• 제목/요약/키워드: large area synthesis

검색결과 168건 처리시간 0.072초

Enantiomer의 분리에 이용될 수 있는 Chelate Resin의 개발 (제1보) -가교 폴리스티렌 Resin Matrix의 염화메칠화에 있어서의 용매효과- (Development of Optically Active Chelate Resin for Direct Resolution of Enantiomers (I) -Solvent Effects in Chloromethylation of Crosslinked Polystyrene Resin Matrix-)

  • 김길수;전동원;박경혜
    • Journal of Pharmaceutical Investigation
    • /
    • 제18권2호
    • /
    • pp.69-81
    • /
    • 1988
  • We studied on the synthesis of chloromethylated polystyrene as a precursor of optically active polymers for direct resolution of optical isomers. Changing the degree of crosslinking and the kind of crosslinking agents, several polystyrene resin matrices were synthesized. The matrices were chloromethylated with methylal and chlorosulfonic acid as chloromethylating agents. The effects of solvents of various dielectric constants on the chloromethylation were quantitavely examined. We also synthesized chloromethylated polystyrene of macroreticular type that retained large surface area and good physical stability. The differences between the macroreticular type and macroporous type were investigated.

  • PDF

Synthesis and Characterization of Crosslinked Hole Transporting Polymers for Organic Light Emitting Diodes

  • Jang, Do-Young;Lim, Youn-Hee;Kim, Joo-Hyun;Kim, Jang-Joo;Shin, Jung-Hyu;Yoon, Do-Y.
    • 한국고분자학회:학술대회논문집
    • /
    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
    • /
    • pp.235-235
    • /
    • 2006
  • Triphenylamine derivatives play important roles as hole transporting materials in organic light emitting devices. However, low molecular weight triphenylamine derivatives show low glass transition temperature and aggregation behavior, and the vapor deposition step of low molecular weight materials is incompatible with large area display fabrication. Conventional polymer PEDOT-PSS HTL has serious drawbacks such as the ITO anode corrosion, poor surface energy match with aromatic EMLs. To solve these problems, we introduced crosslinkable units to triphenylamine-based polymers to make insoluble HTL by thermal curing following spin-coating. Electrochemical and optical properties of the new hole transporting materials were investigated. In addition, the device characteristics obtained with new hole transporting polymers were investigated in details.

  • PDF

효율적인 실시간 영상처리용 2-D 컨볼루션 필터 칩 (An Efficient 2-D Conveolver Chip for Real-Time Image Processing)

  • 은세영;선우명
    • 전자공학회논문지C
    • /
    • 제34C권10호
    • /
    • pp.1-7
    • /
    • 1997
  • This paper proposes a new real-time 2-D convolver filter architecture wihtout using any multiplier. To meet the massive amount of computations for real-time image processing, several commercial 2-D convolver chips have many multipliers occupying large VLSI area. Te proposed architecture using only one shift-and-accumulator can reduce the chip size by more than 70% of commercial 2-D convolver filter chips and can meet the real-time image processing srequirement, i.e., the standard of CCIR601. In addition, the proposed chip can be used for not only 2-D image processing but also 1-D signal processing and has bood scalability for higher speed applications. We have simulated the architecture by using VHDL models and have performed logic synthesis. We used the samsung SOG cell library (KG60K) and verified completely function and timing simulations. The implemented filter chip consists of only 3,893 gates, operates at 125 MHz and can meet the real-time image processing requirement, that is, 720*480 pixels per frame and 30 frames per second (10.4 mpixels/second).

  • PDF

Hydrothermally Synthesized TiO2 Nanoparticles as a Cathode Catalyst Material in Lithium-Oxygen Batteries

  • Kang, Seung Ho;Song, Kyeongse;Jung, Jaepyeong;Jo, Mi Ru;Khan, M. Alam;Kang, Yong-Mook
    • Journal of Electrochemical Science and Technology
    • /
    • 제5권2호
    • /
    • pp.45-48
    • /
    • 2014
  • $TiO_2$ nanoparticles (NPs) with a diameter of 100 nm were synthesized by a simple hydrothermal route at $220^{\circ}C$ and then processed for a possible alternate cathode catalyst material in the lithium-oxygen batteries. It was found that when $TiO_2$ nanoparticles were utilized as cathodes, substantial improvements in the discharge capacity, cycle ability, rate capability and low overpotential were observed. This can be attributed to its high catalytic activity and large surface area.

Hydrothermally Synthesized TiO2 Nanoparticles as a Cathode Catalyst Material in Lithium-Oxygen Batteries

  • Kang, Seung Ho;Song, Kyeongse;Jung, Jaepyeong;Jo, Mi Ru;Khan, M. Alam;Kang, Yong-Mook
    • Journal of Electrochemical Science and Technology
    • /
    • 제5권4호
    • /
    • pp.105-108
    • /
    • 2014
  • $TiO_2$ nanoparticles (NPs) with a diameter of 100 nm were synthesized by a simple hydrothermal route at $220^{\circ}C$ and then processed for a possible alternate cathode catalyst material in the lithium-oxygen batteries. It was found that when $TiO_2$ nanoparticles were utilized as cathodes, substantial improvements in the discharge capacity, cycle ability, rate capability and low overpotential were observed. This can be attributed to its high catalytic activity and large surface area.

Low-Power Bus Architecture Composition for AMBA AXI

  • Na, Sang-Kwon;Yang, Sung;Kyung, Chong-Min
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • 제9권2호
    • /
    • pp.75-79
    • /
    • 2009
  • A system-on-a-chip communication architecture has a significant impact on the performance and power consumption of modern multi-processors system-on-chips (MPSoCs). However, customization of such architecture for a specific application requires the exploration of a large design space. Thus, system designers need tools to rapidly explore and evaluate communication architectures. In this paper we present the method for application-specific low-power bus architecture synthesis at system-level. Our paper has two contributions. First, we build a bus power model of AMBA AXI bus communication architecture. Second, we incorporate this power model into a low-power architecture exploration algorithm that enables system designers to rapidly explore the target bus architecture. The proposed exploration algorithm reduces power consumption by 20.1% compared to a maximally connected reduced matrix, and the area is also reduced by 20.2% compared to the maximally connected reduced matrix.

카본 나노재료 합성을 위한 표면파 플라즈마 CVD 기술 (Surface wave excited plasma CVD technologies for the synthesis of carbon nanomaterials)

  • 김재호
    • 진공이야기
    • /
    • 제2권4호
    • /
    • pp.16-26
    • /
    • 2015
  • Carbon nanomaterials including nanocrystalline diamond and graphene films are expected to play a core role in $21^{st}$ century industries due to their amazing physicochemical properties. To achieve their practical utilization and industrialization, the development of their mass production technologies is strongly required. Recently, a surface wave excited plasma (SWP) which is produced using microwaves has been attracting special attentions as a candidate for the mass production technology of carbon nanomaterials. SWP can allow a low-temperature large-area plasma chemical vapor deposition (CVD) system. Here, this article introduces the promising SWP-CVD technology. Plasma characteristics in a SWP will be introduced in detail to help understanding how to use and control a SWP as a plasma source for CVD applications.

Fabrication of Organic Nanowire Electronics by Direct Printing Method

  • 박경선;성명모
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.563-563
    • /
    • 2012
  • We report a one-step fabrication of single-crystal organic nanowire arrays on substrates using a new direct printing method (liquid-bridge-mediated nanotransfer moulding, LB-nTM), which can simultaneously enable the synthesis, alignment and patterning of the nanowires using molecular ink solutions. Two- or three-dimensional complex structures of various single-crystal organic nanowires were directly fabricated over a large area with a successive process. The position of the nanowires can be aligned easily on complex structures because the mold is movable on substrates before drying the polar liquid layer, which acts as an adhesive lubricant. This efficient manufacturing method can produce a wide range of optoelectronic devices and integrated circuits with single-crystal organic nanowires.

  • PDF

Single-Crystal Poly(3,4-ethylenedioxythiopene) Nanowires as Electrodes for Field-Effect Transistors

  • 조보람;성명모
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.637-637
    • /
    • 2013
  • We develop single-crystal poly(3,4-ethylenedioxythiopene nanowires using liquid-bridge-mediated nanotransfer printing via vapor phase polymerization. This direct printing method can simultaneously enable the synthesis, alignment and patterning of the nanowires from molecular ink solutions. Twoor three-dimensional complex structures of various single-crystal organic nanowires were directly fabricated over a large area using many types of molecular inks. This method is capable of generating several optoelectronic devices. LB-nTM is based on the direct transfer of various materials from a mold to a substrate via a liquid bridge between them. To demonstrate its usefulness, we used LB-nTM to fabricate nanowire field-effect transistors and arrays of 6,13-bis (triisopropyl- silylethynyl) pentacene (TIPS-PEN) nanowire field-effect transistors.

  • PDF

All-Organic Nanowire Field-Effect Transistors and Complementary Inverters Fabricated by Direct Printing

  • 박경선;성명모
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.632-632
    • /
    • 2013
  • We generated single-crystal organic nanowire arrays using a direct printing method (liquidbridge- mediated nanotransfer molding) that enables the simultaneous synthesis, alignment and patterning of nanowires from molecular ink solutions. Using this method, single-crystal organic nanowires can easily be synthesized by self-assembly and crystallization of organic molecules within the nanoscale channels of molds, and these nanowires can then be directly transferred to specific positions on substrates to generate nanowire arrays by a direct printing process. The position of the nanowires on complex structures is easy to adjust, because the mold is movable on the substrates before the polar liquid layer, which acts as an adhesive lubricant, is dried. Repeated application of the direct printing process can be used to produce organic nanowire-integrated electronics with twoor three-dimensional complex structures on large-area flexible substrates. This efficient manufacturing method is used to fabricate all-organic nanowire field-effect transistors that are integrated into device arrays and inverters on flexible plastic substrates.

  • PDF