• Title/Summary/Keyword: leached

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Trace Metals in Surface Sediments of Garolim Bay, Korea (가로림만 표층 퇴적물 내 미량금속 분포 특성)

  • PARK, KYOUNGKYU;CHOI, MANSIK;JOE, DONGJIN;JANG, DONGJUN;PARK, SOJUNG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.25 no.2
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    • pp.9-25
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    • 2020
  • In 2010 and 2015, total 77 surface sediment samples were collected to assess the anthropogenic effects of trace metals in surface sediments of Garolim Bay, and the physical characteristics (particle size and specific surface area) and geochemical components (major (Al, Ca, Fe, K, Ba) and trace metals (Mn, Cs, Cr, Co, Ni, Cu, Zn, Pb), organic carbon and calcium carbonate) were analyzed. Mean grain size of Garolim Bay surface sediments ranged from 0.51-5.58 Ø (mean 3.98 Ø) and increased from the inlet of bay to the inner bay, and from the waterway to the land. Most of the metal concentrations except for some elements showed the similar distribution to those of mean grain size and specific surface area. As the particle size decreased and the specific surface area increased, the metal concentration increased. In order to estimate the factors controlling the concentration of trace metals, factor analysis was performed, and three factors were extracted (92.7% of the total variation). Factor 1 accounted for 71.3% of the total variation, which was a grain size factor. Factor 2 accounted for 14.2% of the total variation, Factor 3 accounted for 7.2% of the total variance. Enrichment factor was calculated using the particle size corrected background concentration. Metals with a enrichment factor of 1.5 or higher and the number of samples were 4 for Cr (St. 1, 16, 27, 39) and 1 for Pb (St. 39), but there were little differences in the concentrations of 1M HCl leached metals for these metals. The percentage of 1M HCl leached fraction to total metal concentration decreased in the order of Pb~Co>Cu>Zn~Mn>Ni>Cr. Comparing this value with contaminated and clean sediments in other coastal areas, the percentages for each metal were similar regardless of the trace metal levels in all regions. This fact might be resulted from the reaction between the 1M HCl solution and the different sediment constituents, indicating that there is a limit to apply this percentage of leached metal to the estimation of the contamination extent.

The Characteristics of Solidification and Leachability of Lead Sludge (납슬러지 고형화 및 용출 특성)

  • 연익준;주소영;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.22-30
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    • 1999
  • This study was carried out to examine the compressive strength characteristics of solids solidified with the lead sludge with mixture of cement and fly ashes as additive. And the additives are commercial fly ash and ESP(Electrostatic precipitator) fly ash. The compressive strength of solidified lead sludge solid was increased by adding fly ash up to 46~62%, which was the results of pozzolanic reaction. When replaced the cement with 10%of commercial fly ash, the solid showed the highest value $210{\;}kg/cm^2$, and the solidification conditions were 0.55 of the water/cement ratio and curing for 14 days. Also, the results of leaching test by EPT(Environmental Protection Agency-Toxicity Test) were showed that the solidified lead has leached out under 10%, which was less than 0.173 mg/L of EPA standard. As leaching solutions, the demineralized water, 0.1N acetic acid solution, and synthetic brine were used. and the observations by SEM of the solidified lead-laden solid after EPT leaching test were indicated the severe erosion on solid surface.

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Manufacture and Properties of Gypsum-Wood (Gypsum-Wood의 제조와 성질)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.19 no.1
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    • pp.83-90
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    • 2008
  • Gypsum-wood composites were made by introducing inorganic substances into wood using calcium chloride, first treating solution, and sodium sulfate, secondary treating solution, by double diffusion process under atmospheric pressure at room temperature. The process conducted as follows: water saturated specimens were soaked in calcium chloride solutions at several concentration. Then the specimens were soaked further in saturated sodium sulfate solution, and they were leached in flowing tap water for 24h. To attain sufficient weight percent gain (WPG) values, the suitable concentration of calcium chloride and soaking time in saturated sodium sulfate solution were 20% and 48h, respectively. Inorganic substances were produced mainly in the lumina of tracheides. It was made sure that these substances were dihydrate gypsum($CaSO_4$ $2H_2O$) by X -ray microanalysis (SEM-EDX). The composites had good fire resistance due to low heat transfer rate of gypsum formed in wood. However, the composites had little decay resistances, because they showed high weight losses by test fungi attacks.

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Microstructure of Raney Ni fabricated by Mechanochemical Process in Al-Ni System (Al-Ni계의 기계·화학적 방법으로 제조된 Raney Ni의 미세 구조 분석)

  • Choi, Jae-Woong;Lee, Chang-Rae;Kang, Sung-Goon
    • Korean Journal of Materials Research
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    • v.13 no.1
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    • pp.24-30
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    • 2003
  • The Raney Ni catalyst was fabricated by mechanochemically process(MC process) in the Al-Ni system. Intermetallic compound obtained by mechanical alloying was leached in an alkaline solution. The characteristics of the mechanically alloyed powder and Raney Ni catalyst were analyzed by XRD, ICP-AES and EXAFS. In Al-50wt.%Ni, the metastable intermetallic compound phase close to AlNi phase was obtained by mechanical alloying unlike Al-Ni equilibrium phase diagram. The metastable intermetallic compound was transformed into $Al_3$$Ni_2$phase via the annealing at $750^{\circ}C$. The microstructure of Raney Ni fabricated by MC process was mainly bcc Ni including fcc Ni.

The Monitoring of Biogeochemical Interactions Between Sediment and Water: a Mesocosm Study

  • Yang, Jae-Sam;Kim, Yeong-Tae;Choi, Kang-Won
    • Journal of the korean society of oceanography
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    • v.39 no.1
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    • pp.107-118
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    • 2004
  • A series of mesocosm experiments has been conducted to investigate the effects of sediment on the qualities of superficial water over the tidal flats. The experiments involved two different kinds of sediments (Silt and Fine Sand) to mimic the natural habitats. Other environmental conditions in the mesocosm were kept as natural as possible. The mesocosm coincided with the annual patterns of the natural water qualities and was identical with the composition of benthic organisms of three reference sites of natural tidal flats. DIP has been leached out from sediment from June to October, but not for ammonium and DIN. The mesocosm was successfully able to simulate the environmental situations of natural tidal flat and will be a useful tool to assess the environmental impacts by human activities.

A Study on the Flaking Mechanism of Glass (유리의 Flaking 생성기구에 관한 기구)

  • 김명석;심명재;김정환;이기강
    • Korean Journal of Crystallography
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    • v.11 no.4
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    • pp.224-230
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    • 2000
  • We have been investigated the flaking mechanism of the soda-line glass. The pH of aqueous solution approached to 10 and increased with reaction time by ion exchange reaction between Na/sup +/ ion of glass and H/sup +/ ion of aqueous solution under the conditions of below pH 9 of start solution. The relationship between the pH of solution and reaction time shows logarithm. Total dissolution reaction of glass components by OH/sup -/ ion in aqueous seems to be dominant after the pH solution reached to 10 and the dissolution rate linearly increased with reaction time. The above tow reactions are simultaneously occurred. The dissolved Ca/sup 2+/ ions are reprecipitated on the glass surface to Ca-compound. The flakes are formed by the separation of leached layer of glass due to the different thermal expansion coefficient.

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Depositional Characteristics of Busan Clay, Effects of Artesian Pressure, and Experiences from Ground Improvement (부산 점토의 퇴적 특성, 피압의 영향 및 지반 개량에서 얻은 경험)

  • Kim, Sang-Kyu
    • Proceedings of the Korean Geotechical Society Conference
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    • 2007.09a
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    • pp.3-38
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    • 2007
  • The depositional characteristics of Busan clay are initially described in this paper. The deposits of the Nakdong River estuary are composed of some different layers, which have been affected by marine transgression and regression. The upper clay layer is thick and soft. The lower clay layer and some depth of the upper clay layer have been leached by artesian pressure existing in an aquifer below. The clay shows unique physical and engineering characteristics due to leaching. Several large-scale reclamation projects have been performed in this delta area. The preloading method using long vertical drains has been applied for soft ground improvement. Experiences obtained from ground improvement are mentioned in connection with the depositional characteristics of the clay layers.

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Influence of Frit Surface on the Transmittance of Transparent Dielectric in PDP

  • Kim, Hyung-Sun;Cha, Myung-Lyoung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.828-831
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    • 2005
  • Producing high transparency dielectric is still one of the most important subjects in the PDP process for improving luminous efficiency. It has been reported by many workers that transparency is improved by controlling the composition of the frit, the frit size and distribution, and the firing atmosphere. To understand the mechanism of discoloration of frit, $Bi_2O_3$ and $B_2O_3$ glasses were used for a leaching test using water and alcohol solution in milling. As a result, the frit prepared by wet milling had lower chemical durability than that prepared by dry milling. The leached layer around the frit showed high stability for heat treatment because the frit surface was covered with hydroxides or hydrates which was resulted from a reaction between the frit and the solution during milling.

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A study on the crystallization processing of photosensitive glass by FT-IR and FT-Raman spectroscopy (FT-IR과 FT-Raman 분광계를 이용한 광민감유리의 결정화 과정에 관한 연구)

  • 이명원;강원호
    • Electrical & Electronic Materials
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    • v.10 no.3
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    • pp.284-288
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    • 1997
  • FT-IR and FT-Raman spectra were measured for 15Li$_{2}$O.3Al$_{2}$O$_{3}$.78SiO$_{2}$. 4K$_{2}$O glass system after UV irradiations. Optimum UV irradiation time of Li$_{2}$O.SiO$_{2}$ crystalline phase was 60 seconds and crystalline phase of Li$_{2}$O.SiO$_{2}$ was leached out on 5% HF. 977 cm$^{1}$ band of FT-Raman spectra can be attributed to two-non bridging oxygen in unit cell for 1 hour and optimum crystallization was confirmed for 3 hrs, 630.deg. C.

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Effect of Glassy Phases on the Ferroelectric Anomaly of PbTiO$_3$ in PbO-TiO$_2$-B$_2$O$_3$-BaO System (PbO-TiO$_2$-B$_2$O$_3$-BaO 계에서 PbTiO$_3$ 결정의 상전이 특성에 대한 유리질상의 영향)

  • 이선우;심광보;오근호
    • Journal of the Korean Ceramic Society
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    • v.35 no.7
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    • pp.665-670
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    • 1998
  • Ferroelectric anomaly in PbO-{{{{ { {B }_{2 }O }_{3 } }}-{{{{ {TiO }_{3 } }}-BaO glasses which is observed in DAT measurements was in-vestigated together with the effect of BaO content on the shift of Cuire temperature. The temperature where the ferroelectric anomaly apperars on cooling in DTA decreased in proportion with increasing BaO content,. For as-crystallized samples the ferroelectric anomaly was not observed on heating but on cooling whilist for powder samples leached chemically from the crystallized samples both endothermic and ex-otehrmic peaks were observed. This fact suggests that the appearance of the ferroelectric anomaly in DAT largely depends on glassy phases surrounding individual {{{{ {PbTiO }_{3 } }} crystals rather than effects of grain size and crystallinity.

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