• Title/Summary/Keyword: leached residue

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Application of Adsorption Isotherms for Manganese Nodule-Cadmium Interaction (망간단괴-Cd 상호작용에 대한 등온흡착식 적용)

  • 전영신;김진화;김동수
    • Resources Recycling
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    • v.8 no.1
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    • pp.37-43
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    • 1999
  • Studies have been conducted for the purpose of using manganese nodule and residue remained after extracting valuable metals [mm it as the adsorbent of cadmium wastewater. The study observed the adsorption percentage according to initial cadmium concentration and interpreted each adsorption systems by applying the Freundlich, Langmuir, and Temkin isotherms. The adsorption amounts increased as the initial concentration at cadmium ion increased, whereas the adsorption percentage decreased. Linearity was shown when applied to the Freundlich and Langmuir isotherms. The k value which evaluates the adsorption capacity of adsorbent in Freundlich isotherm, turned out to be 11.72, the highest in case of manganese nodule. The Xm value, the maximum adsorption amount of the adsorbate that adsorbs as a monolayer in Langmuir isotherm of manganese nodule, was estimated as 0.16, representing higher value compared with those of leached residue, leached residue-raw manganese nodule mixture, and activated carbon.

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Study on the Development of Food Tourism Products Based on the Local Food and Folktale (아산 지역특산물과 설화를 활용한 Food Tourism 제품 개발)

  • Kim, Mi-Hye
    • Journal of the Korean Society of Food Culture
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    • v.33 no.3
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    • pp.217-228
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    • 2018
  • This study aimed to develop unique, local "food tourism" products by finding specialized items that combine tourist attractions, such as folklore or hot springs. Traditional ingredients were analyzed with ancient texts for the methods of research. A brand image was made possible utilizing hot spring lore and other regional stories. The tofu products were produced using local specialty beans. Products, such as tofu residue cake and willow bean tea, were made with the tofu residue. After the products were completed, the sensory test began at the local tourist attraction. Asan City's food tourism product willow tofu was made with beans that were given as compensation for building the Onyang temporary palace according to the Annals of the Joseon Dynasty and the willow tree that appears in Sunshin Lee's anecdotes. After the preference test between normal tofu and willow-extract tofu was conducted to measure the product potential of willow tofu, among the sample extracts, 0.04% of the willow extract showed a significant preference. The hot spring tofu-residue cake was baked using tofu residue and vegetable olive oil to substitute for animal oil, such as butter, or margarine. After the sensory test targeting the adults was conducted, both products displayed significant product potential with average scores above 5.0. Willow tree bark, which has antioxidation and anti-inflammatory effects without a bitter taste or strong smell, was proven to bean appropriate ingredient for leached tea. The nutty flavor of leached tea was enhanced by roasted green kernel black beans and willow tree bark. The sensory test showed that the leached tea and tofu received a high preference rating on both color and flavor.

Test Run of Pilot Plant for Recycling of the Leached Residue in the Processing of Waste Aluminum Dross (알루미늄 폐드로스 침출잔사 처리 파일롯트 플랜트 시운전 결과)

  • 박형규;이후인
    • Resources Recycling
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    • v.13 no.3
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    • pp.50-57
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    • 2004
  • Waste aluminum dross is a major waste in the aluminum scrap smelters and its components are mostly alumina and remained metallic aluminum. In the process to extract the remained aluminum from the waste dross by leaching with sodium hydroxide solution, residue is generated and its main component is alumina. This residue could be recycled into ceramic materials such as alumina castable refractories by going through a series of treatments such as washing, drying and roasting. In this study, a pilot plant was constructed and tested to demonstrate the developed technology. One thousand tons of waste aluminum dross could be processed, and about seven hundred tons of ceramic materials produced in the demonstration line. From the test run of the pilot plant, although it was confirmed that the developed technology could be applied to commercialization, several technical improvements were found to be necessary for reducing impurities such as Na, Fe and for reforming drying equipment.

A Study on the Leaching of Valuable Metals from Spent Silver-Oxide Battery (폐산화은 전지로부터 유가금속의 침출에 관한 연구)

  • 박경호;손정수
    • Resources Recycling
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    • v.4 no.1
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    • pp.46-51
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    • 1995
  • After removal of mercury in the silver oxide batteries with the distillation process, the leaching of valuable metals from the residue was studied. The distilled residue was reacted with the various HNO, concentration, reactlon temperature, readion time and pulp density. It was found that the optimum condition for leachmg was 2N HNO,, 40-60% reaction temperature, 6 hours reaction tlme and 10g/200ml pulp density. More than 99% of silver and zinc were dissolved in this process while less than 50% of iron and nickel were leached

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Reduction Leaching of Manganese Dioxide Ore Using Black Locust as Reductant in Sulfuric Acid Solution

  • Xue, Jianrong;Zhong, Hong;Wang, Shuai;Li, Changxin;Li, Jinzhong;Wu, Fangfang
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.509-516
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    • 2015
  • We investigated the reduction leaching process of manganese dioxide ore using black locust as reductant in sulfuric acid solution. The effect of parameters on the leaching efficiency of manganese was the primary focus. Experimental results indicate that manganese leaching efficiency of 97.57% was achieved under the optimal conditions: weight ratio of black locust to manganese dioxide ore (WT) of 4:10, ore particle size of $63{\mu}m$, $1.7mol{\cdot}L^{-1}\;H_2SO_4$, liquid to solid ratio (L/S) of 5:1, leaching time of 8 h, leaching temperature of 368 K and agitation rate of $400r{\cdot}min^{-1}$. The leaching rate of manganese, based on the shrinking core model, was found to be controlled by inner diffusion through the ash/inert layer composed of associated minerals. The activation energy of reductive leaching is $17.81kJ{\cdot}mol^{-1}$. To conclude the reaction mechanism, XRD analysis of leached ore residue indicates manganese compounds disappear; FTIR characterization of leached residue of black locust sawdust shows hemicellulose and cellulose disappear after the leaching process.

Preparation of Castable Refractories by Recycling of Aluminum Dross (알루미늄드로스를 재활용한 캐스타블내화물 제조)

  • Park Hyungkyu;Lee Hooin;Lee Jinyoung
    • Resources Recycling
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    • v.12 no.3
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    • pp.46-53
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    • 2003
  • Recycling of aluminum dross is an important issue in the secondary aluminum industries. In this study, aluminum dross generated in the domestic secondary aluminum industry was processed to use it as raw material for producing alumina refractories. Sample dross was classified according to its size. The dross smaller than 1 mm was leached with sodium hydroxide solution to extract the remained aluminum from the dross into the solution. and then aluminum hydroxide precipitate was recovered from the leach liquor. The waste residue in the leaching was washed, dried and roasted. Most remained metallic components in the residue was changed into oxide through the processes. The roasted dross was made into alumina castable refractories by mixing with aggregates and a binder. Bending strength of the tested castable specimen was over $25\;kg/\textrm{m}^2$ and compressive strength over $80\;kg/\textrm{cm}^2$, which satisfied the Korean Standard value respectively. From the results, it was suggested that this process could be applicable to recycling of aluminum dross.

Pilot Plant Test for Recycling of the Leached Residue in Processing of Waste Aluminum Dross (알루미늄폐드로스 잔사처리 파일릇트플랜트 시험)

  • Park, Hyung-Kyu;Lee, Hoo-In
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.128-132
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    • 2004
  • 알루미늄 폐드로스 내에 잔류하는 금속 알루미늄을 수산화나트륨용액으로 침출, 분리시켜서 수산화알루미늄으로 제조하는 과정에서 침출잔사가 발생된다. 본 연구에서는 이 침출잔사를 세척, 건조, 배소하여 알루미나질 캐스타블 내화물과 같은 세라믹 원료로 재활용하는 연구를 수행하였으며, 상용화를 위하여 파일롯트 플랜트 시험을 수행하였다. 시험 생산라인은 년간 1,000톤의 폐드로스를 처리하여 약 700톤의 세라믹 원료를 생산할 수 있는 규모이다. 생산라인의 시운전 결과 상용화를 위해서는 건조기의 개선이 필요하고, Na, Fe 등 불순 성분들이 시료에 유입되는 것을 줄여야 하는 문제점들을 파악할 수 있었으며, 개발한 기술의 상용화 적용 가능성을 확인할 수 있었다.

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Test Run of the Pilot Plant for Recycling of the Waste Aluminum Dross (알루미늄 페드로스 재활용 파일롯트플랜트 시운전 결과)

  • Park, Hyung-Kyu;Lee, Hoo-In;Choi, Young-Yoon
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.41-46
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    • 2005
  • Waste aluminum dross is a major waste in the aluminum scrap smelters and its major components are alumina and metallic aluminum. In this study, waste aluminum dross was leached with sodium hydroxide solution to extract the remained aluminum into the solution, and aluminum hydroxide was recovered from the leached solution. The dross residue generated at the leaching step was recycled into alumina base ceramic materials through a series of treatments such as washing, drying and roasting. Also, a pilot plant was constructed and tested to demonstrate the developed technology. Four tons of waste aluminum dross could be processed per day. From the test run of the pilot plant, it was confirmed that the developed technology could be applied to commercialization.

Changes in the Mercury Content of Some Foods during the Washing and Cooking Processes (쌀, 콩나물, 물고기의 수세(水洗) 및 조리(調理)중 수은(水銀) 함량의 변화)

  • Park, Sun-Ok;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.19 no.6
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    • pp.543-549
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    • 1987
  • This study was carried out to estimate the change of Hg content in contaminated food materials including rice grain, soybean sprouts and crucian carp during their washing and cooking processes. The residue level of Hg in contaminated rice at 1 ppm level was decreased to the extent of 24% by three-times washing whereas it was not decreased in cooking. The removal efficiency of Hg in soybean sprouts contaminated at 80 ppm level was about 26% in three-times washing. While the Hg content was not decreased in blanching or cooking of soybean sprouts as a whole, the extent of leached Hg into the fluid part varied in the range of 23-41% depending on the heating time, salinity and volume of cooking water. While the Hg content in fish contaminated at 1 ppm level was not decreased in cooking as a whole, the leaching ratio of Hg into the fluid part was in the range of 2-10% depending on the salinity of cooking water. Disposal of inedible portion in cooked fish could remove 32% of contaminated Hg residue.

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Dissipation of Cyclosulfamuron in Rice Paddies (수도 재배환경 중 제초제 Cyclosulfamuron의 잔류특성)

  • Lee, Young-Deuk;Song, Sung-Do
    • Korean Journal of Environmental Agriculture
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    • v.20 no.4
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    • pp.269-276
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    • 2001
  • Several experiments including persistence, distribution, leaching, and terminal residue trials were carried out to investigate the behavior of cyclosulfamuron in rice paddies. Cyclosulfamuron was gradually dissipated in two different soils showing the first-order kinetics. Half-lives of the herbicide were calculated to be $17{\sim}30$ and $14{\sim}16$ days under field and laboratory conditions, respectively. In the paddy soil/water system, the residue tended to reside more in the soil phase as time elapsed. Cyclosulfamuron was less persistent in paddy water than in soil with half-lives of 10 and 19 days, respectively. No cyclosulfamuron was leached below 20 cm-deep soil during water percolation with 50 cm hydraulic head, while some downward mobility was observed within the soil column. When EC and SC formulations of cyclosulfamuron were applied to the paddy field at 120 or 150-day pre-harvest intervals, its terminal residues in hulled rice were all less than 0.01 mg/kg, irrespective of formulation type and application timing. In rice straw, however, some residues were found at $<0.02{\sim}0.05$ mg/kg as SC formulation was applied. Rapid dissipation, restricted mobility, and low terminal residues of cyclosulfamuron in rice paddies suggest that no significant residues would be transported or carried over to the non-target environment.

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