• Title/Summary/Keyword: layer approach

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Biosensing interfaces based on the dendrimer-underlying layer on gold

  • Yun, Hyeon-Cheol;Kim, Hak-Seong
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.52-55
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    • 2000
  • Structually organized mono- and multilayers were developed on gold for the catalytic and affinity biosensing using hyper-branched dendrimers. For the catalytic biosensing interface, a new approach to construct a multilayered enzyme film on the electrode surface was developed. The film was prepared by layer-by-layer depositions of dendrimers and periodate-oxidized glucose oxidase. The voltammograms obtained from the GOx/dendrimer multilayered electrodes revealed that bioelectrocatalytic response is directly correlated to the number of deposited bilayers. From the analysis of voltammetric and ellipsometric signals, the coverage of active enzyme per layer during the layering steps was estimated, demonstrating the spatially-ordered multilayer formation. As an extension of the study, dendrimers having various degrees of ferrocenyl modification were prepared and used. The resulting electrodes were electrochemically characterized, and the density of ferrocenyl groups, active enzyme coverage, and sensitivity were estimated. For the affinity-sensing surrface, a biosensor system based on avidin-biotin interaction was developed. As the building block of affinity monolayer, G4 dendrimer having partial ferrocenyl-tethered surface groups was prepared and used. And the biotinylated and electroactive dendritic monolayer was used for the affinity-sensing surface interacting with avidin. Electrochemical characterization of the resulting biosensor was conducted using free enzyme in electrolyte in terms of degree of surface coverage with avidin and subsequent surface shielding.

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Fabrication of sub-micron sized organic field effect transistors

  • Park, Seong-Chan;Heo, Jeong-Hwan;Kim, Gyu-Tae;Ha, Jeong-Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.84-84
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    • 2010
  • In this study, we report on the novel lithographic patterning method to fabricate organic-semiconductor devices based on photo and e-beam lithography with well-known silicon technology. The method is applied to fabricate pentacene-based organic field effect transistors. Owing to their solubility, sub-micron sized patterning of P3HT and PEDOT has been well established via micromolding in capillaries (MIMIC) and inkjet printing techniques. Since the thermally deposited pentacene cannot be dissolved in solvents, other approach was done to fabricate pentacene FETs with a very short channel length (~30nm), or in-plane orientation of pentacene molecules by using nanometer-scale periodic groove patterns as an alignment layer for high-performance pentacene devices. Here, we introduce the atomic layer deposition of $Al_2O_3$ film on pentacene as a passivation layer. $Al_2O_3$ passivation layer on OTFTs has some advantages in preventing the penetration of water and oxygen and obtaining the long-term stability of electrical properties. AZ5214 and ma N-2402 were used as a photo and e-beam resist, respectively. A few micrometer sized lithography patterns were transferred by wet and dry etching processes. Finally, we fabricated sub-micron sized pentacene FETs and measured their electrical characteristics.

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Seismic response of smart nanocomposite cylindrical shell conveying fluid flow using HDQ-Newmark methods

  • Zamani, Abbas;Kolahchi, Reza;Bidgoli, Mahmood Rabani
    • Computers and Concrete
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    • v.20 no.6
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    • pp.671-682
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    • 2017
  • In this research, seismic response of pipes is examined by applying nanotechnology and piezoelectric materials. For this purpose, a pipe is considered which is reinforced by carbon nanotubes (CNTs) and covered with a piezoelectric layer. The structure is subjected to the dynamic loads caused by earthquake and the governing equations of the system are derived using mathematical model via cylindrical shell element and Mindlin theory. Navier-Stokes equation is employed to calculate the force due to the fluid in the pipe. Mori-Tanaka approach is used to estimate the equivalent material properties of the nanocomposite and to consider the effect of the CNTs agglomeration on the scismic response of the structure. Moreover, the dynamic displacement of the structure is extracted using harmonic differential quadrature method (HDQM) and Newmark method. The main goal of this research is the analysis of the seismic response using piezoelectric layer and nanotechnology. The results indicate that reinforcing the pipeline by CNTs leads to a reduction in the displacement of the structure during an earthquake. Also the negative voltage applied to the piezoelectric layer reduces the dynamic displacement.

A Separator with Activated Carbon Powder Layer to Enhance the Performance of Lithium-Sulfur Batteries

  • Vu, Duc-Luong;Lee, Jae-Won
    • Journal of Powder Materials
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    • v.25 no.6
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    • pp.466-474
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    • 2018
  • The high theoretical energy density ($2600Wh\;kg^{-1}$) of Lithium-sulfur batteries and the high theoretical capacity of elemental sulfur ($1672mAh\;g^{-1}$) attract significant research attention. However, the poor electrical conductivity of sulfur and the polysulfide shuttle effect are chronic problems resulting in low sulfur utilization and poor cycling stability. In this study, we address these problems by coating a polyethylene separator with a layer of activated carbon powder. A lithium-sulfur cell containing the activated carbon powder-coated separator exhibits an initial specific discharge capacity of $1400mAh\;g^{-1}$ at 0.1 C, and retains 63% of the initial capacity after 100 cycles at 0.2 C, whereas the equivalent cell with a bare separator exhibits a $1200mAh\;g^{-1}$ initial specific discharge capacity, and 50% capacity retention under the same conditions. The activated carbon powder-coated separator also enhances the rate capability. These results indicate that the microstructure of the activated carbon powder layer provides space for the sulfur redox reaction and facilitates fast electron transport. Concurrently, the activated carbon powder layer traps and reutilizes any polysulfides dissolved in the electrolyte. The approach presented here provides insights for overcoming the problems associated with lithium-sulfur batteries and promoting their practical use.

Analysis of key elements of single-layer dome structures against progressive collapse

  • Zhang, Qian;Huang, Wenxing;Xu, Yixiang;Cai, Jianguo;Wang, Fang;Feng, Jian
    • Steel and Composite Structures
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    • v.42 no.2
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    • pp.257-264
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    • 2022
  • The analysis of the progressive collapse resistance of structures is a well-known issue among structural engineers. Large-span reticulated dome structures are commonly utilized in large public buildings, necessitating research into their progressive collapse resistance to assure user safety. The most significant part of improving the structural resilience of reticulated domes is to evaluate their key elements. Based on a stiffness-based evaluation approach, this work offers a calculating procedure for element importance coefficient. For both original and damaged structures, evaluations are carried out using the global stiffness matrix and the determinant. The Kiewitt, Schwedler, and Sunflower reticulated domes are investigated to explore the distribution characteristic of element importance coefficients in the single-layer dome structures. Moreover, the influences of the load levels, load distributions, geometric parameters and topological features are also discussed. The results can be regarded as the initial concept design reference for single-layer reticulated domes.

The Enhanced Electrochemical Performance of Lithium Metal Batteries through the Piezoelectric Protective Layer (압전 특성의 보호층을 통한 리튬 금속 전지의 전기화학적 특성 개선)

  • Dae Ung Park;Weon Ho Shin;Hiesang Sohn
    • Membrane Journal
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    • v.33 no.1
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    • pp.13-22
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    • 2023
  • Despite high capacity of lithium metal anode, its uncontrollable dendrite growth results in the poor electrochemical (EC) performance (low Coulomb efficiency and limited cycle stability) and unsafe operation. In this study, we demonstrated a lithium metal anode protected with BaTiO3/PVDF based piezoelectric layer to enhance its EC performance by utilizing the locally polarized lithium metal after volume expansions. As-formed lithium metal electrode deposited with BTO@PVDF layer exhibited an enhanced Coulombic efficiency (> 98% for 100 cycles) and facilitated lithium ion diffusions (lithium diffusion coefficient: DLi+), revealing the effectiveness of piezoelectric layer deposited lithium metal electrode approach.

Direct Runoff Reduction Analysis and Application Feasibility Evaluation of Vegetation-type Facilities (식생형시설의 직접유출량 저감 효과분석 및 적용 방법 타당성 검토)

  • Hanyong Lee;Won Hee Woo;Youn Shik Park
    • Journal of Korean Society of Rural Planning
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    • v.30 no.2
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    • pp.69-77
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    • 2024
  • As impervious area increases due to urbanization, rainfall on the impervious area does not infiltrate into the ground, and stormwater drains quickly. Low impact development (LID) practices have been suggested as alternatives to infiltrate and store water in soil layers. The practices in South Korea is applied to urban development projects, urban renewal projects, urban regeneration projects, etc., it is required to perform literature research, watershed survey, soil quality, etc. for the LID practices implementation. Prior to the LID implementation at fields, there is a need to simulate its' effect on watershed hydrology, and Storm Water Management Model (SWMM) provides an opportunity to simulate LID practices. The LIDs applied in South Korea are infiltration-based practices, vegetation-based practices, rainwater-harvesting practices, etc. Vegetation-based practices includes bio-retention cell and rain garden, bio-retention cells are mostly employed in the model, adjusting the model parameters to simulate various practices. The bio-retention cell requires inputs regarding surface layer, soil layer, and drain layer, but the inputs for the drain layer are applied without sufficient examination, while the model parameters or inputs are somewhat influential to the practice effects. Thus, the approach to simulate vegetation-based LID practices in SWMM uses was explored and suggested for better LID simulation in South Korea.

Processing Techniques of Layer Channel Image for 3D Image Effects (3D 영상 효과를 위한 레이어 채널 이미지의 처리 기법)

  • Choi, Hak-Hyun;Kim, Jung-Hee;Lee, Myung-Hak
    • The Journal of the Korea Contents Association
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    • v.8 no.1
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    • pp.272-281
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    • 2008
  • A layer channel, which can express effects on 3D image, is inserted to use it on application rendering effectively. The current method of effect rendering requires individual sources in storage and image processing, because it uses individual and mixed management of images and effects. However, we can save costs and improve results in images processing by processing both image and layer channels together. By changing image format to insert a layer channel in image and adding a hide function to conceal the layer channel and control to make it possible to approach image and layer channels simultaneously during loading image and techniques hiding the layer channel by changing image format with simple techniques, like alpha blending, etc., it is developed to improve reusability and be able to be used in all programs by combining the layer channel and image together, so that images in changed format can be viewed in general image viewers. With the configuration, we can improve processing speed by introducing image and layer channels simultaneously during loading images, and reduce the size of source storage space for layer channel images by inserting a layer channel in 3D images. Also, it allows managing images in 3D image and layer channels simultaneously, enabling effective expressions, and we can expect to use it effectively in multimedia image used in practical applications.

Estimation of Air Voids in Asphalt Mixtures Using Ground-Penetrating Radar (지표투과레이더를 이용한 아스팔트 혼합물의 공극률 예측에 관한 연구)

  • Kim, Je Won;Kim, Yeon Tae;Kim, Booil;Park, Hee Mun
    • International Journal of Highway Engineering
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    • v.18 no.4
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    • pp.55-61
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    • 2016
  • PURPOSES : The objective of this study was to determine the relationship between the dielectric characteristics of asphalt mixtures and the air voids present in them using ground penetrating radar (GPR) testing. METHODS : To measure the dielectric properties of the asphalt mixtures, the reflection coefficient method and the approach based on the actual thickness of the asphalt layer were used. An air-couple-type GPR antenna with a center frequency of 1 GHz was used to measure the time for reflection from the asphalt/base layer interface. A piece of aluminum foil was placed at the interface to be able to determine the reflection time of the GPR signal with accuracy. An asphalt pavement testbed was constructed, and asphalt mixtures with different compaction numbers were tested. After the GPR tests, the asphalt samples were cored and their thicknesses and number of air voids were measured in the laboratory. RESULTS : It was found the dielectric constant of asphalt mixtures tends to decrease with an increase in the number of air voids. The dielectric constant values estimated from the reflection coefficient method exhibited a slight correlation to the number of air voids. However, the dielectric constant values measured using the approach based on the actual asphalt layer thickness were closely related to the asphalt mixture density. Based on these results, a regression equation to determine the number of air voids in asphalt mixtures using the GPR test method was proposed. CONCLUSIONS : It was concluded that the number of air voids in an asphalt mixture can be calculated based on the dielectric constant of the mixture as determined by GPR testing. It was also found that the number of air voids was exponentially related to the dielectric constant, with the coefficient of determination, $R^2$, being 0.74. These results suggest that the dielectric constant as determined by GPR testing can be used to improve the construction quality and maintenance of asphalt pavements.

Development of Ultrasonic Testing Method for Evaluation of Adhesive Layer of Blaster Tube (토출관 접합계면 평가를 위한 초음파 시험법 개발)

  • Kim, Y.H.;Song, S.J.;Park, J.S.;Cho, H.;Lim, S.Y.;Yun, N.G.;Park, Y.J.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.2
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    • pp.46-53
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    • 2004
  • Ultrasonic testing method has been developed to evaluate flaw of adhesive layers in blast tube for the reliability of the rocket nozzle. The ultrasonic reflection from the interface between the steel sheet and the epoxy adhesive is measured with a high-frequency Pulse-echo setup in order to identify contact debonding and missing adhesive in epoxy layer between steel and FRP layers. The steel sheet is resonated by low-frequency ultrasound, and the gap size underneath the measuring location is estimated from the resonance responses. For practical application in industry an automated testing system has been developed where the proposed approach is implemented. The performance of the proposed approach has been verified by actual measurement of gap sizes from the cross-sections of cut specimens using an optical microscope.