• Title/Summary/Keyword: leached

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Removal and Separation of Metallic Constituents from the By-product Recovered from Gold Mine Tailings (금(金) 광산(鑛山) 폐광미(廢鑛尾)로부터 회수(回收)된 금속광물(金屬鑛物) 부산물(副産物) 중의 금속성분(金屬成分) 분리(分離), 제거연구(除去硏究))

  • Youn, Ki-Byoung
    • Resources Recycling
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    • v.19 no.3
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    • pp.9-15
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    • 2010
  • Domestic gold mine tailings, generally, contain a lot of non-metallic silica and clay minerals. These minerals can be separated from the tailings by various physical separation methods and used as raw materials for cements and ceramic products. In these physical separation procedures, metallic complex sulfides, in which Au and metallic constituents such as Pb, As and Fe were concentrated, were obtained as a by-product. These metallic constituents should be removed or separated from the by-product to extract Au efficiently. In this work, removal and separation processes of Pb, As, and Fe from the by-product were investigated. Pb was removed to under 3% by using alkaline oxidative leaching at the leaching condition of $120^{\circ}C$, 2M NaOH, 100psi $Po_2$, 250r.p.m., 4 wt.% solid and 30 min. leaching time. The leached residue was roasted and separated magnetically to obtain a non-magnetic product contained <0.2% As, <3% Fe and high concentrated Au more than 8,000 ppm.

Effects of Relative Humidity and Temperature on the Transport of Chloride in the Concrete

  • Nam Jin-Gak;Hartt William H.;Kim Ki-Joon
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.821-828
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    • 2005
  • To investigate the role of RH and temperature on the transport of chloride in the concrete, two groups of specimens were configured. For both groups, mix design was based on w/c=0.45, $400kg/m^3$ cement, $794kg/m^3$ fine aggregate and $858kg/m^3$ coarse aggregate. After specimen fabrication these were exposed to four different RH (35, 55, 75 and $95\%$ RH) and temperature (0, 20, 30 and $40^{\circ}C$) conditions. After 3 and 6 months $15\%$ NaCl exposure 5mm cores were taken. These cores were sliced and individual cores were ground to powder. In addition, to evaluate the effect of temperature on the chloride binding some powder samples were leached in the each of four temperature chambers. Chloride titration fur these was performed using FDOT acid titration method. Based upon the resultant data conclusions were reached regarding that 1) effective diffusion coefficient, $D_e$, increased with increasing exposure RH, suggesting that the size and number of water paths increased with elevated moisture content in the specimens, 2) $D_e$ increased with increasing temperature in the range of 0 to $40^{\circ}C$ possibly by elevated thermal activation of chloride ions and reduced chloride binding at higher temperature, 3) water soluble chloride concentration, $[Cl^-]_s$, increased with increasing temperature, and 4) chloride concentration profile for initially dry concrete specimens was higher than for the initially wet ones indicating pronounced capillary suction (sorption) occurred for the dry concrete specimens.

Preparation of Aluminum Hydroxide by Recycling of Aluminum Dross (알루미늄드로스로부터 수산화알루미늄 제조)

  • 박형규;이호인;김준수
    • Resources Recycling
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    • v.10 no.5
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    • pp.8-15
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    • 2001
  • Aluminum dross should be recycled in consideration of characteristics of the dross and its reutilization after processing. In this study, aluminum dross generated in the domestic secondary aluminum industry was processed to use it as raw material for producing aluminum hydroxide. Sample dross was classified according to its size. The dross smaller than $850\mu$m was leached with sodium hydroxide solution to extract the remaining aluminum from the dross into the solution, and then aluminum hydroxide precipitate was recovered (rom the leach liquor. Purity of the obtained aluminum hydroxide was above 98% and size of the sample was in range of $\3~39mu$m. Recovery of aluminum hydroxide precipitate was highest on condition that A/C ratio of the solution was 0.5 and pulp density was 14~16% at the leaching step. From the result, it was suggested that this process could be applicable to recycling of aluminum dross.

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A Study on the Properties of Electric Arc-Furnace Steelmaking Dusts for Stabilization Processing (안정화 처리를 위한 전기로 제강분진의 물성)

  • 현종영;조동성
    • Resources Recycling
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    • v.7 no.5
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    • pp.13-18
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    • 1998
  • This study was carried out to understand the properties of the E.A.F. steel-making dusts for stabilization processing. The properties are related to mincral composition, shape, particle size, magnetism, density, porosity and leaching characteristic. the dust particles, the size of which ranges from sub-micron to tens-micron, were mainly spherical like balls that were agglomerated each other: the large particles were generally Fe-rich and the small particles were spherical like balls that were agglomerated each other: the large particles were franklinite (ZnFe$_{2}O_{4}$), magnetite (Fe$_{3}O_{4}$) and zincite (ZnO) by XRD analysis. When the dusts were sieved by a wet process, the particle fraction over 200 mesh had 1.5 wt.% with magnetite and quartz. The particles in the size range of 200-500 mesh consisted of magnetite, franklinite. The 82 wt.% of the steel-making dusts were occupied by the particles finer than 500 mesh and contained franklinite and zincite as main mineralogical compositions. When the dusts of around 78% porosity compressed under the load of approximately 1 KPa, the porosity decreased to 68% and to 535 under around 13 KPa. When the E.A.F. dusts were leached according to the Korea standard leaching procedure on the waster, the heavy metals exceeding the leaching criteria were cadmium, lead and mercury.

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Removal of Iron and Phosphorus from Metallurgical Grade Silicon by Melting with Ca and Aqua Regia Leaching (칼슘 첨가(添加)-용융(溶融) 금속급(金屬級) 실리콘의 왕수(王水) 침출(浸出)에 의한 철(鐵)과 인(憐)의 제거(除去))

  • SaKong, Seong-Dae;Sohn, Ho-Sang
    • Resources Recycling
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    • v.20 no.5
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    • pp.34-39
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    • 2011
  • Metallurgical grade silicon(MG-Si) was melted with Ca at 1500$^{\circ}C$ under Ar atmosphere. The sample was cooled at 10 $^{\circ}C$/min to room temperature and leached in aqua regia. In the present study, the effect of Ca addition and conditions of acid leaching on removal of Fe and P in MG-Si were investigated. CaSi$_2$ phase was formed at the grain boundary of MG-Si melting with Ca. Also FeSi$_2$ phase was precipitated in CaSi$_2$ phase. By the formation of CaSi$_2$ phase, 97% of Fe and 66 % of P were removed from Ca added MG-Si with the particle size of 600~850${\mu}m$ by aqua regia(more than 30%) leaching.

Effects of Simulated Acid Rain on Mineral Nutrient Movement in Soil (인공산성비 처리가 토양의 무기양분 이동에 미치는 영향)

  • Ryu, Kwan-Shig
    • Korean Journal of Environmental Agriculture
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    • v.17 no.4
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    • pp.362-367
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    • 1998
  • To investigate the effects of simulated acid rain(SAR) on the downward movement of mineral nutrients, SARs of different pH were applied to the soil. SAR of pH 2.0 decreased the soil pH greatly, while SAR of pH 4.0 and 6.0 did not change the soil pH to compare to that of SAR of pH 2.0. Decrease in soil pH was in the order of sandy loam > loam > clay loam. The amoumt of leached exchangeable and soluble bases from the soil due to the penetration of SAR was in the order of Ca >Mg > K. After application of 1200mm SAR of pH 2.0 in to the soil downward mean movements of the exchangeable and soluble bases was in the order of Mg > Ca > K in sandy loam and loam soil and Ca > Mg > K in clay loam soil. Downward movements of the those bases under pH 4.0 into the soil was in the order of Mg > K > Ca in sandy loam and clay loam, and K > Mg > Ca in loam soil. Available phosphorus moved slightly downward with increasing acidity of the SAR.

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Changes of Texture, Soluble Solids and Protein during Cooking of Soybeans (콩의 조리과정 중 텍스쳐, 고형물 및 단백질의 변화)

  • Kim, Young-Ok;Jung, Hae-Ok;Rhee, Chong-Ouk
    • Korean Journal of Food Science and Technology
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    • v.22 no.2
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    • pp.192-198
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    • 1990
  • Texture, losses of total solids and proteins o) soybeans were studied during cooking at $100-135^{\circ}C$. The textural changes were measured using the puncture probe with an Instron Universal Testing Machine, and changes in microstructure of beans were observed with scanning electron microscopy during the cooking. The major effect observed was a breakdown of the cell walls and appearance of the protein bodies with soaking process. As the cooking time at $100^{\circ}C$ is longer, the separation of cells and changes in cell shape could be seen in the sample. The greater amounts of soluble solids were leached out with longer coo king time from the beans.

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Gelling Properties of Acid-Modified Red Bean Starch Gels (산처리 팥 전분의 겔 특성)

  • Kim, Rae-Eon;Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.39 no.1
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    • pp.49-53
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    • 1996
  • Acid-modified starch was prepared by treating a warm aqueous starch suspension with dilute mineral acid$(0.2\;N\;HCl,\;45^{\circ}C,\;20\;mim{\sim}1\;h)$. The swelling power and solubility of acid-modified red bean starches increased and the changes occurred at tower temperature. According to gel chromatography of starches, the amylose and amylopectin moieties of red bean starches were not affected very much by hydrolysis conditions used. The elution profiles of soluble carbohydrate showed that the larger molecules were leached as the heating temperature increased. Total amounts of soluble carbohydrate were increased by acid-modification. The gel strength of acid-modified starches at each temperature increased, whereas cohesiveness decreased in acid-modified starch gels except at $85^{\circ}C$.

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Studies on the Influence of Sample thickness, Load Increment Ratio and Load Increment Duration on Consolidation Characteristics. (시료의 두께, 하중증가율 밀 재하시간이 압밀특성에 미치는 영향)

  • 류능환;강예묵
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.20 no.3
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    • pp.4750-4770
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    • 1978
  • Under the various variations of the sample thickness, the load increment ratio and the load increment duration, this consolidation test of the clay in the Asan Bay was tried for the comparison with the standard consolidation test. The results gained are as follows; 1. The void ratio variations of the leached-clay samples were increasingly high, according as the sample thickness thinned and the load increment duration and the laod increment ratio increased. 2. The coefficient of consolidation were increased with the increment of the sample thickness, of the load increment ratio and of the load increment duration. Near the pre-consolidation load, the coefficient of secondary consolidation had the maximum value and lessened with the increment of the sample thicknss, and of the load increment duration 3. The value of the pre-consolidation load increased in proportion to the increment of the sample thickness and the decrease of the load increment ratio and the load increment duration. 4. The compression indices increased as the increment of load increased and decreased as the sample thickness increased. 5. The initial compression ratio increased as the sample thickness, the load increment ratio and the load increment duration decreased. The ratio of primary compression to the secondary decreased with the increment of the sample thickness and of the load increment ratio. 6. The time at the completion of psimary consolidation increased with the increment of the sample thickness and of the consolidation load, and with the decrease of the load increment ratio. 7. The compression indicses increaed as the sample thickness lessened and decreased as the load increment ratio increased. The coefficient of consolidation increased according as the sample thickness, the load increment ratio and the load increment duration went up. The settlement at the construction site should be calculated highly in proportion as the sample thickness lessened and the load increment ratio increased. The consolidation ratio is thought to be accelerated if the sample thickness and the load increment ratio becomes higher and the load increment duration longer.

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Glass Formation and Ion Dissolution of P2O5-K2O-FeO-CuO Glasses (P2O5-K2O-FeO-CuO계 유리형성 및 이온용출)

  • Kang, Won-Ho;Kim, Ki-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.604-607
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    • 2010
  • The glass formation and the dissolution property in $P_2O_5-K_2O$-FeO-CuO system were studied. In the batch process, the content of P2O5 was fixed at 60mol% and the other elements were varied from 10~40mol%. The prepared glasses were soaked in the D.I. water up to 13hr and the dissolution properties were investigated with the solutions sampled every 2 hr. The result shows that the $P_2O_5$ was leached out firstly from Phosphate glass system and then Cu and Fe ions were observed according to atmosphere change in solution. ICP shows that the dissolution amount in Phosphate was depended on the glass structure and the highest dissolution amount of CuO and FeO ions was observed when the 10mol% $K_2O$ was added in batch process.