• Title/Summary/Keyword: lattice energy

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Equilibrium Conditions of Methane Hydrate added Help Gases (보조가스가 첨가된 메탄 하이드레이트 상평형 조건에 대한 연구)

  • Kim, Nam-Jin;Lim, Sang-Hoon;Chun, Won-Gee
    • Journal of the Korean Solar Energy Society
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    • v.27 no.4
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    • pp.51-58
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    • 2007
  • Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. When referred to standard conditions, $1m^3$ solid hydrates contain up to $172Nm^3$ of methane gas, depending on the pressure and temperature of production. Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming methane hydrate were theoretically obtained in aqueous single electrolyte solution containing 3wt% NaCl. The results show that the predictions match the previous experimental values very well, and it was found that NaCl acts as an inhibitor.

Bubbly, Slug, and Annular Two-Phase Flow in Tight-Lattice Subchannels

  • Prasser, Horst-Michael;Bolesch, Christian;Cramer, Kerstin;Ito, Daisuke;Papadopoulos, Petros;Saxena, Abhishek;Zboray, Robert
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.847-858
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    • 2016
  • An overview is given on the work of the Laboratory of Nuclear Energy Systems at ETH, Zurich (ETHZ) and of the Laboratory of Thermal Hydraulics at Paul Scherrer Institute (PSI), Switzerland on tight-lattice bundles. Two-phase flow in subchannels of a tight triangular lattice was studied experimentally and by computational fluid dynamics simulations. Two adiabatic facilities were used: (1) a vertical channel modeling a pair of neighboring sub-channels; and (2) an arrangement of four subchannels with one subchannel in the center. The first geometry was equipped with two electrical film sensors placed on opposing rod surfaces forming the subchannel gap. They recorded 2D liquid film thickness distributions on a domain of $16{\times}64$ measuring points each, with a time resolution of 10 kHz. In the bubbly and slug flow regime, information on the bubble size, shape, and velocity and the residual liquid film thickness underneath the bubbles were obtained. The second channel was investigated using cold neutron tomography, which allowed the measurement of average liquid film profiles showing the effect of spacer grids with vanes. The results were reproduced by large eddy simulation + volume of fluid. In the outlook, a novel nonadiabatic subchannel experiment is introduced that can be driven to steady-state dryout. A refrigerant is heated by a heavy water circuit, which allows the application of cold neutron tomography.

Effect of Non-lattice Oxygen Concentration on Non-linear Interfacial Resistive Switching Characteristic in Ultra-thin HfO2 Films

  • Kim, Yeong-Jae;Kim, Jong-Gi;Mok, In-Su;Lee, Gyu-Min;Son, Hyeon-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.359-360
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    • 2013
  • The effect of electrode and deposition methods on non-linear interfacial resistive switching in HfO2 based $250{\times}250$ nm2 cross-point device was studied. HfO2 based device has the interfacial resistive switching properties of non-linearity and self-compliance current switching. The operating current in HfO2 based device was increased with negatively increasing the heat of formation energy in top electrode. Also, it was investigated that the operating current in HfO2 based device was changed with deposition methods of O3 reactant ALD, H2O reactant ALD and dc reactive sputtering, resulting the magnitude of the operating current and on/off ratio in order of HfO2 films deposited by dc reactive sputtering, H2O reactant ALD, and O3 reactant ALD. To investigate the effect of electrode and deposition methods on operating current of non-linear interfacial resistive switching in the cross-point device, X-ray photoelectron spectroscopy was measured. Through the analysis of O 1s spectra, non-lattice oxygen concentration, which is closely related to oxygen vacancies, was increased in order of Pt, TiN, and Ti top electrodes and in order of O3 reactant ALD, H2O reactant ALD, and O3 reactant ALD, and dc reactive sputtering deposition method. From all results, non-lattice oxygen concentration in ultra-thin HfO2 films play a crucial role in the operating current and memory states (LRS & HRS) in the non-linear interfacial resistive switching.

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A Study on the Optimal Design of Ti-6Al-4V Lattice Structure Manufactured by Laser Powder Bed Fusion Process (Laser Powder Bed Fusion 공정으로 제조된 Ti-6Al-4V 격자 구조물의 최적 설계 기법 연구)

  • Ji-Yoon Kim;Jeongmin Woo;Yongho Sohn;Jeong Ho Kim;Kee-Ahn Lee
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.146-155
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    • 2023
  • The Ti-6Al-4V lattice structure is widely used in the aerospace industry owing to its high specific strength, specific stiffness, and energy absorption. The quality, performance, and surface roughness of the additively manufactured parts are significantly dependent on various process parameters. Therefore, it is important to study process parameter optimization for relative density and surface roughness control. Here, the part density and surface roughness are examined according to the hatching space, laser power, and scan rotation during laser-powder bed fusion (LPBF), and the optimal process parameters for LPBF are investigated. It has high density and low surface roughness in the specific process parameter ranges of hatching space (0.06-0.12 mm), laser power (225-325 W), and scan rotation (15°). In addition, to investigate the compressive behavior of the lattice structure, a finite element analysis is performed based on the homogenization method. Finite element analysis using the homogenization method indicates that the number of elements decreases from 437,710 to 27 and the analysis time decreases from 3,360 to 9 s. In addition, to verify the reliability of this method, stress-strain data from the compression test and analysis are compared.

Investigation on the heat transfer of MHD nanofluids in channel containing porous medium using lattice Boltzmann method

  • Xiangyang Liu;Jimin Xu;Tianwang Lai ;Maogang He
    • Advances in nano research
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    • v.15 no.3
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    • pp.191-201
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    • 2023
  • In order to develop better method to enhance and control the flow and heat transfer inside the radiator of electronic device, the synergistic effect of MHD nanofluids and porous medium on the flow and heat transfer in rectangular opened channel is simulated using Lattice Boltzmann method. Three nanofluids of CuO-water, Al2O3-water and Fe3O4-water are studied to analyze the influence of the type of nanofluid on the synergistic effect. The simulation results show that the porous medium can increase the flow velocity in fluid zone adjacent to the porous medium and enhance the heat transfer on the surface of the channel. Under no magnetic field, when the porosity of porous medium is 0.8, the Nusselt number is 4.46% higher than when the porosity is 0.9. Al2O3-water has the best heat transfer effect among the three nanofluids. At Ф=0.06, Ha=100, θ=90°, ε=0.9, Nu of Al2O3-water is 6.51% larger than that of CuO-water and 5.05% larger than that of Fe3O4-water. Magnetic field enhances seepage in porous medium and inhibits heat transfer in the bottom wall. When Ha=30 and 60, the inhibiting effect is the most significant as the magnetic field angle is 90°. And when Ha=100, the inhibiting effect is the most significant as the magnetic field angle is 120°.

The Evolution of Preferred Orientation and Morphology of NiO Thin Films under Variation of Plasma Source and RF Power (Plasma source와 RF power에 따른 NiO박막의 우선배향성 및 표면형상)

  • Hyunwook Ryu;Park, Jinseong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.121-121
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    • 2003
  • NiO thin films are very attractive for use as an antiferromagnetic layer, p-type transparent conducting films, in electrochromic devices and functional sensor layer for chemical sensors, due to their excellent chemical stability, as well as optical, electrical and magnetic properties. In addition, (100)- and (111)-oriented NiO films can be used as buffer layers on which to deposit other oriented oxide films, such as c-axis-oriented perovskite-type ferromagnetic films and superconducting films, because of the similarity in symmetry of oxygen ion lattice and lattice constants between the NiO films and the oriented oxide films. Thus, controlling the crystallographic orientation and surface roughness of the NiO films for a buffer layer are very important.

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Potential Based Prediction Methods of Aerodynamic and Wake Simulation of Wind Turbine Blade (포텐셜 유동을 기반으로 한 풍력 터빈 블레이드의 공력 해석 및 후류 예측 기법에 관한 연구)

  • Kirn, Ho-Geon;Shin, Hyung-Ki;Lee, Soo-Gab
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.414-419
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    • 2007
  • This paper describes the prediction of aerodynamic performance and wake of HAWT in normal and yawed flow operation using potential based methods. In order to analyze aerodynamic performance of wind turbine WINFAS program is used, which is based on VLM(Vortex Lattice Method) and CVC(Constant vorticity contour) Free wake model. Some problems of CVC vortex filament method are investigated arid to improve these problems vortex ring wake are introduced in behalf of CVC vortex filament. The prediction results using the vortex lattice wake are compared to experimental data.

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Theoretical Consideration on Influences of Cavity or Pillar Shape on Band Structures of Silicon-Based Photonic Crystals

  • Ogawa, Yoshifumi;Tamura, Issei;Omura, Yasuhisa;Iida, Yukio
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.7 no.1
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    • pp.56-65
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    • 2007
  • This paper describes physical meanings of various influences of cavity (or pillar) shape and filling factor of dielectric material on band structures in two-dimensional photonic crystals. Influences of circular and rectangular cross-sections of cavity (or pillar) arrays on photonic band structures are considered theoretically, and significant aspects of square and triangular lattices are compared. It is shown that both averaged dielectric constant of the photonic crystal and distribution profile of photon energy play important roles in designing optical properties. For the triangular lattice, especially, it is shown that cavity array with a rectangular cross-section breaks the band structure symmetry. So, we discuss this point from the band structure and address optical properties of lattice with a circular cross-section cavity.

Ab-initio calculation on Co substitution into NiSi (NiSi에의 Co 치환에 대한 ab-initio 계산)

  • Kim, Yeong-Cheol;Seo, Hwa-Il
    • Korean Journal of Materials Research
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    • v.17 no.7
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    • pp.358-360
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    • 2007
  • Cobalt subtitution on NiSi is investigated by using an ab-initio calculation. Firstly, a relaxed NiSi structure is calculated and the calculated lattice parameters are compared with experimentally determined lattice parameters. The calculated values are smaller than the experimental values by about 2%. As the calculation is based on 0 K, and the experimental measurement is performed at room temperature, those values are in good agreement. Next, a Co atom substitutes a Ni and Si site, respectively, to evaluate the preferable site between them. Co prefers Ni site to Si site. The calculated total energy also indicates that the Co substitution to Ni site stabilizes the NiSi structure. Therefore, the thermal stability of NiSi with Co addition can be achieved by the structure stabilization of NiSi by Co substitution into Ni site of NiSi.

A Lattice Model Based Molecular Clusters for Supercritical Fluids (초임계 유체를 위한 분자 클러스터 기반의 격자모델)

  • Shin, Moon-Sam
    • Proceedings of the KAIS Fall Conference
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    • 2011.05a
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    • pp.306-309
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    • 2011
  • A lattice model based molecular clusters is presented to improve a classical equation of state(EOS) for volumetric properties in the critical region. The term is based on the two assumptions: (1) The Helmholtz energy is individually divided into classical and long-range density fluctuation contribution (2) All molecules form cluster near the critical region due to long-range density fluctuation. To formulate such molecular cluster, we extended the Veytsman statistics originally developed for the cluster due to hydrogen bonding. The probability function in the statistics is modified to represent the characteristics of long-range density fluctuation vanishing far from critical region. The proposed fluctuation contribution was incorporated into the Sanchez-Lacombe EOS and the combined model with 6 adjustable parameters has been tested against experimental VLE data for pure compounds. The combined model is found to well represent flatten critical isotherm for methane and top of the coexistence curve for the tested components.

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