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Current Status and Future Directions of Management of Hazardous Air Pollutants in Korea - Focusing on Ambient Air Monitoring Issues - (우리나라 유해대기오염물질의 관리현황과 개선방향 - 환경대기 모니터링 문제를 중심으로 -)

  • Baek, Sung-Ok;Jeon, Chan-Gon
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.5
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    • pp.513-527
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    • 2013
  • Recently, hazardous air pollutants (HAPs) have been of great concern in Korea, largely due to public awareness on the importance of their impacts on environmental health. A group of HAPs includes a large number of various chemicals such as VOCs, PAHs, PCBs, dioxines, furans, organochlorinated pesticides, and some heavy metals. These groups of pollutants are generally known to have genetic toxicity and to be persistent in the environment. In addition, most of chemicals belong to the category of HAPs are widely distributed not only in air, but also in water and soil environments, and has therefore undergone considerable scrutiny for the last three decades. In this article, environmental implications and management of HAPs in Korea will be reviewed, with a particular emphasis on the monitoring of HAPs in the ambient air. A number of field studies will be introduced, which were recently conducted in large urban and industrial areas. Based on the filed studies, eight pollutants have been suggested to be intensively managed as higher priority pollutants, which are benzene, 1,3-butadiene, formaldehyde, acrolein, trichloroethylene, benzo(a)pyrene, hexa-valent Cr, and $PM_{2.5}$. Finally, future directions for a mega scale project for comprehensive monitoring of ambient atmosphere in large urban areas will be suggested. Such an innovative project is believed to provide more realistic information on the nature of the population exposure, which can not be simply identified by emission inventories or source investigations. Therefore, any strategy for the management of HAPs should be developed by not only emission-based approaches, but also observation-based approaches.

Design of Mesoporous Silica at Low Acid Concentrations in Triblock Copolymer-Butanol-Water Systems

  • Kleitz, Freddy;Kim, Tae-Wan;Ryoo, Ryong
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1653-1668
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    • 2005
  • Assembly of hybrid mesophases through the combination of amphiphilic block copolymers, acting as structuredirecting agents, and silicon sources using low acid catalyst concentration regimes is a versatile strategy to produce large quantities of high-quality ordered large-pore mesoporous silicas in a very reproducible manner. Controlling structural and textural properties is proven to be straightforward at low HCl concentrations with the adjustment of synthesis gel composition and the option of adding co-structure-directing molecules. In this account, we illustrate how various types of large-pore mesoporous silica can easily be prepared in high phase purity with tailored pore dimensions and tailored level of framework interconnectivity. Silica mesophases with two-dimensional hexagonal (p6mm) and three-dimensional cubi (Fm$\overline{3}$m, Im$\overline{3}$m and Ia$\overline{3}$d) symmetries are generated in aqueous solution by employing HCl concentrations in the range of 0.1−0.5 M and polyalkylene oxide-based triblock copolymers such as Pluronic P123 $(EO_{20}-PO_{70}-EO_{20})$ and Pluronic F127 $(EO_{106}-PO_{70}-EO_{106})$. Characterizations by powder X-ray diffraction, nitrogen physisorption, and transmission electron microscopy show that the mesoporous materials all possess high specific surface areas, high pore volumes and readily tunable pore diameters in narrow distribution of sizes ranging from 4 to 12 nm. Furthermore, we discuss our recent advances achieved in order to extend widely the phase domains in which single mesostructures are formed. Emphasis is put on the first synthetic product phase diagrams obtained in $SiO_2$-triblock copolymer-BuOH-$H_2O$ systems, with tuning amounts of butanol and silica source correspondingly. It is expected that the extended phase domains will allow designed synthesis of mesoporous silicas with targeted characteristics, offering vast prospects for future applications.

Technical Development for Large DNA Fragment Transformation in Plants

  • Park, Su-Ryun;Seo, Mi-Suk;Lee, Sang-Kug;Park, Jee-Young;Kim, Hye-Ran;Lee, Hyo-Yeon;Bang, Jae-Wook;Lim, Yong-Pyo
    • Journal of Plant Biotechnology
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    • v.2 no.2
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    • pp.89-96
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    • 2000
  • For large DNA fragment transformation in dicots and monocots, BIBAC2 vector system was applied to Arabidopsis thaliana and Oryza sativa L. cv. Jinmi as a model plant, respectively. For Arabidopsis, the Th1 gene in T23L3 BAC clone whose size is about 90 kb was used as the target gene source for transformation. Because T23L3 BAC clone was originally constructed in pBelloBAC11, the target gene was reconstructed into BIBAC2. As the results of reconstruction, 476 colonies were survived in selection medium containing 40 mg/L kanamycin. In colony hybridization analysis, 24 out of 476 colonies exhibited positive signals. In the pulsed-field gel electrophoresis analysis, 11 out of 24 positive clones exhibited the band at the location of 90 kb. In Southern hybridization, positive signal band at the location of 90 kb was observed in all 11 transformants. Using these verified clones, Agrobacterium-mediated transformation was applied to Arabidopsis thaliana th1-201 mutant for genetic complementation test. Twelve thousands T$_1$ seeds were harvested, and antibiotic selection test is being analyzed to verify whether these seeds were transformed. for rice, COR356 that contains 150 kb human genomic DNA in a BIBAC2 vector was used as the target gene. As the results of transformation, 151 out of 210 co-cultivated calli were survived in selection medium containing 5 mg/L hygromycin, and 45 out of 151 survived calli were regenerated into plants. Transformation efficiency was 21.6%. Progeny test using 71 seeds is being analyzed now. These results provide the potential that large DNA fragments can be transferred into both dicots and monocot by Agrobacterium-mediate d transformation system.

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The Generative Mechanism of Cloud Streets

  • Sung-Dae Kang;Fujio Kimura
    • Journal of Environmental Science International
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    • v.1 no.2
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    • pp.119-124
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    • 1992
  • Cloud streets were successfully simulated by numerical model (RAMS) including an Isolated mountain near the coast, large sensible heat flux from the sea surface, uniform stratification and wind velocity with low Froude number (0.25) in the inflow boundary The well developed cloud streets between a pair of convective rolls are simulated at a level of 1 km over the sea. The following five results were obtained: 1) port the formation of the pair of convective rolls, both strong static instability and a topographically induced mechanical disturbance are strongly required at the same time. 2) Strong sensible heat flux from the sea surface is the main energy source of the pair of convective rolls, and the buoyancy caused by condensation in the cloud is negligibly small. 3) The pair o( convective rolls is a complex of two sub-rolls. One is the outer roll, which has a large radius, but weak circulation, and the other is the inner roll, which has a small radius, but strong circulation. The outer roll gathers a large amount of moisture by convergence in the lower marine boundary, and the inner roll transfers the convergent moisture to the upper boundary layer by strong upward motion between them. 4) The pair of inner rolls form the line-shaped cloud streets, and keep them narrow along the center-line of the domain. 5) Both by non-hydrostatic and by hydrostatic assumptions, cloud streets can be simulated. In our case, non-hydrostatic processes enhanced somewhat the formation of cloud streets. The horizontal size of the topography does not seem to be restricted to within the small scale where non-hydrostatic effects are important.

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Fabrication of Porous Mo by Freeze-Drying and Hydrogen Reduction of MoO3/Camphene Slurry (MoO3/camphene 슬러리의 동결건조 및 수소환원에 의한 Mo 다공체 제조)

  • Lee, Wonsuk;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.446-450
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    • 2012
  • In order to fabricate the porous Mo with controlled pore characteristics, unique processing by using $MoO_3$ powder as the source and camphene as the sublimable material is introduced. Camphene-based 15 vol% $MoO_3$ slurries, prepared by milling at $50^{\circ}C$ with a small amount of dispersant, were frozen at $-25^{\circ}C$. Pores were generated subsequently by sublimation of the camphene during drying in air for 48 h. The green body was hydrogen-reduced at $750^{\circ}C$, and sintered at $1000-1100^{\circ}C$ for 1 h. After heat treatment in hydrogen atmosphere, $MoO_3$ powders were completely converted to metallic W without any reaction phases. The sintered samples showed large pores with the size of about $150{\mu}m$ which were aligned parallel to the camphene growth direction. Also, the internal wall of large pores and near bottom part of specimen had relatively small pores due to the difference in the camphene growth rate during freezing process. The size of small pores was decreased with increase in sintering temperature, while that of large pores was unchanged. The results are strongly suggested that the porous metal with required pore characteristics can be successfully fabricated by freeze-drying process using metal oxide powders.

Parallel Multithreaded Processing for Data Set Summarization on Multicore CPUs

  • Ordonez, Carlos;Navas, Mario;Garcia-Alvarado, Carlos
    • Journal of Computing Science and Engineering
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    • v.5 no.2
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    • pp.111-120
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    • 2011
  • Data mining algorithms should exploit new hardware technologies to accelerate computations. Such goal is difficult to achieve in database management system (DBMS) due to its complex internal subsystems and because data mining numeric computations of large data sets are difficult to optimize. This paper explores taking advantage of existing multithreaded capabilities of multicore CPUs as well as caching in RAM memory to efficiently compute summaries of a large data set, a fundamental data mining problem. We introduce parallel algorithms working on multiple threads, which overcome the row aggregation processing bottleneck of accessing secondary storage, while maintaining linear time complexity with respect to data set size. Our proposal is based on a combination of table scans and parallel multithreaded processing among multiple cores in the CPU. We introduce several database-style and hardware-level optimizations: caching row blocks of the input table, managing available RAM memory, interleaving I/O and CPU processing, as well as tuning the number of working threads. We experimentally benchmark our algorithms with large data sets on a DBMS running on a computer with a multicore CPU. We show that our algorithms outperform existing DBMS mechanisms in computing aggregations of multidimensional data summaries, especially as dimensionality grows. Furthermore, we show that local memory allocation (RAM block size) does not have a significant impact when the thread management algorithm distributes the workload among a fixed number of threads. Our proposal is unique in the sense that we do not modify or require access to the DBMS source code, but instead, we extend the DBMS with analytic functionality by developing User-Defined Functions.

An Orchestrated Attempt to Determine the Chemical Properties of Asian Dust Particles by PIXE and XRF Techniques

  • Ma, Chang-Jin;Kim, Ki-Hyun;Choi, Sung-Boo;Kasahara, Mikio;Tohno, Susumu
    • Asian Journal of Atmospheric Environment
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    • v.4 no.3
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    • pp.189-197
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    • 2010
  • An orchestrated attempt was made to analyze samples of bulk and individual particulate matters (PM) collected at the Gosan ground-based station on the west coast of Jeju, Korea. A two-stage filter pack sampler was operated to collect particles in both large (> $1.2\;{\mu}m$) and small size fractions (< $1.2\;{\mu}m$) between the Asian dust (hereafter called "AD") storm event and non-Asian dust period. Elemental components in bulk and individual particles were determined by PIXE and synchrotron XRF analysis systems, respectively. To assess the transport pathways of air parcels and to determine the spatial distribution of PM, the backward trajectories of the Meteorological Data Explorer (Center for Global Environmental Research, 2010) and the NOAA's HYSPLIT dispersion-trajectory models were applied. In line with general expectations, Si and other crustal elements in large size particles showed considerably higher mass loading on AD days in comparison with non-AD days. Computation of the crustal enrichment factors [(Z/Si)$_{particle}$/(Z/Si)$_{desert}$ sand] of elements in large size particles (> $1.2\;{\mu}m$) allowed us to estimate the source profile and chemical aging of AD particles as well as to classify the soil-origin elements. On the basis of a single particle analysis, individual AD particles are classified into three distinct groups (neutralized mineral particles, S-rich mineral particles, and imperfectly neutralized particles).

Harmonic Reduction of Electric Propulsion Ship using New Rectification Scheme (새로운 정류방식을 이용한 전기추진선박의 고조파 저감)

  • Kim, Jong-Su;Choi, Jae-Hyuk;Yoon, Kyoung-Kuk;Seo, Dong-Hoan
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.16 no.10
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    • pp.2230-2236
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    • 2012
  • Currently, the AC-to-DC power conversion system using diode rectifiers is mainly used in large vessels. Also, to reduce the total harmonic distortion(THD) of current and voltage, this system requires an additional phase-shifting transformer which can be powered multi-pulses. In this case, due to the installation of the transformer, the spatial or economic loss occurs. This paper presents a novel active rectification scheme using silicon controlled rectifier(SCR) or insulated gate bipolar transistor(IGBT) devices on behalf of the diode rectifiers which are currently operating in large vessels such as LNG Carrier(LNGC). The proposed system can use the low voltage source and reduce current and voltage harmonics generated by nonlinear loads connected to the power distribution bus and save economic costs by removing the phase-shifting transformers which are used in conventional system. Computer simulations are performed under the electric propulsion system which is operating in current large vessel. The results are shown in support of the improvement of THD included in the current and voltage wave forms of propulsion motor.

Growth and Decay of Alpha Tracks in a Large Scale Cloud Chamber after Injection of Radon

  • Wada, Shinichi;Kobayashi, Tsuneo;Katayama, Yoshiro;Iwami, Toshiaki;Kato, Tsuguhisa;Cameron, John R.
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2002.09a
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    • pp.275-278
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    • 2002
  • The recognition of the natural background radiation is important not only for radiological education but also for the promotion of people's scientific view about radiation. We made a "room" on the web showing natural background radiation as part of a VRM (Virtual Radiation Museum). The "room" shows the video images of the tracks of charged particles from natural background radiation, alpha and beta ray track from known sources using a Large Scale Diffusion Cloud Chamber. The purpose of this study is to make clear the origin of a kind of track (named A-track) which is thick and easy to recognize with the length less than several cm in the cloud chamber, and to make numerical explanation of its counting rate. The study was carried out using a Large Scale Diffusion Cloud Chamber (Phywe, Germany) installed in the Niigata Science Museum. The Model RNC (Pylon Electronics, Canada) was used as Rn-222 source. Ra-226 activity in RNC was 111.6 Bq calibrated with NIST protocol. Rn-222 gas was injected into the cloud chamber. Continuous video recording with use of Digital Handycam (SONY, Japan) was carried out for 360 min. after injection of Rn-222 gas. The number of alpha-ray track (alpha track) in the video images was analyzed. The growth and decay curve of the total activity of Rn-222 and its alpha emitting progeny were calculated and compared with the count of the alpha tracks. As a result the alpha tracks formed by Rn-222 injection resemble A-Tracks. The relationship between A-track in the cloud chamber and atmospheric Rn is discussed.

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The Effect of Source of Dietary Fiber and Starch on Ileal and Fecal Amino Acid Digestibility in Growing Pigs

  • Wang, J.F.;Wang, M.;Lin, D.G.;Jensen, B.B.;Zhu, Yaohong
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.7
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    • pp.1040-1046
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    • 2006
  • Studies were carried out with a repeated $4{\times}4$ Latin square design with eight cannulated pigs fed four experimental diets to investigate the effect of dietary fiber and starch sources on apparent ileal and fecal amino acid digestibility. Each period lasted 15 d, with diet acclimation from d 1 to 7, feces collection for 48 h on d 8 to 9 and ileal sample collection for 12 h on d 13 to 15. The four experimental diets consisted mainly of cooked rice with the addition of protein sources (CON), partial replacement of cooked rice with either potato starch (PS), sugar beet pulp (SBP) or wheat bran (WB). Chromic oxide was used as an indigestible marker. With the exception of histidine, lysine and tryptophan, no differences were observed in the apparent ileal digestibility of amino acids between diets. The inclusion of potato starch did not affect the ileal and fecal amino acid digestibility. In comparison with diet CON, a decreased (p<0.05) ileal digestibility of histidine was found in pigs fed diet SBP, while the ileal digestibilities of histidine, lysine and tryptophan were decreased (p<0.05) by the inclusion of wheat bran. Inclusion of fiber sources (sugar beet pulp and wheat bran) caused a reduction (p<0.05) in the fecal amino acid digestibility and the net disappearance of amino acids in the large intestine. Of the indispensable amino acids, there was a 'net synthesis' for methionine in the large intestine of pigs when diets were supplemented with dietary fiber. The decrease in fecal amino acid digestibility with the addition of dietary fiber indicates an increase in the synthesis of bacterial protein in the large intestine.