• Title/Summary/Keyword: lead(II)

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Mode of Occurrences and Depositional Conditions of Stannite from the Yeonhwa 1 Mine (제 1 연화광산에서 산출되는 황석석의 산출상태와 생성환경)

  • Chung, Je-Il
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.279-287
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    • 1993
  • In the zinc-lead (-silver) ores from the Yeonhwa 1 mine, stannite is widespread, though minor in amount It may be divided largely into two species on the basis of its chronological order during mineralization; i.e., stannite I formed in Stage I, and stannite II formed in Stage II. Also, the mineral may be classified into two types according to the difference of its associates; i.e., stannite 1 closely associated with sphalerite, and stannite 2 with galena. In general, the stannite 1 tends to predominate in the stannite I and the stannite 2 in the stannite II. The formation temperature and sulphur fugacity of stannite 1 deduced from stannite-sphalerite geothermometry are from 280 to $350^{\circ}C$ and from $10^{-11}$ to $10^{-8}$ atm.

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Development of the Vehicle Diagnosis Program Using OBD-II (OBD-II 시스템을 활용한 자동차 고장진단 프로그램 개발)

  • Yoo, Changhyun;Ko, Yongseo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.3
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    • pp.271-278
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    • 2015
  • This paper develops an OBD Diagnostic Program (Program) using Visual Studio (C#), which was used to diagnosis malfunction information from OBD-II system vehicles. We accomplished this using the Program, Diagnostic tests, Board (STN1110), FTDI Basic Cable, Mini USB Cable, OBD Data Cable, and both hybrid and regular vehicles. The Program tests real-time data output, DTC output, sensor value output, engine RPM, waveform data, OBD type check, PID inspection, and whole monitoring. We found vehicles used in this research had 19 PIDs, which was within OBD-II regulations. We also gathered data on control and diagnostic code regulated by OBD-II system, such as, sensor output value, engine RPM, DTC output, each PID analytic value, OBD type, fuel mode, and whole monitoring result value. Using the data collected through the Program appropriately can lead to more effective diagnostic practices and contribute to education.

Applicability of Composite Beads, Spent Coffee Grounds/Chitosan, for the Adsorptive Removal of Pb(II) from Aqueous Solutions

  • Choi, Hee-Jeong
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.536-545
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    • 2019
  • An experiment was conducted to evaluate the adsorptive removal of Pb(II) from an aqueous solution using a mixture of spent coffee grounds and chitosan on beads (CC-beads). Various parameters affecting the adsorption process of Pb(II) using CC-beads were investigated. Based on the experimental data, the adsorption kinetics and adsorption isotherms were analyzed for their adsorption rate, maximum adsorption capacity, adsorption energy and adsorption strength. Moreover, the entropy, enthalpy and free energy were also calculated by thermodynamic analysis. According to the FT-IR analysis, a CC-bead has a very suitable structure for easy heavy metal adsorption. The process of adsorbing Pb(II) using CC-beads was suitable for pseudo-second order kinetic and Langmuir model, with a maximum adsorption capacity of 163.51 (mg/g). The adsorption of Pb(II) using CC-beads was closer to chemical adsorption than physical adsorption. In addition, the adsorption of Pb(II) on CC-beads was exothermic and spontaneous in nature. CC-beads are economical because they are inexpensive and also the waste can be recycled, which is very significant in terms of the continuous circulation of resources. Thus, CC-beads can compete with other adsorbents.

Indirect Determination of Nitrite by Flame Atomic Absorption Spectrometry Using a Lead(IV) Dioxide Oxidant Microcolumn

  • Noroozifar, Meissam;Khorasani Motlagh, Mozhgan;Taheri, Aboozar;Homayoonfard, Marjan
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.875-880
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    • 2006
  • A new, simple and fast flow injection analysis (FIA) method has been developed for the indirect determination of nitrite. The proposed indirect automatic method is based on the oxidation of nitrite to nitrate using a lead(IV) dioxide oxidant microcolumn where the flow of the sample through the microcolumn reduces the $PbO_2$ solid phase reagent to Pb(II), which is measured by flame atomic absorption spectrometry. The absorbance of Pb(II) are proportional to the concentration of nitrite in the samples. The calibration curve was linear up to 30 mg $L ^{-1}$, with a detection limit of 0.11 mg $L ^{-1}$ for a 400 mL injected sample volume and a sampling rate of about 80 $h ^{-1}$. The results exhibit no interference from the presence of large amounts of ions. The developed procedure was found to be suitable for the determination of nitrite in foodstuffs and wastewaters. A relative standard deviation better than 0.9% was obtained in a repeatability study. The reliability of the method was established by parallel determination against the standard method.

Integrated Storage Function Model with Fuzzy Control for Flood Forecasting (II) - Theory and Proposal of Model - (홍수예보를 위한 통합저류함수모형의 퍼지제어 (II) - 이론의 모형의 수립 -)

  • Lee, Jeong-Gyu;Kim, Han-Seop
    • Journal of Korea Water Resources Association
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    • v.33 no.6
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    • pp.701-709
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    • 2000
  • Integrated storage function model (ISFM) is applied to some rainfall-runoff events of the selected basins in Korea to show validity of the proposed model. Comparing the numerical results of the model with the field measurements, the simulated hydrographs and peak flood discharges for the most part showed good agreements, except the occurrence time of the peak discharges which showed a bit discrepancy, and they showed it was very hard to have a sufficient lead-time to forecast the flood when the upstream inflow of the channel reach was more dominant than the inflow from the residual watershed of the channel.hannel.

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Mineralogy and Iron Chemistry of Garnets and Clinopyroxenes in the Skarn Deposits, the Hambaek Geosyncline Belt, Korea (함백지향내의 스카른광상에서 산출되는 석류석과 단사휘석의 광물학과 철화학)

  • 최진범;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.4 no.2
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    • pp.119-128
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    • 1991
  • In the southern limb of the Hambaek geosyncline belt, large-scaled skarn deposits are developed in the Cambro-Ordovician sedimentary rocks of the Chosun Supergroup. They are the Sangdong tungsten deposit, Geodo iron-copper deposit, Yeonhwa I and II lead-zinc deposits, and Ulchin zinc-lead deposit, all of which are associated with various skarn minerals. Though different occurrences and paragenesis are found in different deposits, most skarn deposits always have skarns of garnet (andradite-grossular series) and clinopyroxene(heden-bergite-diopside series). Andradite and hedenbergite are Fe-dominant members, but show different oxidation states, that is, Fe3+ for andradite and Fe2+ for hedenbergite. According to iron chemistry and log([Fe/Al]gd/[Fe/Mg]cpx) derived from equilibrium reactions, the diopside-andradite and hedenbergite-grossular pairs suggest the oxidized state (dian type) and reduced state (hegro type), respectively. Among skarn deposits developed in the Hambaek geosynline, it can be classified that the Geodo and Yeonhwa I skarns are of dian type, while the Sangdong, Yeonhwa II, and Ulchin deposits are of hegro type. This classification is not applicable to all kinds of skarn deposits, but may be applicable to such deposits as are more controlled by oxygen fugacity than composition of skarn fluid.

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Determining PGAA collimator plug design using Monte Carlo simulation

  • Jalil, A.;Chetaine, A.;Amsil, H.;Embarch, K.;Benchrif, A.;Laraki, K.;Marah, H.
    • Nuclear Engineering and Technology
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    • v.53 no.3
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    • pp.942-948
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    • 2021
  • The aim of this work is to help inform the decision for choosing a convenient material for the PGAA (Prompt Gamma Activation Analysis) collimator plug to be installed at the tangential channel of the Moroccan Triga Mark II Research Reactor. Two families of materials are usually used for collimator construction: a mixture of high-density polyethylene (HDPE) with boron, which is commonly used to moderate and absorb neutrons, and heavy materials, either for gamma absorption or for fast neutron absorption. An investigation of two different collimator designs was performed using N-Particle Monte Carlo MCNP6.2 code with the ENDF/B-VII.1 and MCLIP84 libraries. For each design, carbon steel and lead materials were used separately as collimator heavy materials. The performed study focused on both the impact on neutron beam quality and the neutron-gamma background at the exit of the collimator beam tube. An analysis and assessment of the principal findings is presented in this paper, as well as recommendations.

The exposure of lead and cadmium and the dental caries (납 및 카드뮴의 노출과 치아우식증 발생요인과의 관련성)

  • Won, Young-Soon;Kwon, Ho-Jang;Rho, Sang-Chul;Chae, Yoo-Mi;Kim, Young-Soo;Bae, Kwang-Hak
    • Journal of Korean society of Dental Hygiene
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    • v.12 no.4
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    • pp.695-705
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    • 2012
  • Objectives : The purpose of this study is to evaluate the appearance of having relationship between the exposure to lead and cadmium and the dental caries targeting adults in the Republic of Korea. Methods : The study was designed as a cross-sectional study, using the data of the Fourth Korea National Health and Nutrition Examination Survey. The subjects as 1,966 people, who were confirmed the appearance of dental caries among 1,991 people of having been offered the heavy-metal concentration in blood. Statistical analysis was conducted using SPSS 19.0, according to complex sampling design. Results : As a result of multi-variate analysis on factors of dental caries, in Model I without correction, the gender, age, educational level, appearance of lifelong smoking, daily toothbrushing frequency, appearance of using dental floss, and subjective oral health status were recognized as important factors. In Model II with correction of gender and age, the educational level, daily toothbrushing frequency, and subjective oral health status were recognized as statistically significant factors. In Model III with correction of all factors, the gender, age, educational level, appearance of using dental floss, and subjective oral health status were functioning as statistically significant factors. As a result of statistically analyzing relationship between the exposure to lead and cadmium and the dental caries targeting adults, it was analyzed that there is no significant correlation. However, in case of lead, the tendency of being grown the cross ratio of dental caries could be examined in model I, which didn't correct disturbance factor, model II, which corrected gender and age, and model III, which corrected all variables of disturbance factor. Conclusions : The exposure to lead and cadmium was indicated to have no relationship with adults' dental caries. However, a continuous research of relationship was considered to be necessary by using Korea National Health and Nutrition Examination Survey, which is surveyed in the future.

On the Occurrences of Pyrrhotite from the Yeonhwa 1 Mine, Korea

  • Chung, Jae-Il;Lee, Young-Up
    • Journal of the Korean earth science society
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    • v.24 no.1
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    • pp.36-45
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    • 2003
  • This study is made for examining the characteristics of the lead-zinc deposition from the mineralogy of pyrrhotite at the Yeonhwa 1 Mine, Korea. The pyrrhotite of the Yeonhwa 1 mine is divided two species; the pynhotites I and II. The pyrrhotite I that represents the product in Stage II mineralization is characterized by hexagonal pyrrhotite occurring as the mechanical mixtures of hexagonal and monoclinic phases with various proportion. These mixtures might be formed from 'primary' hexagonal pyrrhotite by the subsequent retrograde reaction and/or by the influence of later mineralization in Stage III. Whereas the pyrrhotite II crystallized out in later Mineralization Stage III (hydrothermal stage) is always monoclinic variant with ferromagnetic properties; no two phase mixtures have been recognized.

Electrolytic Treatment of Heavy Metallic ion Wastewater by BPBE Cell (BPBE Cell에 의한 중금속함유폐수처리)

  • 장철현;박재주;박승조;김수생
    • Environmental Analysis Health and Toxicology
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    • v.4 no.3_4
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    • pp.29-59
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    • 1989
  • For the purpose of electrolytic treatment of wastewater containing various heavy metals, the BPBE Cell of batch and continuous type was considered and experimented. Some results from this study were summarized as follows: 1. When the artificial wastewater containing 500 mg/l of the concentration of various heavy metallic ion was electrolyzed in BPBE Cell of batch type, the removal efficicency was over 95% in cadmiun (II), lead (II), chromium (Ⅵ) and over 85% in copper (II), chromium (III). 2, As granular activated carbon packed in BPBE Cell, coconut shell was superior to lignite and the removal efficiency was the highest when the activated carbon was 4/6 mesh, the voltage was 20V. 3. When the heavy metallic ion in wastewater was electrolyzed in BPBE Cell of continuous type, about 1,000mg of heavy metal per 1kg of coconut sell could be removed. 4. The treatment method of heavy metallic ion in wastewater by BPBE Cell cost less than in the former chemical treatment method and the coconut shell packed in BPBE Cell could be regenerated by chemical method.

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