• Title/Summary/Keyword: lead & tin

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Flexible quantum dot solar cells with PbS-MIx/PbS-BuDT bilayers

  • Choe, Geun-Pyo;Yang, Yeong-U;Yun, Ha-Jin;Im, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.347.2-347.2
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    • 2016
  • Recently, in order to improve the performance of the colloidal quantum dot solar cells (CQDSCs), various efforts such as the modification of the cell architecture and surface treatment for quantum dot (QD) passivation have been made. Especially, the incorporation of halides into the QD matrix was reported to improve the performances significantly via passivating QD trap states that lower the life-time of the minority-carrier. In this work, we fabricated a lead sulfide (PbS) QD bilayer treated with different ligands and utilized it as a photoactive layer of the CQDSCs. The bottom and top PbS layer was treated using metal iodide ($MI_x$ and butanedithiol (BuDT), respectively. All the depositions and ligand treatments were carried out in air using layer-by-layer spin-coating process. The fabrication of the active layers as well as the n-type zinc oxide (ZnO) layer was successfully carried out on the bendable indium-tin-oxide (ITO)-coated polyethylene terephthalate (PET) substrate, which implies that this technique can be applied to the fabrication of flexible and/or wearable solar cells. The power conversion efficiency (PCE) of the CQDSCs with the architecture of $PET/ITO/ZnO/PbS-MI_x/PbS-BuDT/MoO_x/Ag$ reached 4.2 %, which is significantly larger than that of the cells with single QD (PbS-BuDT) layer.

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Two-Dimensional River Flow Analysis Modeling By Finite Element Method (유한요소법에 의한 2차원 하천 흐름 모형의 개발)

  • Han, Kun-Yeun;Kim, Sang-Ho;Kim, Byung-Hyun;Choi, Seung-Yong
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.425-429
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    • 2006
  • The understanding and prediction of the behavior of flow in open channels are important to the solution of a wide variety of practical flow problems in water resources engineering. Recently, frequent drought has increased the necessity of an effective water resources control and management of river flows for reserving instream flow. The objective of this study is to develop an efficient and accurate finite element model based on Streamline Upwind/Petrov-Galerkin(SU/PG) scheme for analyzing and predicting two dimensional flow features in complex natural rivers. Several tests were performed in developed all elements(4-Node, 6-Node, 8-Node elements) for the purpose of validation and verification of the developed model. The U-shaped channel of flow and natural river of flow were performed for tests. The results were compared with these of laboratory experiments and RMA-2 model. Such results showed that solutions of high order elements were better accurate and improved than those of linear elements. Also, the suggested model displayed reasonable velocity distribution compare to RMA-2 model in meandering domain for application of natural river flow. Accordingly, the developed finite element model is feasible and produces reliable results for simulation of two dimensional natural river flow. Also, One contribution of this study is to present that results can lead to significant gain in analyzing the accurate flow behavior associated with hydraulic structure such as weir and water intake station and flow of chute and pool.

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Analysis of Flat Board-shaped Lacquer ware Excavated from Daho-ri in Changwon, Korea (다호리 출토 판상 칠기의 재질 분석)

  • Kim, Soochul;Park, Minsoo;Yun, Eunyoung
    • Conservation Science in Museum
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    • v.13
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    • pp.33-36
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    • 2012
  • Analysis of Flat board-shaped Lacquer ware excavated from Daho-ri was conducted. The result of species identification is identifed as Pinus spp. As a result of microscopic observation, lacquer fragment is consist of 5 layers and its thickness is about 100 ㎛. Infrared spectroscopy of the lacquer ware revealed that they had a very similar absorption band as refined lacquer, confirming that they were painted with lacquer. Result of Analysis for Circular metal ornament is alloy smelted by tin and lead. It is called Pewter. While The species of wooden objects investigated until now is broad-leaved tree; the species of flat board-shaped lacquer ware is conifer.

A Basic Study on the Fabrication of W-M(M=Cu, Sn, Ni) System High Density Composite (I) (W-M(M=Cu, Sn, Ni)계 고밀도 복합재료 제조에 관한 기초연구(I))

  • Jang, Tak-Soon;Hong, Jun-Hee;Lee, Tae-Haeng;Koo, Jar-Myung;Song, Chang-Bin
    • Journal of Powder Materials
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    • v.16 no.4
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    • pp.268-274
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    • 2009
  • For the purpose of obtaining basic information on the development of lead-free materials, a high density composites (a) W-Cu, (b) W-Sn (c)W-Cu-Sn and (d) W-Cu-Ni were fabricated by the P/M method. The particle size of used metal powders were under 325 mesh, inner size of compaction mould was $\phi8$ mm, and compaction pressure was 400 MPa. A High density composite samples were sintered at a temperature between $140^{\circ}C$ and $1050^{\circ}C$ for 1 hour under Ar atmosphere. The microstructure, phase transformation and physical properties of the sintered samples were investigated. As the results, the highest relative density of 95.86% (10.87 g/$cm^3$) was obtained particularly in the sintered W-Cu-Sn ternary system sample sintered at 450 for 1hr. And, Rockwell hardness (HRB) of 70.0 was obtained in this system.

Imaging Characteristics of Plastic Scintillating Fiber Screens for Digital Mammography

  • Choi, Won-Young;Walker, James K.;Jing, Zhenxue
    • Journal of Biomedical Engineering Research
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    • v.17 no.2
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    • pp.165-172
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    • 1996
  • A scanning slot digital mammography system Luing a plastic scintillating fiber screen (SFS) is currently being developed To improve the x-ray interaction efficiency and absorption efficiency of an SFS, high Z elements can be added into the scintillating fiber core. In this paper, we investigated theoretically the zero spatial frequency detective quantum efficiency, DQE(0), and modulation transfer function, MTF(f), of three 2 cm thick SFSs made of polystyrene, polystyrene loaded with 5% by weight of lead, and polystyrene Loaded with 10% by weight of tin scintillating fibers. X-ray interaction efficiency, scintillating light intensity distributions and line spread functions were generated using Monte Carlo simulation. DQE(0) and MTF(f) were computed for x-ray energies ranging from 15 to 50 keV. Loading high Z elements into the SFS markedly increased the DQE(0). For x-ray energies used for mammovaphy, DQE(0) values of both high Z element loaded SFSs are about a factor of three higher than the DQE(0) of an Min-R screen. At mammographic x-ray energies, MTF(f) values of all three SFSs are Venter than 50% at 25 Ip/mm spatial frequency, and were found to be dominated by the 20 um individual scintillating fiber diameter used The results show that both hiP DQE(0) and spatial resolution can be achieved with the high Z element loaded SFSs, which make these SFSs attractive for use in a scanning slot detector for digital mammography.

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The study of Germanium analysis by Adsorption Stripping Voltammetry (흡착벗김 전압전류법을 이용한 게르마늄 분석에 관한 연구)

  • Yun, Young Ja;Jeong, David;Namgung, Mi Ok
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.171-179
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    • 1995
  • This is an analytical study of germanium by adsorption stripping squarewave voltammetry. Tannic acid was used as a ligand. The accumulation potential was -0.2V, accumulation time was carried out for 60 second under constant stirring, followed by a 20 second quiescent period, and frequency was 10Hz. A hanging mercury drop electrode was used as a working electrode and acetate buffer solution, pH=4.5, as supporting electrolyte. The proper conditions of ligand for germanium analysis was established. The effect of metal ions(lead, cupper, silicon, tin, gallium) on germanium peak was also studied.

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A Study on Reliability Assessment of Ag-free Solder (무은 솔더의 신뢰성 평가에 관한 연구)

  • Kim, Jong-Min;Kim, Gi-Young;Kim, Kang-Dong;Kim, Seon-Jin;Jang, Joong Soon
    • Journal of Applied Reliability
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    • v.13 no.2
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    • pp.109-116
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    • 2013
  • The solder is any of various fusible alloys, usually tin and lead, used to join metallic parts that provide the contact between the chip package and the printed circuit board. Solder plays an important role of electrical signals to communicate between the two components. In this study, two kinds of Ag-free solder as sample is made to conduct the thermal shock test and the high humidity temperature test. Low resistance is measured to estimate crack size of solder, using daisy chain. The low speed shear test is also performed to analyze strength of solder. The appropriate degradation model is estimated using the result data. Depending on the composition of solder, lifetime estimation is conducted by adopted degradation model. The lifetime estimated two kinds of Ag-free solder is compared with expected lifetime of Sn-Ag-Cu solder. The result is that both Ag-free composition are more reliable than Sn-Ag-Cu solder.

Reviews on Natural Resources in the Arctic: Petroleum, Gas, Gas Hydrates and Minerals

  • Yoon, Jong-Ryeol;Kim, Yea-Dong
    • Ocean and Polar Research
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    • v.23 no.1
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    • pp.51-62
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    • 2001
  • The Arctic consists of numerous sedimentary basins containing voluminous natural resources and two of the world's major oil and gas producing areas. The western Siberia Basin in the Arctic region has the largest petroliferous province with an area of 800 ${\times}$ 1,200 km and produces more than 60% of total Russian oil production. The North Slope of Alaska produces about 20% of the U.S. output, i.e., 11% of the total U.S. consumption. Being small compared to those regions, the Canadian Northwest Territories and the Pechora Basin in Russia produce only fair amount of oil and natural gas. There are also many promising areas in the northern continental shelf of Russia. In addition to Russia, Svalbard and Greenland have been investigated for oil and gas. Gas hydrates are widespread in both permafrost regions and arctic continental shelf areas. The reserves of gas hydrates in the Arctic Ocean are about 20${\sim}$32% of total estimated amounts of gas hydrates in the world ocean. Mineral mining is well developed, especially in Russia. The major centers are located around the Kuznetsk Basin and Noril'sk. They are major suppliers of gold, tin, nickel, copper, platinum, cobalt, iron ore, coal as well as apatite. There are also some minings of lead-zinc in Alaska and Arctic Canada.

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Workers' Possible Exposure Hazards in Solar Energy Industries (결정질 실리콘 기반 태양광산업에서의 근로자노출 가능 유해인자)

  • Jang, Jae-Kil;Park, Hyunhee
    • Journal of the Korean Solar Energy Society
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    • v.33 no.5
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    • pp.24-33
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    • 2013
  • Renewable energy industries, including sola cell plants, has been ever increasing ones for reducing fossil fuel consumption and strengthening national energy policy. In this paper we tried to identify occupational health hazards in solar cell-related industries operated in Korea. Poly silicon, silicon ingot and wafer, solar cell and module are major processes for producing solar cells. Poly silicon operations may cause hazards to workers from metal silicon, silanes, silicon, hydro fluoric acid and nitric acid. Solar cells could not be constructed without using metals such as aluminum and silver, acids such as hydrofluoric acid and nitric acid, bases such as sodium hydroxide and potassium hydroxide, and solvent and phosphorus chloride oxide. Workers in module assembly process may exposed to isopropanol, flux, solders that contain lead, tin and/or copper. To prevent occupational exposure to these hazards, it is essential to identify the hazards in each process and educate workers in industries with proper engineering and administrative control measures.

Effects of Metallaic Dialkyldithiophosphates on Lubricating Oil (금속 디알킬디티오인산염이 윤활유에 미치는 영향)

  • Moon Tak Jin;Kwon Oh Kwan
    • Journal of the Korean Chemical Society
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    • v.23 no.1
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    • pp.52-58
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    • 1979
  • Metallic dialkyldithiophosphates are widely used in lubricating oils as antioxidant and antiwear agents. Zinc DDTP are used most frequently in lubricating oil. Zinc, lead, tin and cobalt DDTP were prepared with primary and secondary alkyl groups. The effects of oxidation, thermal stability, metal corrosion and antiwear of each metallic DDTP prepared were studied. Based on the results, cobalt DDTP has a significant effect of antiwear on chrome alloy steel comparing with the other metallic DDTP. Also cobalt DDTP has a characteristic property of thermal sensitivity in its color, which was shown by the color change from brown to blue over a certain temperature. Another phenomenon obtained was that all metallic DDTP initiates the effect of antioxidation at the time of reaching to a certain effective acid concentration in lubricating oil.

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