• 제목/요약/키워드: lRE

검색결과 932건 처리시간 0.03초

혼합용매를 이용한 진생베리 추출물 최적 공정 개발 및 추출물의 진세노사이드 분석 (Process Optimization of Ginseng Berry Extract Using Mixed Solvent and its Ginsenoside Analysis)

  • 하유진;김미리;유선균
    • 한국산학기술학회논문지
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    • 제16권11호
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    • pp.7794-7800
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    • 2015
  • 진생베리에 포함이 되어 있는 진세노사이드들은 인체에 유용한 다양한 생리기능물질을 포함한 것으로 알려졌다. 특히 진생베리는 진세노사이드 Re가 다량으로 함유된 것으로 알려 졌으나 추출공정은 비교적 연구가 이루어지지 않았기 때문에 본 연구에서는 진생베리로부터 복합 용매인 주정과 정제수를 이용하여 최적 공정 조건 확립을 수행하였다. 진생베리 추출물 제조를 위해서 건조 진생베리 분말 10 g를 부직포에 담아 250 mL 추출용 둥근 플라스크에 넣고 150 mL 용매를 넣어 내용물이 완전히 잠기게 한 후에 플라스크를 냉각 순환 수조에 연결을 하여 환류 추출하였다. 추출 과정은 주정과 정제수의 혼합비율, 복합용매의 추출 온도, 추출 시간 및 추출 회수에 따라 수행하였다. 추출 후 진세노사이드 Re, Rg1, Rd 및 조 진세노사이드의 함량 및 수율을 비교하였다. 최적 추출조건으로 주정 및 정제수 의 비율은 70% 대 30%, 추출온도는 $80^{\circ}C$, 추출 시간은 4시간, 추출 횟수는 2회로 결정되었다. 최적 추출 공정 조건에서 총 진세노사이드 함량은 건조 진생베리 g 당 약 88.6 mg이었다. 주요 진세노사이드의 분포는 Rb1이 5.3%, Rc가 5.2%, Rd가 14.3%, Re가 51.5%, Rf가 8.1%, Rg1이 15.7%이었다. 전체 추출 진세노사이드 중에 protopanaxatriol 계통의 진세노사이드가 약 80%를 차지하였다.

HDPy 및 HDTMA로 개질된 벤토나이트에 대한 Re(VII)의 흡착반응 분석 (Investigation of Sorption Reaction of Re(VII) onto HDPy- and HDTMA-modified Bentonite)

  • 최준명;하준혁;최란영;이준엽
    • 방사선산업학회지
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    • 제18권3호
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    • pp.167-171
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    • 2024
  • Technetium-99 (99Tc) is recognized as a critical concern in the disposal of spent nuclear fuel due to its long half-life and remarkable stability, existing predominantly as TcO4- in the natural environment. The anionic form of technetium is highly soluble and mobile, posing significant environmental risks from the viewpoint of nuclear waste management. Thus, developing efficient and cost-effective sorbents for aqueous Tc(VII) is essential for mitigating relevant contamination. In the present work, the adsorption characteristics of Re(VII), a chemical analog of Tc(VII), were investigated using the clay mineral bentonite, modified with two different organic cations: hexadecylpyridinium (HDPy) and hexadecyltrimethylammonium (HDTMA). Sorption experiments were conducted at a liquid-to-solid ratio of 1 g/L with Re(VII) solutions prepared at concentrations from 10-4 mol/L to 10-6 mol/L. The sorption ratio and distribution coefficients were determined with samples collected at reaction times of 10, 50, 100, and 500 minutes after 0.45 ㎛ syringe filtration. In parallel, the modified bentonite samples were further analyzed using the X-ray diffraction (XRD) method to understand the adsorption mechanism of Re(VII) onto the target minerals. According to the quantification analysis results, a rapid equilibrium reaction of aqueous Re(VII) for all modified bentonite samples was identified. Moreover, near-complete adsorption of Re(VII) was observed when the bentonite was modified at 200-400% of its cation exchange capacity (CEC) for both organic cations. For cases of lower modification, the HDTMA-modified bentonite showed relatively higher adsorption efficiency compared with the one modified with HDPy. This result was inferred to be due to the difference in inter-layer spacing based on the characteristics of the organic cations. It is expected that the results obtained through this study will serve as a preliminary case for the synthesis of adsorbents for the retardation of highly mobile anionic radionuclides, such as I and Tc, in the natural environment.

Systematic influence of wind incident directions on wind circulation in the re-entrant corners of high-rise buildings

  • Qureshi, M. Zahid Iqbal;Chan, A.L.S.
    • Wind and Structures
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    • 제22권4호
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    • pp.409-428
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    • 2016
  • The mechanical and aerodynamic effect of building shape plays a dominate role in the pedestrian level wind environment. These effects have been presented in numerous studies and are available in many wind codes. However, most studies have focused on wind flow around conventional buildings and are limited to few wind directions. The present study investigated wind circulation in the re-entrant corners of cross-shaped high-rise buildings from various wind directions. The investigation focused on the pedestrian level wind environment in the re-entrant corners with different aspect ratios of building arrangements. Ninety cases of case study arrangements were evaluated using wind tunnel experimentation. The results show that for adequate wind circulation in the re-entrant corners, building orientations and separations play a critical role. Furthermore, in normal wind incident directions and at a high aspect ratio, poor wind flow was observed in the re-entrant corners. Moreover, it was noted that an optimized building orientation and aspect ratio significantly improved the wind flow in re-entrant corners and through passages. In addition, it was observed that oblique wind incident direction increased wind circulation in the re-entrant corners and through passages.

Forces and flow around three side-by-side square cylinders

  • Zheng, Qinmin;Alam, Md. Mahbub;Rehman, S.;Maiti, D.K.
    • Wind and Structures
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    • 제29권1호
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    • pp.1-13
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    • 2019
  • A numerical investigation on forces and flow around three square cylinders in side-by-side arrangement is conducted at a Reynolds number Re = 150 with the cylinder center-to-center spacing ratio L/W = 1.1 ~ 9.0, where W is the cylinder side width. The flowat this Re is assumed to be two-dimensional, incompressible, and Newtonian. The flow simulation is conducted by using ANSYS-Fluent. The flow around the three side-by-side cylinders entails some novel flow physics, involving the interaction between the gap and free-stream side flows as well as that between the two gap flows. An increase in L/W from 1.1 to 9.0 leads to five distinct flow regimes, viz., base-bleed flow (L/W < 1.4), flip-flopping flow (1.4 < L/W < 2.1), symmetrically biased beat flow (2.1 < L/W < 2.6), non-biased beat flow (2.6 < L/W < 7.25) and weak interaction flow (7.25 < L/W < 9.0). The gap flow behaviors, time-averaged and fluctuating fluid forces, time-averaged pressure, recirculation bubble, formation length, and wake width in each flow regime are discussed in detail.

Ion Exchange Recovery of Rhenium and Its Determination in Aqueous Solutions by Diffuse Reflection Spectroscopy

  • Kalyakina, O.P.;Kononova, O.N.;Kachin, S.V.;Kholmogorov, A.G.
    • Bulletin of the Korean Chemical Society
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    • 제25권1호
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    • pp.79-84
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    • 2004
  • The existing technological schemes for processing rhenium-containing raw materials involve the recovery of Re from solutions, which can be effectively achieved by anion exchange method. The application of anion exchange also allows to study rhenium state in aqueous solutions and to develop analytical control methods. The present work is focused on investigation of ion exchange equilibrium in the analytical system Re(VII)-HCl-$SnCl_2$-KSCN-anion exchanger by means of sorption-desorption method as well as by electron, IR- and diffuse reflection spectroscopy. It was shown that rhenium can be quantitatively recovered from this system. It is proposed to use the sorption-spectroscopic method for Re(VII) determination in aqueous solutions. The calibration curve is linear in the concentration range of 0.5-20.0 mg/L (sample volume is 25.0 mL) and the detection limit is 0.05 mg/L. The presence of Mo(VI), Cu(II), Fe(II, III), Ni(II), Zn(II) as well as $K^+,\;Na^+$ do not hinder the solid-phase determination of rhenium. Rhenium (VII) determination by diffuse reflection spectroscopy was carried out in model solutions as well as in samples of river-derived water and in solutions obtained after the dissolution of spent catalysts.

단감(Diospyros Kaki L.)껍질 추출물의 신경세포 보호 효과 (Neuroprotective Effects of Extracts from Diospyros kaki L. Peel)

  • 이미라;문성희;최애란;이승철;안광환;박해룡
    • 한국식품조리과학회지
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    • 제27권4호
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    • pp.67-73
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    • 2011
  • This study was performed to assess the neuroprotective effects of methanolic extracts from sweet persimmon peel (PPE) against glutamate-induced cytotoxicity in hybridoma N18-RE-105 cells. The neuroprotective effects of PPE in N18-RE-105 cells were measured using the MTT reduction assay, LDH release assay, and phase-contrast microscopy. The results of the MTT reduction assay showed that treating cells with 500 ${\mu}g/ml$ PPE resulted in cell viability of 66.9%. Additionally, the morphological changes and the results of the LDH release assay showed that glutamate-induced damage to nerve cells was strongly inhibited by PPE. GSH content of N18-RE-105 cells was 3.5 ${\mu}M$ compared to that of the control, whereas pretreatment with 500 ${\mu}g/ml$ PPE increased GSH content by 4.7 ${\mu}M$. PPE was fractionated with hexane, and that layer had the highest neuroprotective effects in glutamate-stressed N18-RE-105 cells. In conclusion, our data showed that glutamate potentiated the effects of N18-RE-105 cell death by a mechanism involving oxidative stress. Therefore, PPE may be a potential candidate for prevention and therapy of neurodegenerative diseases.

호흡 재교육 훈련이 만성 목통증 환자의 통증과 기능장애 수준, 자세, 삶의 질, 폐 기능에 미치는 영향: 무작위 대조군 실험 (Effects of Breathing Re-education Training on Pain and Dysfunction Levels, Posture, Quality of Life, Pulmonary Function in Patients with Chronic Neck Pain: A Randomized Controlled Trial)

  • 이상휴;김선엽
    • 대한정형도수물리치료학회지
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    • 제30권1호
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    • pp.29-42
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    • 2024
  • Background: This study aimed to determine the effects of training on breathing re-education on pain and dysfunction levels, posture, quality of life (QoL), and pulmonary function in patients. Methods: This study included 34 patients with chronic neck pain and upper thoracic breathing pattern were included. The participants were assigned to either the routine physical therapy program (RPTP) (CG; n=17) or RPTP and breathing pattern re-education training (EG; n=17). The CG and EG groups performed RPTP for 40 minutes, and only the EG groups performed breathing re-education training for 10 minutes. Exercises were performed thrice weekly for both groups. Level of pain and dysfunction, posture, QoL and pulmonary function status were assessed before and after the intervention. Results: After four weeks of intervention, numeric pain rating scale (NPRS), Korean version of neck disability index, cranio-vertebral angle, cranial rotation angle, and 12-item short form health survey-physical and mental component summaries had significant differences before and after intervention in both groups (p<.01). However, only NPRS, forced vital capacity, forced expiratory volume in 1s, and maximum voluntary ventilation showed significant interactions between the two groups and measurement time (p<.01). Conclusion: Breathing re-education training and RPTP may be optimal for patients with chronic neck pain and may be more effective in improving neck pain and pulmonary function.

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All-in-one adhesive의 다층적용이 미세인장결합강도에 미치는 영향 (THE EFFECT OF MULTIPLE APPLICATION ON MICROTENSILE BOND STRENGTH OF ALL-IN-ONE DENTIN ADHESIVE SYSTEMS)

  • 손성애;허복
    • Restorative Dentistry and Endodontics
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    • 제29권5호
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    • pp.423-429
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    • 2004
  • The purpose of this study was to evaluate the effect of multiple application of all-in-one dentin adhesive system on microtensile bond strength using confocal laser scanning microscope and microtensile bond strength test. Flat occlusal dentin surfaces were prepared using low-speed diamond saw. In group I, Scotchbond Multipurpose (SM) was applied by manufacturer's recommendation. In group II, after Adper Prompt L-Pop was applied for 15s and light cured for 10s. the second coat was re-applied and light-cured. In group III, after light-curing the second layer. the third coat was re-applied and light-cured. Specimens bonded with a resin-composite were sectioned into resin-dentin stick for measuring the adhesive layer thickness by confocal laser scanning microscope and evaluating micro-tensile bond strength. The adhesive layers of three-step dentin adhesive system. 3 coats of Adper Prompt L-Pop had significantly thicker than SM. 2 coats of Adper Prompt L-Pop (p < 0.05). However. there was no significant differences in bond strengths between SM and 3 coats of Adper Prompt L-Pop (p > 0.05). And SM. 3 coats of Adper Prompt L-Pop had significantly higher than 2 coats of Adper Prompt L-Pop in bond strengths (p < 0.05).

The effective of Radiation Pattern on Two Shape of Slot Antenna

  • Chanwattanapong, W.;Anantrasirichai, N.;Wakabayachi, T.
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2003년도 ICCAS
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    • pp.1660-1663
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    • 2003
  • This paper present the characteristics of radiation pattern of microstrip slot antenna on the ground plane fed by microstrip line. It is proposed for resonance frequency at 10 GHz. We will analysis two shape of slot antenna; double L-shape slot antenna and U-shape slot antenna. In this case, we will compare far-field radiation pattern of two shape slot antenna. Far-field radiation pattern of double L-shape slot antenna is bi-directional nevertheless U-shape slot antenna is uni-directional. The microstrip slot antenna is propose to analyze far-field radiation pattern for use in the wireless communication systems

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