• Elastomers and Composites
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• 제28권4호
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• pp.274-282
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• 1993

Resorcinol-tannin-formaldehyde-latex(RTFL) adhesive was prepared to bond SBR to nylon in reinforced rubber composites. A key factor of adhesive contributes to the adhesion strength between SBR and nylon was the toughness of adhesive itself. Although the stiffness and strength of adhesive film decreased slightly with increasing level of tannin substitution for resorcinol in a standard RFL adhesive, the maximum toughness of adhesive film, which showed yield behavior and high dissipative capacity, was obtain by 60% tannin substitution. However, a marked softening and reduction in toughness occurred at sufficiently high substitution. Also, the adhesive film, which was heat-treated to simulate cure, showed higher strength than the unheated film. Thus, the properties of tannin containing adhesives could be optimized by using 40/60 weight ratio of the resorcinol/tannin in RTFL adhesive composition as well as heat treatment of adhesive film.

• Elastomers and Composites
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• 제50권4호
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• pp.304-313
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• 2015

In this study, the anionic emulsified asphalt was prepared by dispersing asphalt particles evenly into water with combination of anionic and nonionic surfactants. Effects of NaOH and $CaCl_2$ on the phase stability of the emulsified asphalt were also investigated through zeta potential value and rheology behavior; the emulsified asphalt added with NaOH and $CaCl_2$ showed higher zeta potential value than that the asphalt with addition of only anionic and nonionic surfactants. In addition, with regard to shear thinning behaviors, it was found that pH of the emulsified anionic asphalt and $Ca^{2+}$, counter ion, affected the phase stability. SBR (styrene-butadiene-rubber) latex, EPD (water dispersed Epoxy), PU (polyurethane) and RI-10S, SBS (styrene-butadiene-styrene)-based property improvement additive, were used and studied to enhance the adhesion properties with the aggregates. RI-10S, however, was found to be only compatible with the anionic emulsified asphalt; the coating rate, adhesion and compression strength were increased with the RI-10S content.

• Elastomers and Composites
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• 제37권1호
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• pp.21-30
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• 2002

개시제 ammonium persulfate(APS)와 유화제 sodium dodecyl benzene sulfonate(SDBS)를 이용하여 methyl methacrylate(MMA), styrene(St), ethyl acrylate(EA)등의 단량체를 core(내부)와 shell(외부)의 폴리머성분이 다른 core-shell 폴리머를 합성하고 각 core-shell 폴리머에 대한 구조를 연구하였다. 한 입자의 내부와 외부의 고분자 조성이 다른 composite 라텍스는 고분자 블렌딩과 공중합의 물성과는 달리 한 입자 내에서도 상반된 두 가지 물성을 동시에 나타내는 특성으로 인하여 여러 산업 분야에 응용이 가능하다. 그러나, core-shell 라텍스를 제조할 때 반응중입자가 성장하는 과정에서 입자의 응집과 중합율이 떨어지고, 라텍스의 응용시 기계적 안정성이 문제점으로 되고 있다. 따라서 shell 중합시에 새로운 입자의 생성이 적고 중합중 안정성이 우수한 라텍스를 제조하기 위해 유화제농도, 개시제농도, 중합온도가 PMMA/PSt과 PSt/PMMA의 core-shell 구조에 미치는 영향과 중합 후 입도분석기(particle size analyzer; PSA) 및 투과전자현미경(transmission electron microscope; TEM)을 이용하여 실제 입자측정과 입자형태 특성을 확인하였으며 시차주사열량계(differential scanning calorimeter, DSC)를 이용하여 유리전이온도($T_g$)의 측정, 최저성막온도(minimum film formation temperature; MFFT), NaOH 첨가에 의한 가수 분해에 따르는 pH를 측정하여 core-shell의 새로운 특성을 확인하였다.

• 한국염색가공학회지
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• 제11권4호
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• pp.50-56
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• 1999

The adhesive properties of polyester cord in rubber matrix were investigated according to the surface modification. The polyester cord was oxidized in sodium hypochlorite solution, and graft-polymerized with acrylic acid under the irradiation with ultraviolet light, and then coated with resorcinol-formaldehyde latex (RFL). The modified surface was checked with scanning electron microscope. The adhesive properties were measured by the full-Out method, and evaluated with regard to the energy of adhesion and the maximum load. The polyester was not oxidized in sodium hypochlorite solution, so the surface was not able to etch to produce the coarse topology. As the concentration of acrylic acid and the reaction time were increased, the graft yields were also increased. It was considered that the acrylic acid would swell the polyester and diffuse easily to the inner side of substrate. The adhesive properties of polyeser to rubber matrix were affected by the surface condition. Namely, the maximum load was almost same, but the energy of adhesion was rather higher In the polyester grafted with acrylic acid than in control one. We concluded that the flexible aliphatic chains of polyacrylic acid situated in the interface of cord and rubber matrix were distributed well the stress and strain all over the filler resulting the high energy of adhesion.

• Elastomers and Composites
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• 제54권2호
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• pp.97-104
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• 2019

Emulsion styrene-butadiene rubber silica wet masterbatch (ESBR silica WMB) technology was studied to develop highly filled and highly dispersed silica compounds, involving the preparation of a composite by co-coagulating the modified silica and the rubber latex in a liquid phase. Previous studies have shown that when manufacturing ESBR silica WMB/Butadiene silica dry masterbatch (BR silica DMB) blend compounds, preparing BR silica dry masterbatch and mixing it with ESBR silica WMB gave excellent results. However, WMB still has the problem of lower crosslink density due to residual surfactants. Therefore, in this study, tetrabenzylthiuram disulfide (TBzTD) was added instead of diphenyl guanidine (DPG) in the ESBR silica WMB/BR silica DMB blend compounds and sulfur/CBS contents were increased to evaluate their cure characteristics, crosslink densities, mechanical properties, and dynamic viscoelastic properties. TBzTD was found to be more effective in increasing the crosslink density and to produce superior properties compared to DPG. In addition, with increasing sulfur/CBS contents, mechanical properties and rolling resistance were enhanced due to high crosslink density, but the abrasion resistance was not significantly changed because of the toughness.

• 콘크리트학회지
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• 제8권5호
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• pp.123-133
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• 1996

최근의 각종 사회시설의 확충에 따른 건설공사 및 교통시설 등은 많은 진동을 유발하여 사회적인 문제를 야기하고 있는 실정이다. 본 연구는 각종 제진재료를 이용하여 진동을 억제할 수 있는 콘크리트를 개발하여 각종 건설공사에서 흔히 발생할 수 있는 진동공해문제를 억제하고자 하며 아울러 폐기물의 재활용차원에서 폐자재를 이용하여 유용한 제진콘크리트를 개발하고자 하는데 그 목적이 있다. 우선, 제진재료를 이용한 압축강도 200kg/$\textrm{cm}^2$ 이상의 콘크리트 배합비를 찾기 위하여 Pilot실험을 수행하였으며, 선정된 적정배합비에 다른 진동시험제를 제작하여 재료의 동적특성 즉, 1차공명진동수, 동탄성계수 및 감쇠비를 측정하여 제진효과를 조사하였다. 제진재료로서는 Foam, Latex, Rubber Powder 그리고 Plastic Resin 등을 사용하였으며 진동의 감쇠효과가 있는 것으로 나타났다. 실험방법으로는 KS F 2437 규정과 진동파의 속도법을 사용하였으며, 감쇠비 측정은 Frequency Response Spectrum 곡선에 대한 Polynomial Curvefitting방법과 기하학적 해석방법을 이용하여 각각의 결과를 비교.분석하였다.

• 콘크리트학회지
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• 제3권3호
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• pp.101-110
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• 1991

이 연구는 피치계 탄소섬유 보강 플라이애쉬.시멘트 복합체의 여러 가지 특성을 실험적으로 구명하고, 그 제조방법을 제시한 것이다. 복합체는 조강시멘트, 시리카 분말, 스티렌 부타디엔 러버 라텍스, 기포제와 탄소섬유 및 플라이애쉬를 사용하여 제조하였고, 배합조건별로 그 특성을 검토하였다. 연구결과, 경량 탄소섬유 보강 플라이애쉬.시멘트 복합체의 압축강도, 인장강도, 휨강도, 흡수성 및 특수성 그리고 건조수축과 같은 물리적.역학적 성질은 스티렌 부타디엔 러버 라텍스를 첨가하므로써 현저히 개선되었으며, 아울러 복합체를 제조하는데는 기건양생보다 오토클래브 양생이 유리한 것으로 나타났다. 이결과, 앞으로 경량 탄소섬유 보강 플라이애쉬.시멘트 복합체를 이용한 프리캐스트 제품의 개발에 크게 기여할 수 있을 것으로 기대된다.

• 패션비즈니스
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• 제12권5호
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• pp.77-93
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• 2008

The purpose of the study was to examine make-up expression elements of horror characters as an evil spirit, a vampire, a zombie, a monster and a psycho murderer through make-up, focused on horror movies of the United States after1960s. First, an evil spirit was expressed that the pupil grew dim without a focus and the skin was torn by going bad and rot completely. Also, it was expressed that its teeth was changed to pointed canine teeth as a wild beast and its pale and bloodless face showed blood vessels clearly. To express its bloodless and pale skin, air brush was swept into the skin over several times. Its canine tooth was made acryl powder into its shape and was harden to make its shape smooth. Also, it was colored to show people like the real thing. Second, a vampire was expressed by make-up elements as long nails, a sharp canine tooth, a pale skin with a blood vessel and dead eyes. Its rough skin and long nails were manufactured with latex foam, which was colored like the skin. Third, a monster image as a werewolf was expressed by make-up elements as fur, sharp teeth, changed nails and toenails, a rough skin and a face changed to a wolf. Rubber mask and rubber body suit were manufactured as a make-up of special character and so all its body was changed. Fourth, a psycho murderer and body-deformed man were expressed by make-up elements as a distorted mask, swelled-up and deformed skull and face form, terribly deformed body, discolored and hang down skin and teeth with an indeterminate form. Its body and face were manufactured by the foam latex technology according to make-up design as a make-up of special character.

• 한국건설순환자원학회논문집
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• 제8권1호
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• pp.25-32
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• 2013

본 연구는 건설 방수 분야에서의 효율적인 재생고무의 활용을 목적으로 개발된 고점착 시트 방수재를 대상으로 현장 적용 가능성 및 성능 검증을 통해 구조물에 적용 가능한 친환경 고기능 방수 기술로 제안하는 것을 목적으로 실시하였으며, 12개월간의 장기적 평가 결과, $0.3N/mm^2$의 정수압 및 측수압에 대해 안정된 방수성능을 확인하였으며, 흡수량 및 부착강도 역시 시일경과에 따라 미미한 변화(+0.05g, $-0.1Nmm^2$)를 보여 방수성능이 안정적으로 유지되고 있음을 확인하였다. 이는 고점착 유연한 재료 특성으로 장기적 부착력 및 수압에 대한 저항성 확보로 현장 적용시 안정적인 방수층 형성 및 유지가 가능할 것으로 판단되며, 상기 연구결과를 통해 재생고무의 건설 방수분야에서의 적용이 천연고무의 재활용 기술의 확대와 향후 적극적인 응용 연구를 통하여 건축 방수시장에서의 친환경 재료를 이용한 기술적 우위를 차지할 수 있을 것으로 기대된다.

• Elastomers and Composites
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• 제34권5호
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• pp.414-422
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• 1999

방수재로 사용하는 EVA 에멀젼 수지에 라텍스 형태의 에폭시 수지, 우레탄 수지 SBR 수지를 전체 혼합물 중에 $0{\sim}50%$ 혼합하여 점성 및 경도 특성을 실험하였다. 시멘트 혼합물의 작업 가능한 한계점도는 20,000 cps이며 가사시간은 30분 이상으로 나타났다. 유색안료를 많이 혼합할수록 높은 점도를 나타내었고 시간경과에 따른 점도 상승폭도 컸다. SBR을 혼합하였을 때에는 경도가 크게 증가하였으나 에폭시 라텍스나 우레탄 라텍스를 혼합하였을 때에는 경도가 크게 증가하지 않았다. 시멘트 함량 30% 이상에서 경도가 크게 증가하였고 $50{\sim}60%$에서는 H이상의 높은 경도를 나타내었다. 고 충전시에는 라텍스의 융착보다는 시멘트 입자의 응집 및 응결에 의하여 경도가 높아졌다.