• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1076-1081
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• 2012

For the purpose of development of the latex suitable for latex modified concrete, experimental researches on the preparation of carboxylated styrene butadiene latex by the method of the two-step emulsion polymerization and application to concrete were performed. Sodium dodecylbenzene sulfonate and sodium salt of lauryl sulfonate were selected as anionic emulsifiers, and nonylphenoxy poly(ethyleneoxy) ethanols (n=10, 20, 40) as latex stabilizer. Potassium persulfate and sodium bisulfite were used as redox initiator, besides $Na_2HPO_4$ and $K_2CO_3$ as electrolytes. Polymerization recipe of latex suitable for latex modified concrete were suggested from the experimental researches on the effects of anionic emulsifiers and their concentration on the polymerization stability, and the effect of electrolytes concentration on the particle size of latex. Physical properties, such as slump, air contents, compressive and flexural strength, of latex prepared by suggested polymerization recipe were examined. The experimental results showed that latex modified concrete satisfied the quality standards in slump and air contents. Furthermore, it was turned out that the compressive and the flexural strength of latex modified concrete with 28 days curing time showed appreciably improvements.

• Journal of the Korea Concrete Institute
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• v.13 no.5
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• pp.507-515
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• 2001

Significant improvements in bond strength between new and existing concrete can be achieved through the modification of the new concrete by latex. This study focuses on the investigation of bond strength of latex modified concrete. Pull-out bond test and uniaxial direct tensile bond test are adopted for evaluating the adhesion characteristics of latex modified concrete to conventional concrete substrate. The main experimental variables are test methods, latex-cement ratio, surface preparations and moisture levels. The results are as follows; The increase of latex-cement ratio substantially improves the adhesion between latex modified concrete and substrate. The effects of surface preparation at substrate into the bonding of latex modified concrete are quite different according to the conditions of surfaces. Thus, an adequate surface preparations are essential for good bond strength. Because the moisture level of the substrate may be critical to achieving bond, optimum moisture condition for a conventional concrete has evaluated in this study. The saturated condition of surface is the most appropriate moisture level among the considered, followed by dry condition and wet condition.

• Magazine of the Korea Concrete Institute
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• v.15 no.6
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• pp.78-84
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• 2003

• Journal of The Korean Society of Agricultural Engineers
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• v.49 no.2
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• pp.37-46
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• 2007

The service life of agricultural concrete structures is designed in about 30 to 100 years, but actual service lift is estimated in an average 18 years. Therefore, as the service life of the agricultural concrete structures increases, necessity of repair by aging from various environment condition exposure increases. This study was to determinate the optimum mix proportion of latex modified repair mortar and to improve the durability performance of agricultural concrete structures. The physical and mechanical tests of latex modified repair mortar were performed. Tests of flow, compressive strength, flexural strength and bond strength tests were conducted. Test results show that the optimum nex proportion of latex modified repair mortar, when used in 5% latex volume fraction (weight of cement), 1.5% antifoaming agent (weight of latex), 0.2% PVA fiber volume fraction, 1:2 (binder-sand ratio), 10% silica fume replacement ratio (weight of cement), could result in best performance for the repair of agricultural concrete structures.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.647-652
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• 2000

The bond strength of latex-modified concrete to normal portland cement concrete measured with direct pull-out test. Using $250\times1100\times1400$mm concrete slab as the base concrete, an overlay of the latex-modified concrete is applied and cured similar to bridge deck and then tested in direct pull-out. The test results not only give values of the bond strength of the overlay tested but also clearly indicate whether the failure is in the bond interface or the materials tested.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.497-502
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• 2000

This study was performed to change the latex content for properties of freezing-thawing resistance. When styrene-butadiene latex is added to portland cement, aggregate and water, a concrete with the color, consistency and workability of ordinary conventional concrete results, but with 20% to 35% less water. When cured, the concrete consists of hydrated cement and aggregate interconnected by a film of latex particles. In general, increasing the amount of latex will produce concrete with increased tensile and flexural strength and lower modulus of elasticity. Air entrainment has been used in conventional concrete for the past 50 years to impart freeze-thaw resistance. Latex modified concrete does not need additional air entrainment for freeze-thaw resistance provided adequate cure occurs.

• Journal of Industrial Technology
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• v.22 no.A
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• pp.161-168
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• 2002

Latex modified concrete is governed by both cement hydration and polymer film formation processes in its binder phase. Such the reactions are expected to improve the polymer-cement co-matrixes themselves and the bond between the cement hydrates and aggregates, and to improve the properties of hardened latex-modified concrete. The purpose of this study was to study the strength and chemical resistance of Rapid-setting latex modified concrete(RSLMC) with the main experimental variables such as latex content(0, 5, 10, 15, 20%) and water-cement ratio(36, 38, 40%) at latex content 15%. Water absorption test was earned out to estimate water permeability resistance. Chemical resistance test was carried out to measure the weight change and to observe the appearance of RSLMC immersion in hydrochloric acid, sulfuric acid, and calcium choloride.

• Journal of The Korean Society of Agricultural Engineers
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• v.49 no.3
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• pp.43-50
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• 2007

The purpose of this study was to determine the optimum mix proportion of latex modified mortar for agricultural underwater concrete structures repair. The experimental variables included a latex and antiwashout admixture amount, binder-sand ratio, water-binder ratio. This study were evaluated a repair performance and environment effect of latex modified repair mortar for agricultural underwater concrete structures. The pH test was conducted to evaluated the environmental effect and the flow test was peformed to evaluated the workability. Also, compressive, flexural and bond tests were conducted. Test results show that the optimum mix proportion of latex modified repair mortar for agricultural underwater concrete structures, was achieved by 1:1.5 binder-sand ratio, 5% latex ratio (weight of binder), 1.3% antiwashout admixture ratio (weight of binder), 0.33 water-binder ratio and 10% silica lune replacement ratio (weight of cement). The environmental effect and repair performance of optimum mix proportion satisfied all target performance.

• Journal of Industrial Technology
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• v.24 no.A
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• pp.165-171
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• 2004

Latex modification of concrete provides the material with higher flexural strength, as well as high bond strength and reduced water permeability. However, If the thermal expansion properties of overlay concrete (latex-modified concretes) are big different from that of substrate (ordinary portland cement concrete), these would cause a big interfacial stresses and result in premature failure. Therefore, the purposes of this study were to investigate thermal expansion characteristics of latex-modified concrete with cement types. The result of thermal expansion showed the coefficient of thermal expansion of concretes increased with latex inclusion. The coefficient of thermal expansion of RSLMC was a little smaller than that of LMC, which might be due to the finer cement grain, compacter internal, and stiffer properties of concrete. However, the coefficients of LMC and RSLMC were quite similar to that of ordinary cement concrete. Thus, this would not cause an interfacial stresses and will enable to ensure long-term performance of concrete bridge deck overlays.

• Journal of the Korea Concrete Institute
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• v.13 no.5
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• pp.484-490
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• 2001

This study focused on the investigation of durability of latex modified concrete in the points of chloride ion permeability and freeze-thaw resistance as latex content variated such as 5%, 10%, 15% and 20%. When latex was mixed in concrete and cured, the concrete consisted of hydrated cement and aggregate interconnected by a film of latex particles. An increasing the amount of latex produced concrete with increased flexural strength, but with slightly lower compressive strength. The increase in flexural strength might be attributed to the latex films between the hydrated cement and aggregates, and the decrease in compressive strength to the flexibility of the latex component named by Butadiene. The rapid chloride permeability test was used to evaluate the relative permeability of latex-modified concretes and conventional concretes. The results showed that the permeability of latex-modified concretes was considerably lower than conventional concretes tested, which might be due to the latex filled in voids and interconnections of hydrated cement and aggregates by a film of latex particles. The freeze-thaw resistance of LMC was quite good comparing to conventional concrete. Air entraining agent has been used in conventional concrete to improve the freeze/thaw resistance, but latex modified concrete does not need additional air entraining agent for freeze-thaw resistance provided adequate cure occurs.