• Title/Summary/Keyword: leaching components

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Evaluation of Leaching Stability of Preservative Treated Wood in the Seawater for the use of a Fish-breeding Ground (해양어초사용을 위한 방부목재의 해수 용탈성 평가)

  • Lee, Myung Jae;Lee, Dong-Heub;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.3 s.131
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    • pp.53-63
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    • 2005
  • This study attempted to obtain the basic data of utilizable possibility of preservative treated wood as a material used in a marine ranch. To evaluate the leaching stability of CCA-, CCFZ-, and ACQ-treated woods in seawater, the specimens treated with 2% and 3% (w/v) of CCA, CCFZ, and ACQ were exposed to deionized water, synthetic seawater and natural seawater for 41 days and then each component released was periodically determined. There was little amount of copper and chromium released from CCA-treated wood exposed in both deionized and seawater. Although relatively large amount of arsenic was released from CCA-treated wood, the release rate in seawater was lower than that in deionized water. The release rate of chromium and zinc from CCFZ-treated wood were somewhat greater in deionized water, but lower in seawater than in deionized water. Retention level and salinity of synthetic seawater had little effect on the release rate of components. The ACQ-treated wood had greater copper release than CCA- and CCFZ-treated wood, and the amount of copper released did not affected by leaching media used.

Physico-Chemical Characteristics of Municipal Solid Waste Generated from T City and Leaching Characteristics of the Incineration Ash (T시 생활폐기물의 물리화학적 특성 및 소각재 용출특성)

  • Park, Joon-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.2
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    • pp.84-92
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    • 2010
  • This research was conducted to investigate physico-chemical characteristics of municipal solid waste (MSW) generated from T City, Gangwon-do and leaching characteristics of the incineration ash. From the results, bulk density of MSW in T city was $231kg/m^3$. Combustible and incombustible components were in 94.0% and 6.0%, respectively. Food waste and papers in combustible component occupied 32.3% and 41.2%. Water, volatile solids, and ash content were 41.3%, 50.5%, and 8.2%. C, H, O, N, S, and Cl showed 51.4%, 6.3%, 26.7%, 1.1%, 0.2%, 0.5%, respectively. Low heating value (2,704 kcal/kg) of T city was similar to 2,764 kcal/kg of Chuncheon and was 1,000 kcal/kg higher than 1,467~1,584 kcal/kg of the past Kuro-gu and Koyang city. The specification of leaching characteristics of the incineration ash were within the Korean regulation standard.

Recovery of Gallium and Indium from Waste Light Emitting Diodes

  • Chen, Wei-Sheng;Chung, Yi-Fan;Tien, Ko-Wei
    • Resources Recycling
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    • v.29 no.1
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    • pp.81-88
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    • 2020
  • Recovery of gallium and indium from waste light emitting diodes has been emphasized gradually owing to high content of gallium and indium. This study was established the recovery of gallium (Ga3+) and indium (In3+) from waste gallium nitride was contained in waste light-emitting diodes. The procedure was divided into the following steps; characteristic analysis, alkaline roasting, and leaching. In characteristic analysis part, the results were used as a theoretical basis for the acid leaching part, and the chemical composition of waste light emitting diodes is 70.32% Ga, 5.31% Si, 2.27% Al and 2.07% In. Secondly, with reduction of non-metallic components by alkaline roasting, gallium nitride was reacted into sodium gallium oxide, in this section, the optimal condition of alkaline roasting is that the furnace was soaked at 900℃ for 3 hours with mixing Na2CO3. Next, leaching of waste light emitting diodes was extremely important in the process of recovery of gallium and indium. The result of leaching efficiency was investigated on the optimal condition accounting for the acid agent, concentration of acid, the ratio of liquid and solid, and reaction time. The optimal condition of leaching procedures was carried out for 2.0M of HCl liquid-solid mass ratio of 30 ml/g in 32minutes at 25℃ and about 96.88% Ga and 96.61% In were leached.

FILLER LEACHING FROM NANOFILLER-CONTAINED COMPOSITE RESIN IN VARIOUS MEDIA (수종의 저장 용액에서 나노필러를 함유한 복합레진의 필러의 용출량에 관한 연구)

  • Yang, Kyu-Ho;Heo, Su-Kyung;Choi, Nam-Ki;Kim, Seon-Mi
    • Journal of the korean academy of Pediatric Dentistry
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    • v.36 no.1
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    • pp.62-70
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    • 2009
  • The objective of this study was to measure the leaching of filler (Si, Ba) from nanofiller-contained composites (Palfique Estelite $sigma^{{R}}$ (Tokuyama Dental Corp., Tokyo, Japan), $Z-350^{{R}}$ (3M ESPE, USA), Ceram X duo $E3^{{R}}$, $D3^{{R}}$ (Dentsply, Konstanz, Germany)) under different conditions. The samples used for the study of leachable components were made by insertion of the material into a circular mold, 10 mm in diameter and 3.0 mm high. Each specimen was placed in a disposable polystyrene vial containing 5 mL of distilled water, artificial saliva or 0.1N NaOH and kept in an oven at $37^{\circ}C$. ; water and artificial saliva - 150 days, 0.1N NaOH - 15days. Inductively coupled plasma atomic emission spectroscopy (ICP-AES) was used to determine the amount of Si and Ba in the test solutions. 1. Filler leaching was significantly great in 0.1N NaOH among all samples(p<.0.001). 2. When samples were stored in the distilled water, Estelite showed the lowest amount of Si leaching. When samples were stored in the artificial saliva, Z-350 showed the lowest amount of Si leaching. 3. There were significant differences in filler leaching between 3 storage medias and composite resins(p<.0.001). 4. Si and Ba leaching occurred in greater proportion when samples were stored in the artificial saliva than distilled water. 5. There were significant interactions in monthly filler leaching between leaching in artificial saliva and in distilled water, as well as the interaction between storage medium and filler(p<.0001). These results indicate that a continuous filler leaching of nanofiller-contained composite resins was in storing aqueous solutions under over time.

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Changes in chemical composition and physiological activity of Jeju-Tatary buckwheat tea according to leaching temperature (제주 타타리메밀의 침출 조건에 따른 제주 타타리메밀침출차의 이화학적 특성 및 생리활성)

  • Hyun-A Ko;Hyun Ju Park;Inhae Kang
    • Journal of Applied Biological Chemistry
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    • v.65 no.4
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    • pp.421-427
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    • 2022
  • In this study, Jeju Tatary buckwheat tea's chemical composition and physiological activities were compared according to the leaching temperature (60, 80, 100 ℃). As the leaching temperature is increased, the degree of browning is induced. However, there was no significant change in pH. The total polyphenol content was higher at 80 ℃ than at 60 ℃ leaching temperature, but significantly decreased at 100 ℃ leaching temperature (60 ℃: 17.06 mg GA/g, 80 ℃: 20.09 mg GA/g, 100 ℃ :18.45 mg GA/g). There were high content of flavonoid and rutin as the leaching temperature increased. Consistently, 2,2-diphenyl1-picrylhydrazyl (DPPH) radical scavenging activity and tyrosinase inhibitory activity were significantly higher with increasing temperature (DPPH % inhibition: 60 ℃: 41.88%, 80 ℃: 46.01%, 100 ℃: 46.80%/tyrosinase inhibitory activity: 60 ℃: 9.38%, 80 ℃: 22.94%, 100 ℃: 28.17%). However, there was no significant difference in DPPH radical scavenging activity between 80 and 100 ℃. A cytotoxicity test was performed by treating with Jeju Tatary buckwheat extract into mouse macrophage cells (Raw264.7). 100 and 200 ㎍/mL treatment (100 ℃ extract) were significantly upregulated the survival rate, but there was no significant difference in other concentrations. Collectively, most of the bioactive components, antioxidant activity, and tyrosinase inhibitory activity were induced as the leaching temperature increased. However, the content of polyphenols which are known to have antioxidant activity, was significantly reduced at 100 ℃ leaching temperature. Several reports have demonstrated that leaching at too high temperature lowered the overall acceptability, so the optimal leaching condition of Tatary Buckwheat is 80 ℃, 5 min in this study.

BIOGEOCHEMICAL ACTIVITIES OF MICROORGANISMS IN MINERAL TRANSFORMATIONS: CONSEQUENCES FOR METAL AND NUTRIENT MOBILITY

  • Gadd, Geoffrey M.
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 2002.10a
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    • pp.39-61
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    • 2002
  • Bacteria and fungi are fundamental biotic components of natural biogeochemical cycles for metals and metalloids and play important roles in dissolution, precipitation, oxidation and reduction processes. Some processes catalyzed by microorganisms also have important applications in environmental biotechnology in the areas of ore leaching and bioremediation.

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Biogeochemical Activities of Microorganisms in Mineral Transformations: Consequences for Metal and Nutrient Mobility

  • Gadd, Geoffrey-M.;Burford, Euan-P.;Fomina, Marina
    • Journal of Microbiology and Biotechnology
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    • v.13 no.3
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    • pp.323-331
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    • 2003
  • Bacteria and fungi are fundamental biotic components of natural biogeochemical cycles for metals and metalloids, and play important roles in dissolution, precipitation, oxidation and reduction processes. Some processes catalyzed by microorganisms also have important applications in environmental biotechnology in the areas of ore leaching and bioremediation.

경작조건별 농경지 비료성분의 거동특성에 관한 칼럼 연구

  • 최태범;이기철;장윤영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.279-281
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    • 2003
  • This study is intended to give information on agricultural nonpoint source pollution and transport related to fertilizer application and irrigation practice. Field-simulated soil columns were set up and leaching studies on fertilizer components such as nitrogen and phosphorus were performed. Nitrogen and phosphorus in the leachate showed different trends in each column and nonpoint source pollution in agricultural areas may be expected to depend on planted crops, soil conditions, and climate as well as irrigation and fertilizing management.

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Pre-leaching of Lithium and Individual Separation/Recovery of Phosphorus and Iron from Waste Lithium Iron Phosphate Cathode Materials (폐리튬인산철 양극재로부터 리튬의 선침출 및 인과 철의 개별적 분리 회수 연구)

  • Hee-Seon Kim;Boram Kim;Dae-Weon Kim
    • Clean Technology
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    • v.30 no.1
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    • pp.28-36
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    • 2024
  • As demand for electric vehicles increases, the market for lithium-ion batteries is also rapidly increasing. The battery life of lithium-ion batteries is limited, so waste lithium-ion batteries are inevitably generated. Accordingly, lithium was selectively preleached from waste lithium iron phosphate (LiFePO4, hereafter referred to as the LFP) cathode material powder among lithium ion batteries, and iron phosphate (FePO4) powder was recovered. The recovered iron phosphate powder was mixed with alkaline sodium carbonate (Na2CO3) powder and heat treated to confirm its crystalline phase. The heat treatment temperature was set as a variable, and then the leaching rate and powder characteristics of each ingredient were compared after water leaching using Di-water. In this study, lithium showed a leaching rate of approximately 100%, and in the case of powder heat-treated at 800 ℃, phosphorus was leached by approximately 99%, and the leaching residue was confirmed to be a single crystal phase of Fe2O3. Therefore, in this study, lithium, phosphorus, and iron components were individually separated and recovered from waste LFP powder.

A Study on the Au Recoverability from Mongolian Tailings (몽골 광미로부터 Au 회수 가능성에 관한 연구)

  • Ko, Chin-Surk;Burentogtokh, Togtokhmaa;Lee, Jong-Ju;Park, Cheon-Young
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.1
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    • pp.41-51
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    • 2020
  • The purpose of this study was to investigate the possibility of eco-friendly/efficient recovery of valuable resources, such as Au from mine tailings, which are environmental pollutants in the Mongolian mine sector. For this purpose, this study selected 4 place of mine tailings of the Mongolian mines sector and carried out mineralogy evaluation of the valuable resources in the tailings. In this study, flotation was performed to separate and concentrate valuable resources in the tailings. Microwave nitric acid leaching was used to leach the valuable resources contained in the sample and to improve the Au grade. Chloride leaching attempted to leach Au from the leaching residues. XRD analysis of the tailings samples showed that most of the samples consisted of silicate minerals. As a result of confirming the content of the element through XRF analysis, the SiO2 content was very high, the Fe2O3 content was 2.32-4.23%, and the content of PbO, CuO and ZnO components were all within 2%. As a result of flotation for the tailings samples, the recovery of Au was the highest in Bayanairag sample (95.38%). As a result of microwave nitric solution experiment on Au concentrate sample obtained by flotation, the content of Au in the microwave nitrate leaching residue increased by 12.15% from 192.72 g/ton to 216.14g/ton in Khamo sample, the highest increase was 57.58% in Bayanairag sample. TCLP tests on tailings generated after flotation showed dissolution characteristics within EPA. Chloride leaching test was performed to recover Au from solid residues. The leaching rate was 87.43-89.35% within 10 minutes. For Khamo sample, 100% Au was leached after 60 minutes of leaching time. Therefore, in order to process the tailings continuously generated in Mongolia, applying the same process as the present study is expected to effectively recover the valuable resources contained in the tailings.