• Title/Summary/Keyword: kinetic transport model

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Evaluation of Bacterial Transport Models for Saturated Column Experiments

  • Ham, Young-Ju;Kim, Song-Bae;Kim, Min-Kyu;Park, Seong-Jik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.7
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    • pp.55-63
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    • 2006
  • Bacterial transport models were evaluated in this study to determine the suitable model at describing bacterial transport in saturated column experiments. Four models used in the evaluation were: advective-dispersive equation (ADE) + equilibrium sorption/retardation (ER) + kinetic reversible sorption (KR) (Model I), ADE + two-site sorption (Model 2), ADE + ER + kinetic irreversible sorption (KI) (Model 3), ADE + KR + KI (Model 4). Firstly, analyses were performed with the first experimental data, showing that Model 4 is appropriate for describing bacterial transport. Even if Model 1 and 2 fit well to the observed data, they have a defect of not including the irreversible sorption, which is directly related to mass loss of bacteria. Model 3 can not properly describe the tailing observed in the data. However, further analysis with the second data indicates that Model 4 can not describe retardation of bacteria, even if the sorption-related parameters are varied. Therefore, Model 4 is modified by incorporating retardation factor into the model, resulting in the improved fitting to the data. It indicates that the transport model, into which retardation, kinetic reversible sorption, and kinetic irreversible sorption are incorporated, is suitable at describing bacterial transport in saturated column experiments. It is expected that the selected transport model could be applied to properly analyze the bacterial transport in saturated porous media.

A Kinetic Study of Phosphate Absorption by Rice Roots (벼에 의한 인산흡수의 기작에 관한 연구)

  • 장남기
    • Journal of Plant Biology
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    • v.21 no.1_4
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    • pp.33-38
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    • 1978
  • Phosphate absorption from a Na2H32PO4 solution by Oryza sativa L. was studied in order to elucidate kinetic mechanisms of ion transport. The rates of phosphate absorption from different concentraitons indicated the presence of dual mechanisms in root tips, one in the low (1$\times$10-6 to 8$\times$10-5M) and the other in the high (1$\times$10-4 to 8$\times$10-3M). A phosphate compensation point of phosphate transport was revealed with a 1$\times$10-6M solution of Na2H32PO4. The kinetic model that ion transport involves an exchange reaction of absorption and desorptin is prosposed as follows: where C represents an ionic-specific organic carrier in the membrane; M, Mo and Mi are the mineral ions, M-outside and M-inside; MC is a carrier-ion complex; and the K's represent rate constants. In this model, the Mi velocity, v, is given by: {{{{v= {dMi} over {dt}= {(K1K3Mo-K2K4Mi) Ct} over {(K2+K3)+K1Mo+K4Mi} }} where Ct is equal to C+MC, and t is time.

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Simulative Calculations of Food Waste Reduction Using Kineto-transport Models (동력학-전달 모델을 활용한 식품 폐기물 감량 해석)

  • Cho, Sun-joo;Kim, Tae-wook;Kwon, Sung-hyun;Cho, Daechul
    • Journal of Environmental Science International
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    • v.30 no.6
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    • pp.429-439
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    • 2021
  • Food waste is both an industrial and residential source of pollution, and there has been a great need for food waste reduction. As a preliminary step in this study, waste reduction is quantitatively modeled. This study presents two models based on kinetics: a simple kinetic model and a mass transport-shrinking model. In the simple kinetic model, the smaller is the reaction rate constant ratio k1, the lower the rate of conversion from the raw material to intermediate products. Accordingly, the total elapsed reaction time becomes shorter. In the mass transport-shrinking model, the smaller is the microbial decomposition resistance versus the liquid mass transfer resistance, the greater is the reduction rate of the radius of spherical waste particles. Results showed that the computed reduction of waste mass in the second model agreed reasonably with that obtained from a few experimantal trials of biodegradation, in which the microbial effect appeared to dominate. All calculations were performed using MATLAB 2020 on PC.

A Study on the Development of Low Reynolds Number k-$\varepsilon$ Turbulence Model (저레이놀즈수 k-$\varepsilon$난류모형 개선에 관한 연구)

  • 김명호;신종근;최영돈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.10
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    • pp.1940-1954
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    • 1992
  • Fine grid computations were attempted to analyze the turbulent flows in the near wall low Reynolds number region and the numerical analyses were incorporated by a finite-volume discretization with full find grid system and low Reynolds number k-.epsilon. model was employed in this region. For the improvement of low Reynolds number k-.epsilon. model, modification coefficient of eddy viscosity $f_{\mu}$ was derived as a function of turbulent Reynolds number $R_{+}$ and nondimensional length $y^{+}$ from the concept of two length scales of dissipation rate of turbulent kinetic energy. The modification coefficient $f_{\epsilon}$ in .epsilon. transport equation was also derived theoretically. In the turbulent kinetic energy equation, pressure diffusion term was added in order to consider low Reynolds number region effect. The main characteristics of this low Reynolds number k-.epsilon. model were founded as : (1) In high Reynolds number region, the present model has limiting behavior which approaches to the high Reynolds number model. (2) Present low Reynolds number k-.epsilon. model dose not need additional empirical constants for the transport equations of turbulent kinetic energy and dissipation of turbulent kinetic energy in order to consider wall effect. Present low Reynolds number turbulence model was tested in the pipe flow and obtained improved results in velocity profiles and Reynolds stress distributions compared with those from other k-.epsilon. models.s.s.

The Transport of Radionuclides Released From Nuclear Facilities and Nuclear Wastes in the Marine Environment at Oceanic Scales

  • Perianez, Raul
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.3
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    • pp.321-338
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    • 2022
  • The transport of radionuclides at oceanic scales can be assessed using a Lagrangian model. In this review an application of such a model to the Atlantic, Indian and Pacific oceans is described. The transport model, which is fed with water currents provided by global ocean circulation models, includes advection by three-dimensional currents, turbulent mixing, radioactive decay and adsorption/release of radionuclides between water and bed sediments. Adsorption/release processes are described by means of a dynamic model based upon kinetic transfer coefficients. A stochastic method is used to solve turbulent mixing, decay and water/sediment interactions. The main results of these oceanic radionuclide transport studies are summarized in this paper. Particularly, the potential leakage of 137Cs from dumped nuclear wastes in the north Atlantic region was studied. Furthermore, hypothetical accidents, similar in magnitude to the Fukushima accident, were simulated for nuclear power plants located around the Indian Ocean coastlines. Finally, the transport of radionuclides resulting from the release of stored water, which was used to cool reactors after the Fukushima accident, was analyzed in the Pacific Ocean.

Pharmacokinetic Modeling and Simulation of the Carrier-Mediated Hepatic Transport of Organic Anions (음이온계 약물의 간수송과정에 있어서 담체매개 수송의 약물동력학적 모델링 및 시뮬레이션)

  • 이준섭;강민희;김묘경;이명구;정석재;심창구;정연복
    • YAKHAK HOEJI
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    • v.47 no.2
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    • pp.110-119
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    • 2003
  • The purpose of the present study was to kinetically investigate the carrier-mediated uptake in the hepatic transport of organic anions, and to simulate the ″in vivo counter-transport″ phenomena, using kinetic model which was developed in this study. The condition that the mobility of carrier-ligand complex is greater than that of free carrier is not essential for the occurrence of ″counter-transport″ phenomenon. To examine the inhibitory effects on the initial uptake of a ligand by the liver, it is necessary to judge whether the true counter-transport mechanism (trans-stimulation) is working or not. The initial plasma disappearance curves of a organic anion were then kinetically analyzed based on a flow model, in which the ligand is eliminated only from the peripheral compartment (liver compartment). Moreover, ″in vive counter-transport″ phenomena were simulated based on the perfusion model which incorporated the carrier-mediated transport and the saturable intracellular binding. The ″in vivo counter-transport″ phenomena in the hepatic transport of a organic anion were well demonstrated by incorporating the carrier-mediated process. However, the ″in vivo counter-transport″ phenomena may be also explained by the enhancement of back diffusion due to the displacement of intracellular binding. In conclusion, one should be more cautious in interpreting data obtained from so-called ″in vivo counter-transport″ experiments.

Kinetic Model for Oxidation of Carbon Fiber/Glass Matrix Composites

  • Park, Chan;Park, Hee-Lack
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.254-259
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    • 1998
  • A kinetic model predicting the oxidation of carbon fiber reinforced glass matrix composites has been described. The weight loss of composites during oxidation implied that a gasification of carbon fiber takes place and the transport of reactants $(O_2)$ or product (CO or $CO_3$) in the glass matrix was partially the rate controlling step. The kinetic model in this study was based on the work of Sohn and Szekely which may be regarded as a generalization of numerous models in the gas-solid reaction system. A comparison of this model with experimental data is also presented.

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Synthesis and characterization of poly(vinyl-alcohol)-poly(β-cyclodextrin) copolymer membranes for aniline extraction

  • Oughlis-Hammache, F.;Skiba, M.;Hallouard, F.;Moulahcene, L.;Kebiche-Senhadji, O.;Benamor, M.;Lahiani-Skiba, M.
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.223-240
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    • 2016
  • In this study, poly(vinyl-alcohol) and water insoluble ${\beta}$-cyclodextrin polymer (${\beta}$-CDP) cross-linked with citric acid, have been used as macrocyclic carrier in the preparation of polymer inclusion membranes (PIMs) for aniline (as molecule model) extraction from aqueous media. The obtained membranes were firstly characterized by X-ray diffraction, Fourier transform infrared and water swelling test. The transport of aniline was studied in a two-compartment transport cell under various experimental conditions, such as carrier content in the membranes, stirring rate and initial aniline concentration. The kinetic study was performed and the kinetic parameters were calculated as rate constant (k), permeability coefficient (P) and flux (J). These first results demonstrated the utility of such polymeric membranes for environmental decontamination of toxic organic molecules like aniline. Predictive modeling of transport flux through these materials was then studied using design of experiments; the design chosen was a two level full factorial design $2^k$. An empirical correlation between aniline transport flux and independent variables (Poly ${\beta}$-CD membrane content, agitation speed and initial aniline concentration) was successfully obtained. Statistical analysis showed that initial aniline concentration of the solution was the most important parameter in the study domain. The model revealed the existence of a strong interaction between the Poly ${\beta}$-CD membrane content and the stirring speed of the source solution. The good agreement between the model and the experimental transport data confirms the model's validity.

The Structure of Axisymmeric Turbulent Diffusion Flame(II) (재순환 영역이 있는 축대칭 난류 확산화염의 구조 (II))

  • 이병무;신현동
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.1
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    • pp.70-77
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    • 1986
  • Turbulent mixing field with recirculating flow which is formed by injecting gaseous fuel on the main air stream is solved numerically by a finite difference method. The turbulence model for obtaining transport properties was k-.epsilon. model, which was obtained from turbulent kinetic energy and its dissipation rate. Considering the effects of streamline curvature, modified k-.epsilon model was used. Generally, Modified k-.epsilon. model makes better predictions than standard model, and from this result, it is recognized that standard model has deficiency when applied to turbulent recirculating flows, and that modified k-.epsilon. model takes into account of streamline curvature effects properly. Meanwhile, A more study will be necessary to find the reason why large differences between predicted and experimental turbulent kinetic energy exist.