• Title/Summary/Keyword: lamellar

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Vibrational Spectroscopic Studies of Crystallization in Mixed n-Paraffins (진동분광실험을 이용한 n-Paraffin혼합물의 결정화에 관한 연구)

  • 김도균;임현주;최선남;김성수;송기국
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.752-758
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    • 2002
  • FTIR, FT-Raman, and X-ray diffraction techniques were used to determine chain segregations and lamellar structures of the mixed binary n-paraffins with different chain lengths. The results of three different techniques, infrared spectroscopic studies of crystal field splitting, the Raman longitudinal acoustic mode, and the SAXS long period measurements were compared one another to understand the crystallization mechanism of separated or mixed n- paraffin lamellae.

Spherulitic Morphologies of Poly(ethylene terephthalate), Poly(ethylene 2,6-naphthalate), and Their Blend

  • Lee, Jong-Kwan;Lee, Kwang-Hee;Jin, Byung-Suk
    • Macromolecular Research
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    • v.10 no.1
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    • pp.44-48
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    • 2002
  • The supermolecular structures of poly(ethylene terephthalate) (PET), poly(ethylene 2,6-naphthalate) (PEN), and their blend were investigated with optical microscopy and small angle light scattering. With increasing the crystallization temperature, incomplete spherulitic texture was developed for the PET samples. At a high crystallization temperature of 220 $^{\circ}C$, the light scattering pattern represented a random collection of uncorrelated lamellae. The general morphological appearances for the PEN samples were similar to that of the PET. A notable feature was that the spherulites of the PEN formed at 200 $^{\circ}C$ showed regular concentric bands arising from a regular twist in the radiating lamellae. The spherulitic morphology of the PET/PEN blend was largely influenced by the changes of the sequence distribution in polymer chains determined by the level of transesterifcation. The increased sequential irregularity in the polymer chains via transesterification caused a morphological transition from a regular folded crystallite to a tilted lamellar crystallite.

Toxicity and Effects of the Herbicide Glufosinate-Ammonium (Basta) on the Marine Medaka Oryzias dancena

  • Kang, Gil Ran;Song, Ha Yeun;Kim, Dong Soo
    • Fisheries and Aquatic Sciences
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    • v.17 no.1
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    • pp.105-113
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    • 2014
  • Glufosinate-ammonium, a component of the herbicide Basta, is one of the most extensively used pesticides worldwide. In this study, we assessed subchronic and chronic toxicities of Basta and its histopathological effects on the marine medaka Oryzias dancena. Marine medaka were exposed to 0, 2, 4, or 8 mg/L of Basta for 28 or 42 days. The lethal concentration ($LC_{50}$) of Basta for 96 h is 8.76 mg/L. Histological changes in the gills and liver were evaluated with histopathological indices, allowing quantification of the damage to fish exposed to Basta. Blood congestion, lamellar fusion, and epithelial lifting were observed in the gills, and hydropic degeneration, fibrosis, lipid degeneration, leukocyte infiltration, and necrosis were found in the liver. These responses could be useful indicators of Basta toxicity in this species.

RIDGE AUGMENTATION USING OF HARD TISSUE $REPLACEMENT(HTP^{TM})$;A CASE REPORT (치조제 증강을 위한 $HTR^{TM}$ 중합체 이식후 치유과정;증례보고)

  • Kim, Su-Gwan;Lim, Sung-Chul
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.22 no.1
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    • pp.83-85
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    • 2000
  • The purpose of this study is to evaluate the effect of $HTR^{TM}$ (hard tissue replacement, Bioplant Inc, U.S.A) polymer on short-term healing as a grafting material for alveolar ridge augmentation. A 48-year-old female presented insufficient bone height and width for the placement of implants. $HTR^{TM}$ polymer was used for ridge augmentation. Bone biopsy was harvested 8 months after the ridge augmentation procedure. $HTR^{TM}$ polymer displayed rapid bone regeneration and mature lamellar and trabecular bone redevelopment. Clinical and histologic observation from the treatment of the patient presented suggest that $HTR^{TM}$ polymer seems to be a appropriate material for alveolar ridge augmentation.

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Ossification of the Achilles tendon in a child - A case report - (소아에서 발생한 아킬레스건의 골화증 - 증례보고 -)

  • Suh, Jin-Soo;Kim, Jin-Hwan;Choo, Suk-Gyu
    • Journal of Korean Foot and Ankle Society
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    • v.6 no.2
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    • pp.224-228
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    • 2002
  • Ossification of the Achilles tendon is a rare condition to be distinguished from the more frequently occuring tendon calcification. It is characterized by the presence of an ossific mass contained within the fibrocartilaginous substance of the tendon and is usually associated with prior surgery or trauma to the tendon. We treated a 13 year old girl with ossification of the Achilles tendon after sprain-like injury. We excised it one year later and the microscopic finding of the extirpated bony mass revealed fully maturated lamellar bone.

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Fabrication of Nano-laminar Glass Composite Using Thin Flake

  • Kakisawa, Hideki;Minagawa, Kazumi;Halada, Kohmei
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.330-331
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    • 2006
  • Fabrication of a nano-laminar ceramic composite by sintering thin ceramic plates was examined. Silver-coated glass flakes with a thickness of less than $1{\mu}m$ were consolidated by pulsed current sintering or hotpressing to obtain model composites. The samples sintered at the optimum conditions were fairly dense, and the flakes were aligned by uniaxial press. The metal coating remained on the flakes through the sintering process, and became an interface layer between the flakes. No crack propagation through the transverse direction of the lamellar was observed in the indentation test. The possibilities of high resistance against crack propagation was suggested.

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Micro-Structural Enhancement of XLPE Insulation Using Additive Diffusion Method

  • Park, Se-Eun;Shim, Sung-Ik;Cho, Dae-Hee;Youn, Bok-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.238-239
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    • 2005
  • With the aim of developing XLPE insulation for extra high voltage cable, we investigated the morphology of cross-linked polyethylene. We used a kind of base materials and additives, and controlled curing condition and amount of additives. The effect of addition of additives on morphology of XLPE such as lamellar density, orientation and additive layer were analyzed using TEM analysis. We applied this result to diffused additive amount was analyzed using FT-IR analysis, and the change of microstructure as the degree of additive diffusion was analyzed using TEM analysis.

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Surgical Treatment of Corneal Sequestrum with Porcine Urinary Bladder Submucosa Extracellular Matrix (ACeLL Vet® Corneal Disc) in Two Cats

  • Kim, Youngsam;Kang, Seonmi;Nam, Sunhwa;Yun, Seongjin;Seo, Kangmoon
    • Journal of Veterinary Clinics
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    • v.37 no.4
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    • pp.213-216
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    • 2020
  • Two cats were presented to the Dana Animal Hospital Eye Center and were diagnosed with corneal sequestrum through full ophthalmic examination. After lamellar keratectomy using a reusable corneal trephine blade and a crescent microsurgical knife, porcine urinary bladder submucosa extracellular matrix (UBM, ACeLL Vet® corneal disc) was applied to the corneal defects. In both cases, no corneal sequestrum recurrences were observed until 119 days and 253 days after the surgery, respectively. Porcine UBM could be recommended as a surgical scaffold for treatment of corneal sequestrum in cats.

Microstructural Factors on Ductility in Steels containing Pearlite (펄라이트 함유강에서 연성에 영향을 미치는 미세조직 인자)

  • 심혜정;송형락;남원종
    • Transactions of Materials Processing
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    • v.13 no.5
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    • pp.415-421
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    • 2004
  • The effect of transformation temperature on microstructural features and their effects on ductility in 0.55%C steels were investigated, compared with in 0.82%C eutectoid steel. The samples were austenitized at 100$0^{\circ}C$ for 30min. followed by quenching in a salt bath in the temperature range of 500 ~ $620^{\circ}C$. It was found that reduction of area(RA) increased with increasing transformation temperature and then, decreased after reaching its maximum value in steels containing pro-eutectoid ferrite less than 6%. The thickness of lamellar cementite was found to be the main factor controlling RA. Additionally, the presence of cementite thickness for the maximum ductility in all the tested steels was observed as about 0.015${\mu}{\textrm}{m}$ for tested steels.

Development of Carbon Nitride Coating for High Wear Resistant Rolling Element (내마모 전동체 제조를 위한 질화탄소코팅의 개발)

  • Choi, Byung-Young;Umehara, Noritsugu
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.11
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    • pp.243-247
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    • 1999
  • Carbon nitride coatings on the substrates of 0.55wt% C - 1.68wt% Mn induction-hardened rolling elements were prepared by ion beam assisted deposition. It was found through metallographic observation that the carbon nitride coatings appeared lamellar-type repeated layers parallel to the surface of substrate. Surface roughness of the coated specimens was improved in comparison with that of the substrates. Wear resistance of the coatings was evaluated using Polymet RCF-1 machine with a constant supply of lubricant followed by Weibull statistical analysis and scanning electron microscopy. the results indicated failure due to old-age wear-out of the coatings was mainly caused by numerous micropits formed on the wear track during repeated rolling contact.

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