• Title/Summary/Keyword: leaking gas

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Chemical Disaster of Methyl Isocyanate Leakage (화학물질 누출에 의한 대량재해 - Methyl Isocyanate 누출을 중심으로 -)

  • Yang, Hyuk-Jun;Choi, Jung-Myung;Yoo, Dong-Jun
    • The Korean Journal of Emergency Medical Services
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    • v.3 no.1
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    • pp.7-19
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    • 1999
  • Background : We are in the edge of some human made disasters such as hazardous materials and air pollution, for example, the world news reported that the city of Bhopal, India had serious victims related with a leaking out of the chemical materials, Methyl Isocyanate and many people in India were killed by. These situations many people who live in this world are world are worrying about are not others, but just ours and people consider about that kind of the disasters are the possible situation to happen to all the people. Therefore, we performed this basic study to recognize the risk of Methyl Isocyanate leak accident and to prepare local disaster plan with EMS system. Method : Trace 8.0, a simulation software made by the U.S. company Safer System was used as a tool to estimate the diffusion distance, area and its victims at the concentrations of 0.02ppm, 0.2ppm 5ppm respectively for an assumed B-city of 2 hundred thousands population count in which was presumed 500kg Methyl Isocyanate gas to leak out. Results : 1. During 1 hour, maximum diffusion distances of 0.02ppm 0.2ppm and 5ppm were 5.41km, 1.61km and 0.29km respectively on the plume impact. 2. Maximum population counts influenced by Methyl Isocyanate gas at the concentrations of 0.02ppm 0.2ppm and 5ppm were 40838, 4346 and 222 on the plume impact, while those were 138238, 17261 and 1588 on the vulnerability impact, respectively. 3. Therefore, 17261 persons must put on respiratory device and 138283 persons must be evacuated to safety place within 1 hour. Conclusions : Only small amount leak of Methyl Isocyanate may cause tremendous chemical disaster in urban area, so its disaster plan must be prepared with an accident simulation program and Material Safety Data Sheets(MSDS). Especially, nearby emergency center of an industrial complex must have a strong position about preparation of chemical disaster plan and perform a disaster dill of hazardous material accident annually.

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A Study on the Pyrolysis System Development for Oil Recovery from Waste Fishing Nets and Ropes (오일 회수를 위한 폐로프와 폐어망 열분해 장치 개발에 대한 연구)

  • Kim Yong-Seop;Yu Jeong Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.4 no.2
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    • pp.43-51
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    • 2001
  • Now our ocean environment pollution is very serious. Its harm hinders in marine breeding and the safe navigation of ships at the coast. We have used an assembly system for a measure taken against environment pollution like this. But, here are some problems awaiting solution. First, most of combustible materials among ocean waste are high polymer, so it is necessary some special equipment to incinerate them. In the process we can't overlook air pollution by exhaust gas. Also, when we reclaim these wastes, we remember that they can't be decomposed naturally and leaking water may pollute soil. Thus now a days new treatment method has been developed, it recycles and doesn't product secondary pollution materials by recovering oil from pyrolysis. For it, this study investigated chemicalㆍphysical properties of wastes. And it found condition of recovering the most oil. Also it probed that the variation of temperature raising speed affects the weight reduction characteristics of wastes. Also, while studying recovered oil by waste pyrolysis and the rate of non-condensing gas in accordance with the variation of temperature raising speed. Finally we had confidence the development of pyrolysis oil recovery would succeed because we carried out evaluation at an economic point of view about it.

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A Quantitative Risk Analysis of LPG Leaked During Cylinder Delivery (가스용기 운반 중 누출된 LPG의 정량적 위험 분석)

  • Kim B-J,;Park Ki-Chang;Lee Kuen-Won
    • Journal of the Korean Institute of Gas
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    • v.7 no.2 s.19
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    • pp.33-41
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    • 2003
  • There exists high hazard when transporting LPG as well as using, storing, and producing. For small scale LPG consumer, retailers deliver LPG to customers via a truck loading many LPG cylinders. Suppose there occurred a accident during LPG cylinder transfer, this could result in serious damages to the life and properties in the near or neighbor of the accident spot. In this regard, we made a quantitative risk analysis to estimate the possible damages and the probability through the identification of accidents causes and the simulation of the possible scenario. In this study, we made the Excel & Visual Basic computer program to perform quantitative LPG accident analysis. The simulation showed the following results. In case of UVCE(Unconfined Vapor Cloud Explosion), the effect within l0m of the accident spot showed very severe structural damages and even the accident can break the window glasses of the area of 150 m apart from accident spot. In case of TNT corresponding probit analysis, after 10 minutes LPG leaking, $75\%$ window glasses of 40 m distance was expected to be broken. And $16\%$ frames of 20m distance, $10\%$ frames of 40m distance was expected to be collapsed.

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Fire Examples Study of Intake and Exhaust System, Alternator Tuning and Inflow of Inflammables on Exhaust Part in a Car (자동차 흡배기장치, 발전기 튜닝 및 배기측 인화성 물질 유입에 관련된 화재사례 연구)

  • Lee, Il Kwon;Kook, Chang Ho;Suh, Moon Won;You, Chang Bae;Youm, Kwang Wook;Lim, Chun Moo;Jung, Dong Hwa
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.47-51
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    • 2014
  • This paper is to analyze and study the fire examples in respect of intake and exhaust, alternator tuning and inflow of inflammables on exhaust part in a car. In the first example, the driver diverted the intake and exhaust system for tuning of a car. Stopping a car to rest for moment, the flammable styrofoam scrap go into exhaust pipe that installed with exhaust manifold newly. It certified the fact that catched fire gradually, furthermore enlarged the fire by leaking fuel. In the second example, the driver enlarged the generator performance to divert the audio system in side room., it knew the fact that the electric wiring connected with generator gave the cause of outbreak a fire by overheating. In the third example, the serviceman replaced the engine oil using funnel-shaped, he put the a bottle of plastic pat onto engine cover carelessly. Consequentially, it found the fire occurrence in the engine room. Therefore, the driver never divert the intake and exhaust and generator construction of a car abnormally. Also, repairing and inspecting a car, the serviceman have a care to not occur the fire by inflammables.

A Study on Contents for Safety Training of the Thermal Power Plant to be Applied by Story Viewing (스토리 뷰잉(Story-viewing)을 적용한 화력발전분야 안전교육 콘텐츠 연구)

  • Kim, Yoo-sik;Min, Seol-hui;Seong, Yun-hak;Park, Yeong-jae
    • Fire Science and Engineering
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    • v.30 no.3
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    • pp.62-66
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    • 2016
  • There have been happening small and big fires due to the various causes in the thermal power plants which are the high risk buildings with the high possibility of big sizes of accidents, so the people in the power plants distribute the workers "the site action manuals in thermal power plants" and try to minimize the rate of disasters like fires through the regular education and training. However, in the Five Thermal Power Plants in Korea, there are no the standard of "the site action manuals" and Furthermore, the present educational manuals are mostly the hard copies with poor readability. So the standardization of the manuals are definitely needed. Therefore, in this research, we proceed the standardization of the manuals for the five areas of the site action manual s in the thermal power plants which are oil fires, electric fires, building fires, facility fires and gas leaking reaction SOP to improve the reaction power on the disasters in the power plants which are the national significant infrastructures, thus by using the manual, we propose the safety education contents for the thermal power plants based on the visualization technology using story-viewing method to complement the hard copy type disaster manuals.

Dynamics and die design in continuous and patch slot coating processes (Continuous 와 pattern slot 코팅 공정에서의 유동특성과 다이 설계)

  • Kim Su-Yeon;Shim Seo-Hoon;Shin Dong-Myeong;Lee Joo-Sung;Jung Hyun-Wook;Hyun Jae-Chun
    • Proceedings of the Korean Society of Rheology Conference
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    • 2006.06a
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    • pp.81-84
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    • 2006
  • Slot coating process, in continuous and patch modes, has been applied for the many precise coating products, e.g., flat panel displays and second batteries. However, manufacturing uniform coating products is not a trivial task at high-speed operations because various flow instabilities or defects such as leaking, bubbles, ribbing, and rivulets are frequently observed in this process. It is no wonder, therefore, that many efforts to understand the various aspects of dynamics and coating windows of this process have been made both in academia and industry. In this study, as the first topic, flow dynamics within the coating bead in slot coating process has been investigated using the one-dimensional viscocapillary model by lubrication approximation and two-dimensional model by Flow-3D software. Especially, operability windows in both 1D and 2D cases with various slot die lip designs have been successfully portrayed. Also, effects of process conditions like viscosity and coating gap size on slot coating window have been analyzed. Also, some experiments to find minimum coating thickness and coating windows have been conducted using slot die coater implemented with flow visualization device, corroborating the numerical results. As the second topic, flow dynamics of both Newtonian and Non-Newtonian fluids in patch or pattern slot coating process, which is employed in manufacturing IT products such as secondary batteries, has been investigated for the purpose of optimal process designs. As a matter of fact, the flow control in this system is more difficult than in continuous case because od its transient or time-dependent nature. The internal die and die lip designs for patterned uniform coating products have been obtained by controlling flow behaviors of coating liquids issuing from slot. Numerical simulations have been performed using Fluent and Flow-3D packages. Flow behavior and pressure distribution inside the slot die has been compared with various die internal shapes and geometries. In the coating bead region, efforts to reduce irregular coating defects in head and tail parts of one patterned coating unit have been tried by changing die lip shapes. It has been concluded that optimal die internal design gas been developed, guaranteeing uniform velocity distribution of both Newtonian and shear thinning fluids at the die exit. And also optimal die lip design has been established, providing the longer uniform coating layer thickness within one coating unit.

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Numerical Study on the Effect of Area Changes in Air Inlets and Vent Ports on the Ventilation of Leaking Hydrogen (급·배기구 면적 변화가 누출 수소 환기에 미치는 영향에 관한 수치해석적 연구)

  • Lee, Chang-Yong;Cho, Dae-Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.2
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    • pp.385-393
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    • 2022
  • Hydrogen has reduced greenhouse gas (GHG) emissions, the main cause of global warming, and is emerging as an eco-friendly energy source for ships. Hydrogen is a substance with a lower flammability limit (LFL) of 4 to 75% and a high risk of explosion. To be used for ships, it must be sufficiently safe against leaks. In this study, we analyzed the effect of changes in the area of the air inlet / vent port on the ventilation performance when hydrogen leaks occur in the hydrogen tank storage room. The area of the air inlet / vent port is 1A = 740 mm × 740 mm, and the size and position can be easily changed on the surface of the storage chamber. Using ANSYS CFX ver 18.1, which is a CFD commercial software, the area of the air inlet / vent port was changed to 1A, 2A, 3A, and 5A, and the hydrogen mole fraction in the storage chamber when the area changed was analyzed. Consequently, the increase in the area of the air inlet port further reduced the concentration of the leaked hydrogen as compared with that of the vent port, and improved the ventilation performance of at least 2A or more from the single air inlet port. As the area of the air inlet port increased, hydrogen was uniformly stratified at the upper part of the storage chamber, but was out of the LFL range. However, simply increasing the area of the vent port inadequately affected the ventilation performance.

A Study on the Manufacture of the Artificial Cardiac Tissue Valve (생체판의 제작 및 실험)

  • Kim, Hyoung-Mook;Song, Yo-Jun;Sohn, Kwang-Hyun
    • Journal of Chest Surgery
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    • v.12 no.4
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    • pp.383-394
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    • 1979
  • Treatment of valvular heart disease with valve replacement has been one of the most popular procedures in cardiac surgery recently. Although, first effort was directed toward the prosthetic valve, it soon became popular that bioprosthesis, the valvular xenograft, was prefered in the majority cases. Valvular xenograft has some superiority to the artificial prosthetic valve in some points of thromboembolism and hemolytic anemia, and it also has some inferiority of durability, immunologic reaction and resistance to Infection. Tremendous efforts were made to cover the inferiority with several methods of collection, preservation, and valve mounting of the porcine valve or pericardium of the calf, and also with surgical technique of the valvular xenograft replacement. Auther has collected 320 porcine aortic valves immediately after slaughter, and aortic cusps were coapted with cotton balls in the Valsalva sinuses to protect valve deformity after immersion in the Hanks' solution, and oxidation, cross-linking and reduction procedures were completed after the proposal of Carpentier in 1972. Well preserved aortic valves were suture mounted in the hand-made tissue valve frame of 19, 21, and 23 mm J.d., and also in the prosthetic vascular segment of 19 mm Ld. with 4-0 nylon sutures after careful trimming of the aortic valves. Completed valves were evaluated with bacteriologic culture, pressure tolerance test with tolerane gauge, valve durability test in the saline glycerine mixed solution with tolerance test machine in the speed of 300 rpm, and again with pathologic changes to obtain following results: 1. Bacteriologic culture of the valve tissue in five different preservation method for two weeks revealed excellent and satisfactory result in view of sterilization including 0.65% glutaraldehyde preservation group for one week bacteriologic culture except one tissue with Citobacter freundii in 75% ethanol preserved group. 2. Pressure tolerance test was done with an apparatus composed of V-connected manometer and pressure applicator. Tolerable limit of pressure was recorded when central leaking jet of saline was observed. Average pressure tolerated in each group was 168 mmHg in glutaraldehyde, 128 mmHg in formaldehyde, 92 mmHg in Dakin's solution, 48 mmHg in ethylene oxide gas, and 26 mmHg in ethanol preserved group in relation to the control group of Ringer's 90 mmHg respectively. 3. Prolonged durability test was performed in the group of frame mounted xenograft tissue valve with 300 up-and-down motion tolerance test machine/min. There were no specific valve deformity or wearing in both 19, 21, and 23 mm valves at the end of 3 months (actually 15 months), and another 3 months durability test revealed minimal valve leakage during pressure tolerance test due to contraction deformity of the non-coronary cusp at the end of 6 months (actually 30 months) in the largest 23 mm group. 4. Histopathologic observation was focussed in three view points, endothelial cell lining, collagen and elastic fiber destructions in each preservation methods and long durable valvular tolerance test group. Endothel ial cell lining and collagen fiber were well preserved in the glutaraldehyde and formaldehyde treated group with minimal destruction of elastic fiber. In long durable tolerance test group revealed complete destruction of the endothelial cell lining with minimal destruction of the collagen and elastic fiber in 3 month and 6 month group in relation to the time and severity. In conclusion, porcine xenograft treated after the proposal of Carpentier in 1972 and preserved in the glutaraldehyde solution was the best method of collection, preservation and valve mounting. Pressure tolerance and valve motion tolerance test, also, revealed most satisfactory results in the glutaraldehyde preserved group.

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