• 제목/요약/키워드: lead metal

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Heavy Metal Biosorption and its Significance to Metal Tolerance if Streptomycetes

  • Park, Jae-young;Kim, Jae-heon
    • Journal of Microbiology
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    • 제40권1호
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    • pp.51-54
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    • 2002
  • Heavy metal adsorptions of four streptomycetes were compared with each other, Among the test strains, Streptomyces viridochromogenes showed the most efficient metal binding activity, which was carried out by cell wall as well as freeze-dried mycelium. An order of adsorption potential (zinc > copper > lead > cadmium) was observed in single metal reactions, whereas this adsorption order was disturbed in mixed-metal reactions. The metal adsorption reactions were very fast, pH dependent and culture age-independen, suggestive of a physico-chemical reaction between cell wall components and heavy metal ions. The metal tolerant stains presented the weakest adsorbing activity, indicating that the metal biosorption was not the basis of the metal tolerance.

포름알데히드에 의한 금속시편의 손상 특성 (Damage Characteristics of Metal Specimens by Formaldehyde)

  • 김명남;임보아;이선명
    • 보존과학회지
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    • 제31권3호
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    • pp.287-298
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    • 2015
  • 포름알데히드의 금속 손상은 보편적으로 알려진 것에 비해 손상농도와 손상정도의 정량화는 명확하지 않다. 본 연구는 금속시편(은, 구리, 철, 납, 황동)을 대상으로 가스부식시험기를 이용하여 포름알데히드 0.5, 1, 10, 100, 500ppm 농도에서의 손상, 손상농도에서 온 습도 조건에 따른 손상 가중, 손상농도에서 열화금속시편의 손상을 광학적, 화학적, 물리적 측정방법으로 평가하였다. 이 결과, 포름알데히드 농도 500ppm/day에서 납시편의 광학적, 화학적, 물리적 손상과 전체금속시편의 광학적 손상이 확인되었다. 기본조건($25^{\circ}C$, 50%), 고온조건($30^{\circ}C$, 50%)에서는 일부시편의 광학적 손상이 가중되었고, 고온 고습조건($30^{\circ}C$, 80%), 고습조건($25^{\circ}C$, 80%)에서는 납시편의 화학적 손상이 각각 2.8배, 1.3배 가중되었다. 열화금속시편의 포름산이온 농도 결과, 철시편, 황동시편의 부식 생성물은 포름알데히드 가스와 활발히 반응하는 것으로 나타났으며, 납시편의 표면 산화막은 포름알데히드 가스와의 반응을 감소시키거나 차단하는 것으로 확인되었다.

주석 함유 폐자원의 공정부산물 전처리 기술 (Development of Pre-treatment for Tin Recovery from Waste Resources)

  • 진연호;장대환;정항철;이기웅
    • 한국분말재료학회지
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    • 제21권2호
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    • pp.142-146
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    • 2014
  • Fundamental experiences have been studied for development of pre-treatment process of Sn by-products such as solders. Dry and wet separation/recovery processes were considered by the differences of physical properties. The by-products, which are analyzed by solder metal and oxides. The metal and oxide were simply separated by dry ball-milling process for 12 hours, after that recovery metal powder might be reusable as lead or lead-free solders. In terms of wet separation process, samples were dissolved in $HNO_3+H_2O_2$ and the precipitation were analyzed by $SnO_2$. Overall efficiency of recovery might be increasing via developing simple pre-treatment process.

Plating 및 Base metal의 Grain size에 따른 Whisker 성장 영향 분석 (Analysis of the effect on the whisker growth as grain size of plating and base metal)

  • 김수진;장미순;곽계달
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1337-1342
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    • 2008
  • The whisker grows at the plating of a lead frame so that it causes the serious problem like the short. To prove this case, many people have studied the cause and influence of the tin whisker growth. This study explains the grain size affects the growth of the whisker in the lead frame. By these studies about the whisker, the whisker growth is discovered by stresses generated by the intermetallic compound and CTE mismatch in both plating and base metal. The stresses or lattice defect generated in the plating process changes grain structure of plating. Consequently, these various stresses are stabilized by forming unspecified whiskers through lots of grain boundaries. Because the grain boundary is the path of the whisker growth, the smaller grain size exists, the more whiskers grow.

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골탄(bone char)의 중금속 제거 특성에 관한 연구 (A Study on Heavy Metal Removal Characteristics Using Bone Char)

  • 김재영;김환기
    • 상하수도학회지
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    • 제21권2호
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    • pp.253-258
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    • 2007
  • The adsorption capacity of bone char for lead, cadmium and zinc was studied in both single and binary multiple component systems. Equilibrium experimental studies have been performed to determine the sorption capacity of bone char for each metal ion. These have been analysed using single and multi-component equilibrum models. The results show that the sorption of metal ions for multi-component systems can be predicted reasonably well from the IAS theory with the Langmuir equation, the Freundlich and the Slip equation for metal ions.

Iron deficiency increases blood concentrations of neurotoxic metals in children

  • Kim, Yangho;Park, Sangkyu
    • Clinical and Experimental Pediatrics
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    • 제57권8호
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    • pp.345-350
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    • 2014
  • Iron deficiency affects approximately one-third of the world's population, occurring most frequently in children aged 6 months to 3 years. Mechanisms of iron absorption are similar to those of other divalent metals, particularly manganese, lead, and cadmium, and a diet deficient in iron can lead to excess absorption of manganese, lead, and cadmium. Iron deficiency may lead to cognitive impairments resulting from the deficiency itself or from increased metal concentrations caused by the deficiency. Iron deficiency combined with increased manganese or lead concentrations may further affect neurodevelopment. We recently showed that blood manganese and lead concentrations are elevated among iron-deficient infants. Increased blood manganese and lead levels are likely associated with prolonged breast-feeding, which is also a risk factor for iron deficiency. Thus, babies who are breast-fed for prolonged periods should be given plain, iron-fortified cereals or other good sources of dietary iron.

Plasma Membrane Transporters for Lead and Cadmium

  • Bressler Joseph P.;Olivi Luisa;Cheong Jae Hoon;Kim Yongbae;Bannon Desmond
    • 한국응용약물학회:학술대회논문집
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    • 한국응용약물학회 2004년도 Annual Meeting of the Korean Society ofApplied Pharmacology
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    • pp.50-61
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    • 2004
  • Lead and cadmium are potent environmental toxicants that affect populations living in Europe, Americas, and Asia. Identifying transporters for lead and cadmium could potentially 1 help us better understand possible risk factors. The iron transporter divalent metal transporter 1(DMT1) mediates intestinal transport of cadmium, and lead in yeast and fibroblasts overexpressing DMT1. In human intestinal cells knocking down expression of DMT1 attenuated uptake of cadmium and iron but not lead. A possible explanation is the expression of a second transporter for lead in intestine. In astrocytes, however, DMT1 appears to transport lead in an extracellular buffer at pH value. At neutral pH, transport was not mediated by DMT1 but rather by a transporter that is stimulated by bicarbonate and inhibited by 4,4'-diisothiocyanatodihydrostilbene-2,2'-disulfonic acid. The identity of this lead transporter is under study.

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Biosorption of lead by Laminaria japonica

  • Jung-Ho;Il-Bae;Hak-Sung
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.208-211
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    • 2003
  • Characteristics of biosorption of lead by marine algae, Laminaria japonica, were examined. The biosorption capacity of lead by L. japonica was achieved up to 30% of its own weight and proportional to the initial lead concentration. However, the opposite result was shown in different initial weight of biomass. Ion exchange reaction between lead ions and calcium ions was observed on lead biosorption with Ca-Ioaded biomass. Stoichiometric coefficient, which can represent the exchange ratio between metal ions and protons during elution process, was determined as 1.39. Therefore, it was concluded that the reaction between lead ions already attached in biomass and protons in bulk solution was not fully stoichiometric ion exchange relation at elution process.

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Lead-selective PVC Membrane Electordes Based on Bis(Crown ether)s

  • 오금철;강은철;정규성;팽기정
    • Bulletin of the Korean Chemical Society
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    • 제20권5호
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    • pp.556-558
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    • 1999
  • Lead-selective PVC membrane electrodes based on newly synthesized bis(crown ether)s containing 18-crown-6 moiety was prepared using standard PVC membrane composition. In order to monitor lead in environmental samples by lead sensor, especially good selectivity over alkali and alkaline earth metals has to be obtained. Thus, responses of the PVC membrane prepared with new bis(crown ether)s and Fluka ionophore V (crown ether) base to various cations include lead, alkali and alkaline earth metal ions were investigated for their use as a lead sensor. The polymeric liquid membrane based on trans-1 8-crown-6 ether exhibits the best overall potentiometric performances as a lead-selective electrode in terms of a wide linear dynamic range (between 10-6 and 10-2 M, Pb2+), excellent detection limit (less than 10-6 M) and good durability within limited error. The preferences of lead over other cations, such as Ag+, Hg2+, Na+, Ca2+ and even K+ in the aforementioned electrode are much better than the Fluka ionophore V system.

금속 몰드를 이용한 금속 분말의 온간 등가압 성형 (Densification Behavior of Metal Powder Under Warm Isostatic Pressing with a Metal Mold)

  • 박중구;김기태
    • 대한기계학회논문집A
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    • 제28권6호
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    • pp.838-847
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    • 2004
  • The effect of a metal mold on densification behavior of stainless steel 316L powder was investigated under warm isostatic pressing with a metal mold. We use lead as a metal mold and obtain experimental data of metal mold properties. To simulate densification behavior of metal powder, elastoplastic constitutive equation proposed by Shima and Oyane was implemented into a finite element program (ABAQUS) under warm die pressing and warm isostatic pressing with a metal mold. Finite element results were compared with experimental data for densification and deformation of metal powder under warm isostatic pressing and warm die pressing.