• Journal of the Korea Organic Resources Recycling Association
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• v.15 no.2
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• pp.81-88
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• 2007

A study on the removal of heavy metals using sawdust was performed. Among heavy metals such as lead, copper and cadmium ions, uptake capacity of lead ions was the highest as about 0.22 mmol/g-dry mass at pH 4. The surface condition and existence of lead ions onto the sawdust was confirmed by the FT-IR, SEM (Scanning Electron Microscopy), and EDX (Energy Dispersive X-ray) instrumental analyses. When 0.5g of sawdust was added to initial lead solution (100ppm) removal efficiency was approximately 90%. Isothermal adsorption curve for lead ions was described by the Langmuir model equation and experimental data well fitted to model equation. Most adsorption for lead ions was also completed within 60min and pH of lead solution from 5.8 to 4.5 decreased with time.

• Journal of The Korean Society of Agricultural Engineers
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• v.63 no.1
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• pp.11-25
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• 2021

The objective of this study was to analyze the impact of activation functions on flood forecasting model based on Artificial neural networks (ANNs). The traditional activation functions, the sigmoid and tanh functions, were compared with the functions which have been recently recommended for deep neural networks; the ReLU, leaky ReLU, and ELU functions. The flood forecasting model based on ANNs was designed to predict real-time runoff for 1 to 6-h lead time using the rainfall and runoff data of the past nine hours. The statistical measures such as R2, Nash-Sutcliffe Efficiency (NSE), Root Mean Squared Error (RMSE), the error of peak time (ETp), and the error of peak discharge (EQp) were used to evaluate the model accuracy. The tanh and ELU functions were most accurate with R2=0.97 and RMSE=30.1 (㎥/s) for 1-h lead time and R2=0.56 and RMSE=124.6~124.8 (㎥/s) for 6-h lead time. We also evaluated the learning speed by using the number of epochs that minimizes errors. The sigmoid function had the slowest learning speed due to the 'vanishing gradient problem' and the limited direction of weight update. The learning speed of the ELU function was 1.2 times faster than the tanh function. As a result, the ELU function most effectively improved the accuracy and speed of the ANNs model, so it was determined to be the best activation function for ANNs-based flood forecasting.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.36 no.5
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• pp.505-512
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• 2023

This study investigated crystal structures, microstructures, and electric-field-induced strain (EFIS) properties of Bi-based lead-free ferroelectric/relaxor composites. Bi_1/2Na_0.82K_0.18)_1/2TiO₃ (BNKT) as a ferroelectric material and 0.78Bi_1/2(Na_0.78K_0.22)_1/2TiO₃-0.02LaFeO₃ (BNKT2LF) as a relaxor material were synthesized using a conventional solid-state reaction method, and the resulting BNKT2LF powders were subjected to high-energy ball milling (HEBM) after calcination. As a result, HEBM proved a larger average grain size of sintered samples compared to conventional ball milling (CBM). In addition, the increased sintering time led to grain growth. Furthermore, HEBM treatment and sintering time demonstrated a significant effect on EFIS of BNKT/BNKT2LF composites. At 6 kV/mm, 0.35% of the maximum strain (S_max) was observed in the HEBM sample sintered for 12 h. The unipolar strain curves of CBM samples were almost linear, indicating almost no phase transitions, while HEBM samples displayed phase transitions at 5~6 kV/mm for all sintering time levels, showing the highest S_max/E_max value of 700 pm/V. These results indicated that HEBM treatment with a long sintering time might significantly enhance the electromechanical strain properties of BNT-based ceramics.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.146-146
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• 2022

A flash flood is one of the most hazardous natural events caused by heavy rainfall in a short period of time in mountainous areas with steep slopes. Early warning of flash flood is vital to minimize damage, but challenges remain in the enhancing accuracy and reliability of flash flood forecasts. The forecasters can easily determine whether flash flood is occurred using the flash flood guidance (FFG) comparing to rainfall volume of the same duration. In terms of this, the hydrological model that can consider the basin characteristics in real time can increase the accuracy of flash flood forecasting. Also, the predicted radar rainfall has a strength for short-lead time can be useful for flash flood forecasting. Therefore, using both hydrological models and radar rainfall forecasts can improve the accuracy of flash flood forecasts. In this study, FFG was applied to simulate some flash flood events in the Taehwa river basin by using of SURR model to consider soil moisture, and applied to the flash flood forecasting using predicted radar rainfall. The hydrometeorological data are gathered from 2011 to 2021. Furthermore, radar rainfall is forecasted up to 6-hours has been used to forecast flash flood during heavy rain in August 2021, Wulsan area. The accuracy of the predicted rainfall is evaluated and the correlation between observed and predicted rainfall is analyzed for quantitative evaluation. The results show that with a short lead time (1-3hr) the result of forecast flash flood events was very close to collected information, but with a larger lead time big difference was observed. The results obtained from this study are expected to use for set up the emergency planning to prevent the damage of flash flood.

• Journal of Environmental Health Sciences
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• v.29 no.2
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• pp.62-68
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• 2003

Differential pulse voltammetry (DPV) using nafion-coated glassy carbon electrodes modified with Tetren(tetraethylene pentamine)-glycerol showed sensitivity for determining lead (II) at low concentration. The Lead (II) was accumulated on the electrode surface by the formation of the complex in an open circuit, and the resulting surface was characterized by medium exchange, electrochemical reduction, and differential pulse voltammetry. Various experimental parameters, such as the composition of modifier, preconcentration time, pH of electrolyte (0.1 M acetate buffer), and parameters of differential pulse voltammetry, were optimized. The initial potential was applied for 50 s, the electrode was scanned from -0.9 to -0.3 V, and the anodic peak current was measured at -0.604 V $\pm$ 0.015 V (vs. Ag/AgCl). The calibration plot was obtained in the range 1.0$\times$10$^{-8}$ M~l.0$\times$10$^{-6}$ M with pH 4.5 buffer solution. The detection limit (3$\sigma$) it as low as 5.0$\times$ 10$^{-9}$ M. This method is applied to the determination of lead(II) in a certified reference material and the result agrees satisfactorily with the certified value.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.43-50
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• 1996

The adsorption charateristics of lead(II) ions on Aspergillus niger and Rhizopus arrhizus were investigated. Adsorption amount of A. niger and R. arrhizus was about 95 mg/g and 25 mg/g, respectively. These biomass was approached to adsorption equilibrium within reaction time of 1hr because of their high reactivity. The uptake of lead ion by A. niger was less sensitivity than it by R. arrhizus on the inhibition effect of alkali metals and the decreasing ratio of uptake of lead ion of A. niger and R. arrhizus by inhibition effect of alkali metals was 37% and 50%, respectively. In pre-treatment on these biomass, NaOH treatment was contributed high adsorption capacity to these biomass. Then, adsorption amount of A. niger and R. allhizus was increased about 25 mg/g and 10 mg/g, respectively. In isotherm for the adsorption of lead ion based on Freundlich equation, 1/n value of A. niger and R. ar고izus was calculated the range of 0.28-0.56 and 0.44-0.67, respectively.

• Bulletin of the Korean Chemical Society
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• v.26 no.1
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• pp.51-56
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• 2005

A PVC membrane electrode for lead ion based on 1-phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone (PQDBP) as ionophore was demonstrated. The optimum composition of the membrane was 30 wt% poly(vinyl chloride), 60 wt% dibutyl phthalate as a plasticizer, 4 wt% ionophore and 6 wt% sodium tetraphenylborate as additive. The electrode exhibits a Nernstian response (28.7 mV decade$^{-1}$) for Pb$^{2+}$ over a wide concentration range (1.0 ${\times}$ 10$^{-1}$ to 1 ${\times}$ 10$^{-6}$ M) with a detection limit of 6.0 ${\times}$ 10$^{-7}$ M. This sensor has a short response time and can be used for at least 2 months without any divergence in potentials. The proposed electrode could be used in a pH range of 3.0-6.0 and revealed good selectivities for Pb$^{+2}$ over a wide variety of other metal ions. It was successfully applied as an indicator electrode for the potentiometric titration of lead ion with potassium chromate and for the direct determination of lead in mine.

• Nuclear Engineering and Technology
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• v.55 no.5
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• pp.1783-1790
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• 2023

Barium Bismuth Oxide Borate (BBOB) has been synthesized for the first time using solution combustion technique. SEM analysis reveal flower shape of the nanoparticles. The formation of the nanoparticles has been confirmed through XRD & FTIR studies which gives the physical and chemical structure of the novel material. The UV light absorption is observed in the range 200-300 nm. The present study highlights the radiation shielding ability of BBOB for different radiations like X/Gamma rays, Bremsstrauhlung and neutrons. The gamma shielding efficiency is comparable to that of lead in lower energy range and lesser than lead in the higher energy range. The bremsstrauhlung exposure constant is comparably larger for BBOB NPs than that of concrete and steel however it is lesser than that of lead. The beauty of BBOB nanoparticles lies in, high absorption of radiations and low emission of secondary radiations when compared to lead. In addition, the neutron shielding parameters like scattering length, absorption and scattering cross sections of BBOB are found to be much better than lead, steel and concrete. Thus, BBOB nanoparticles are highly efficient in absorbing X/Gamma rays, neutrons and bremsstrauhlung radiations.

• Nuclear Engineering and Technology
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• v.56 no.4
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• pp.1213-1224
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• 2024

The liquid lead-bismuth cooled fast reactor has been in a single-phase, low-pressure, and high-temperature state for a long time during operation. Considering the requirement of calculation efficiency for long-term transient accident calculation, based on a homogeneous hydrodynamic model, one-dimensional heat conduction model, coolant flow and heat transfer model, neutron kinetics model, coolant and material properties model, this study used the fully implicit difference scheme algorithm of the convection-diffusion term to solve the basic conservation equation, to develop the transient analysis program NUSOL-LMR 2.0 for the lead-bismuth fast reactor system. The steady-state and typical design basis accidents (including reactivity introduction, loss of flow caused by main pump idling, excessive cooling, and plant power outage accidents) for the ABR have been analyzed. The results are compared with the international system analysis software ATHENA. The results indicate that the developed program can stably, accurately, and efficiently predict the transient accident response and safety characteristics of the lead-bismuth fast reactor system.

• Korean Architects
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• s.523
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• pp.13-13
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• 2012