pPy content on the sheet resistance, mechanical/bending properties and color behaviors of pPy coated fabrics. The coated pPy content, sheet resistance(${\Omega}$/square) and color strength(K/S) of pPy coated fabrics increased sharply with increasing number of treatments up to 20 times, while the increase slowed down afterward. The tensile strength, elongation at break and lightness($L^*$) decreased with increasing number of treatments. The tensile modulus and bending rigidity of coated fabrics increased significantly with increasing number of treatments/coated pPy content. This indicated that the flexibility of coated fabrics decreased considerably.

Dyeing Properties of Ultra-fine Nylon Suede Non-woven Fabric with Sulphur Black Dye by Pad-steam Process (흑색 황화염료와 초극세사 나일론 스웨이드 부직포 직물의 Pad-steam 염색 및 염색성 평가)

  • Kim, Min Seok;Jung, Dae-Ho;Lee, Mikyung;Ko, Jae Wang;Lee, Jeong Hoon;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.211-222
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    • 2017
  • In this study, we investigated the dyeing properties of the ultra-fine nylon suede non-woven fabric with Sulphur black dye regarding to the effect of dye concentrations, reducing agent contents, sodium carbonate contents, antioxidant contents, immersion temperature and exposure time in air by pad-steam process. The optimal conditions of dyeing for the ultra-fine nylon suede non-woven fabric were determined with dye concentration of 30% o.w.f., reducing agent content of $9{\sim}13g/{\ell}$, sodium carbonate content of $1{\sim}4g/{\ell}$, antioxidant content of $1{\sim}5g/{\ell}$, immersion temperature of $70^{\circ}C$, exposure time of 20 minutes in air and immersion time of 1 minute, respectively. Meanwhile, the colorfastness to washing, the colorfastness to light, and the colorfastness to perspiration for dyed ultra-fine nylon suede non-woven fabric were achieved in the range of 4-5 grades. The formaldehyde and arylamine were not detected on the ultra-fine nylon suede non-woven fabric by KC tests.

Characteristics and Release Behaviors of Aromatic Poly(vinyl acetate) Nanoparticles Prepared by Emulsification-Diffusion Technique (유화-확산법에 의해 얻어진 폴리(비닐 아세테이트) 나노 방향 입자의 특성 및 방출 거동)

  • Sohn, Sung-Ok;Lee, So-Min;Kim, Yun-Mi;Ghim, Han-Do
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.177-183
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    • 2007
  • In this study, nano-sized poly(vinyl acetate) (PVAc) particles containing lavender oil as a core material were prepared by using emulsification-diffusion method. Effects of experimental parameters on the characteristics and the release behavior were examined with a field emission- scanning electron microscope, an electrophoretic light scattering spectrophotometer, a visible spectrophotometer and a high performance liquid chromatography The resulting aromatic particles could be prepared in nano-sized globular shapes with the mean particle size of 224 nm by controlling the experimental conditions. From the evaluation of release properties of aromatic PVAc nanoparticles with or without PVA coating, it was found that the aromatic particles coated with PVA show more sustaining and stable release behaviors. Our research on aromatic PVAc nanoparticles could be applied for durable fragrant finishing for textiles, leather products and so on.

A Study on the Base Material Specific and Processing Methods of Recycled New Materials in Space (실내공간에 사용되는 재활용 신재료의 소재 및 가공방법 연구)

  • Seo, Ji-Eun;Jeong, Hee-Jeong
    • Korean Institute of Interior Design Journal
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    • v.21 no.3
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    • pp.22-30
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    • 2012
  • Nowadays the issue of environmental pollution and ecological destruction is not a simple issue but an important issue to be continuously considered. It is deemed that a study for recycled new materials is immediately required and this study is to analyze features and processing methods of new materials which can be used to interior space. We found the recycled new materials used for space through researching various web sits. And then we analyzed what the base materials are and classified that base materials are whether natural or artificial of the recycled materials. We classified processing methods of the recycled new materials after researching general processing methods. The result of this study would be an important material to the research and development of new finishing materials with consideration of environment and to the research for a guideline of applicable new materials. The results of this study are as follows : First, we could classify widely 2 categories into natural material and artificial material and then 10 subcategories into metal, glass, wood, rubber, stone, plastic, leather or fabric, ceramic, concrete and so on, and analyzed that which material is mostly used and whether it is single material or multiple material. In order to analyze the feature of processing method. Second, we could classify into 4 categories such as junction, surface process, molding, and insert, and found out which processing method is applied based on objects of research. Third, as an analysis result of the recycled new material feature, in order to develop various new materials, it is required to study on combination and application of 2 materials or more rather than single material. Four, as a analysis result of the processing method feature, I would like to suggest that development and application of various processing methods are required. Especially, it is necessary to grope for a way to develop new functional materials for interior space through a systemic research and analysis of processing method of other fields. Furthermore, a way to reuse recycled new materials should be considered in a stage of selection and application of processing method.

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Comparative Study of Mechanical and VOC Properties According to Manufacturing Conditions of Glass Fiber/Bamboo Fiber/PP Composites (유리섬유/대나무섬유/PP 복합재의 제조 조건에 따른 기계적 및 VOC 특성 비교 연구)

  • Lee, Su-kyoung;Park, Tae-sung;An, Seung-kook
    • Textile Coloration and Finishing
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    • v.33 no.3
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    • pp.153-160
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    • 2021
  • In this study, composite materials were prepared by varying the content of glass fiber and bamboo fiber in PP/glass fiber/bamboo fiber. Experiments were conducted to confirm the mechanical properties(tensile, impact and burst strength) and volatile organic compound content of the bamboo fiber composite prepared under these conditions. An improvement in the main properties was observed at a fiber content of 30wt%. When the fiber fraction was increased above 30wt%, the mechanical properties tended to decrease due to the agglomeration of fibers at higher load fractions. In addition, the content of volatile organic compounds increased as the content of bamboo fibers increased, which is thought to be due to the volatile organic compounds generated during the manufacturing process of the composite material being present in the composite material without escaping from the pores of the bamboo fibers and volatilizing at a certain temperature. As a result of confirming the physical properties of the composite, it is considered that the optimal mixing condition is 30wt% of bamboo fiber for the composite produced by varying the amount of bamboo fiber composite. In the future, it is thought that follow-up experiments to confirm and improve the pre-treatment conditions for reducing the content of volatile organic compounds in the manufactured composite material are possible.

Preparation and Properties of Eco-friendly Waterborne Polyurethane-urea Primer for Thermoplastic Polypropylene Applied to Automobile Interiors (자동차 내장재용 열가소성 폴리프로필렌에 적용되는 선처리제용 친환경 수분산 폴리우레탄-우레아의 제조 및 성질)

  • Shin, Jong Sub;Park, Jin Myeong;Lee, Young Hee;Kim, Han Do
    • Clean Technology
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    • v.20 no.3
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    • pp.232-240
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    • 2014
  • The significance of thermoplastic polyolefin polypropylene (PP) lies in its potential to replace polyvinyl chloride (PVC), the most widely used material for automobile interiors (door trim, dash board), which discharges harmful compounds in certain conditions. Another benefit of PP (0.855 amorphous - 0.946 crystalline $g/cm^3$) is its low density compared to that of PVC ($1.1-1.45g/cm^3$), which reduces vehicle weight. Market demand for eco-friendly water-based adhesive/coating material is rising significantly as a substitute for solvent-based adhesive/coating material which emits VOC and causes harmful working conditions. Under such context, in this study, a series of eco-friendly waterborne polyurethane-urea primer (a paint product that allows finishing paint to adhere much better than if it were used alone) for hydrophobic PP were prepared from different mix of DMPA content, NCO/OH molar ratio, various wt% of silicone diol and various soft segment content, among which DMPA of 21 mole %, NCO/OH molar ratio of 1.2, modified silicone diol of 5 wt% and soft segment content of 73 wt% led to good adhesion strength. Additionally, the incorporation of optimum content of additives (0.5 wt% dispersing agent, 0.5 wt% levelling agent, 1.5 wt% antifoaming agent, 3.0 wt% matting agent) into the optimum waterborne polyurethane-urea also enabled good stability, levelling, antifoaming and non-glossy.