• Title/Summary/Keyword: kerosene

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Elemental alteration of the surface of dental casting alloys induced by electro discharge machining (치과용 주조 합금의 방전가공에 따른 표면 성분 변화)

  • Jang, Yong-Chul;Lee, Myung-Kon
    • Journal of Technologic Dentistry
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    • v.31 no.1
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    • pp.55-61
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    • 2009
  • Passive fitting of meso-structure and super-structures is a predominant requirement for the longevity and clinical success of osseointegrated dental implants. However, precision and passive fitting has been unpredictable with conventional methods of casting as well as for corrective techniques. Alternative to conventional techniques, electro discharge machining(EDM) is an advanced method introduced to dental technology to improve the passive fitting of implant prosthesis. In this technique material is removed by melting and vaporization in electric sparks. Regarding the efficacy of EDM, the application of this technique induces severe surface morphological and elemental alterations due to the high temperatures developed during machining, which vary between $10,000{\sim}20,000^{\circ}C$. The aim of this study was to investigate the morphological and elemental alterations induced by EDM process of casting dental gold alloy and non-precious alloy used for the production of implant-supported prosthesis. A conventional clinical dental casting alloys were used for experimental specimens patterns, which were divided in three groups, high fineness gold alloy(Au 75%, HG group), low fineness gold alloy(Au 55%, LG group) and nonprecious metal alloy(Ni-Cr, NP group). The UCLA type plastic abutment patterns were invested with conventional investment material and were cast in a centrifugal casting machine. Castings were sandblasted with $50{\mu}m\;Al_2O_3$. One casting specimen of each group was polished by conventional finishing(HGCON, LGCON, NPCON) and one specimen of each group was subjected to EDM in a system using Cu electrodes, kerosene as dielectric fluid in 10 min for gold alloy and 20 min for Ni-Cr alloy(HGEDM. LGEDM, NOEDM). The surface morphology of all specimens was studied under an energy dispersive X-ray spectrometer (EDS). The quantitative results from EDS analysis are presented on the HGEDM and LGEDM specimens a significant increase in C and Cu concentrations was found after EDM finishing. The different result was documented for C on the NPEDM with a significant uptake of O after EDM finishing, whereas Al, Si showed a significant decrease in their concentrations. EDS analysis showed a serious uptake of C and Cu after the EDM procedure in the alloys studied. The C uptake after the EDM process is a common finding and it is attributed to the decomposition of the dielectric fluid in the plasma column, probably due to the development of extremely high temperatures. The Cu uptake is readily explained from the decomposition of Cu electrodes, something which is also a common finding after the EDM procedure. However, all the aforementioned mechanisms require further research. The clinical implication of these findings is related with the biological and corrosion resistance of surfaces prepared by the EDM process.

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Pulmonary Function and Its Influence Factors of Elementary School Children in Gangneung (강릉지역 초등학생들의 폐기능과 영향 요인 분석)

  • Yu, Seung-Do;Yoo, Si-Eun;Lee, Min-Jung;Choi, Wook-Hee;Kim, Dae-Seon;Lee, Chul-Ho;Park, Kyung-Hwa
    • Journal of Environmental Health Sciences
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    • v.34 no.1
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    • pp.20-26
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    • 2008
  • The objective of the study which utilised population based data was to determine the respiratory condition of elementary school children in Gangneung. From October 9th to December 14th, 2006, Pulmonary Function Tests (PFT) including Forced Vital Capacity (FVC) and Forced Expiratoy Volume in I Second $(FEV_1)$ were conducted on the target group of children using a spirometer. The prevalence of asthmatic symptoms was 29.8% among boys and 39.6% among girls. By using logistic regression, we found that family history of allergic rhinitis (OR=3.90, CI=1.05-14.51), experience of allergic conjunctivitis (OR=4.67, CI=1.54-14.16) and atopic dermatitis (OR=2.86, CI=1.17-7.05) significantly increased the asthmatic symptoms. Also, a family history of asthma and food allergy were associated with asthmatic symptoms. In relation to housing and environmental risk factors, residences under the ground (OR=3.59, CI=1.35-9.51) and big-size dolls (OR=2.71, CI=0.86-8.53) significantly increased the prevalence of asthmatic symptoms. For PFT, above four families, exposure of passive smoking and pets significantly reduced FVC in both groups (p<0.05). In girls, a big-size doll was significantly associated with decreased lung function (FVC and $FEV_1$). In boys, using bed significantly reduced $FEV_1$. Also, the risk of asthmatic symptoms was found to increase when the house has been built for 5 years or more, the house is close to a road $({\leq}100m)$, a gas/Kerosene heater or carpet is utilized within the house. However, their differences were not significant. It is concluded that genetic factor such as a family history of respiratory disease, allergic symptoms and housing risk factor are related to asthmatic symptoms. These results were worth noting because the findings will help address risk factors related respiratory symptoms especially in relation to housing and environment.

Biodegradation of Crude Oil and Petroleum Products by Crude Oil-degrading Microorganism (미생물을 이용한 원유 및 원유제품의 분해 특성)

  • 정선용;오경택;박귀환;이정일;이중기
    • KSBB Journal
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    • v.17 no.3
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    • pp.247-254
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    • 2002
  • Two kinds of crude oil-degrading microorganisms from soil and one kind from sea were isolated and named strain Al32, strain F722 and strain OM1, respectively. These microorganism were identified Acinetobacter sp., Pseudomonas aeruginosa and Acinetobacter calcoaceticus, respectively. The optimum cultivation temperature of Acinetobacter sp. A132 and P. aeruginosa F722 was $35^{\circ}C$ and optimum growth pH was 8 and 9, respectively. The growth was the highest at 2.0% (w/v) substrate concentration when crude oil was only carbon source. The growth of A. calcoaceticus OM1 isolated from sea was the highest at 3.0% (w/v) of crude oil. In inspection of crude oil degradability, strain Al32 showed 5.49 g/L.day with Eleuthera (OMAN), 2.0% (w/v). P. aeruginosa F722 showed 1.19 g/L g/L.day with L-Zakum (AFRICA). In case of kerosene $nC_9\simnC_{20}$ and diesel $nC_9\simnC_{28}$, A. calcoaceticus OM1 was degraded 95% and 75%, respectively, for 7 days culture, and P. aeruginosa F722 was 80% after 10 days.

A Survey on the Accidents of the Power Tillers in Korea (동력경운기 이용실태 조사분석(I) -농작업사고에 관하여-)

  • 홍종호;이채식;박호석;박판규;김경수;한성금
    • Journal of Biosystems Engineering
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    • v.5 no.2
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    • pp.58-66
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    • 1980
  • A survey was conducted to investigate the power tiller accidents. Eight provinces were covered for this study, and 278 power tiller owners were selected randomly by computer random generator. The results are summarized as follows : A. Frequency of accident. (1) Each power tiller had an accident 0.98 times a year and once every 361 hours of use. Higher frequency of accident was found during the miscellaneous operations including the preparation for farming operation, and there was one accident for every 92 hours of use. (2) The power tiller, which are more than six years old, met an accident 1.19 times a year , or one every 311 hours of use. This value was the highest one compared with any other group. (3) Kerosene engine power tillers met an accident 0.97 times a year, or one every 389 hours of use. It was one tie a year, or once every 329 hours of use for diesel engine power tillers. (4) Among diesel-engine power tillers, 10 horse-power group showed a higher frequency tillers. B. Cause of accident (1) The accidents of power tiller were mainly of sefety , which occurred due to the lack of attention during the operation and 47.4% of the total accidents. The next was of accidental, which represented 26.3% of the total accidents. (2) High percentage of safety accidents occurred during the preparation for farming operation including adjustment. Most of the accidental accidents occurred during the transportation. (3) Lower frequency of accident was found in the power tiller group which were operated by the 21-40 years old operator in comparison with that of the power tiller which was operated by other age group. Power tillers which were operated by high school graduates experienced less accidents compared to other education levels. C. Damage by accident (1) Eighty seven pescents of the total accidents caused damage to the power tiller operator , and 13 % of the total accidents caused property damage only. (2) With regard to the damage to the power tiller operator, 73.8% of the total accidents caused light injury but 26.3% caused heavy injury. (3) Accidents which occurred during machine preparation , and farming operations caused minor injury to the operator, but the accidents during transportation caused heavy injury which cost more than 15 days for recovery. (4) Among the 39 accidents , which caused property damage 18 accidents were from the transportation . Among the total property damage accidents 53.8% were light one which cost only less than 1,000 won. (5) The property damage from each accident cost 1,017 won, on the average, with regard to the kinds of operation, the highest property damage occurred during transportation work, with the value of 2, 965won.

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A Study on the Possibility of Using of Spent RHDS Catalyst as a SCR Catalyst wash-coated on the metal corrugated substrate (폐 RHDS 촉매재생 후 메탈 코로게이트 지지체상에서 워시코팅에 의한 NOx 저감 SCR 촉매에 관한 연구)

  • Na, Woo-jin;Cha, Eunji;Kang, Dae-hwan;Go, Young-ju;Cho, Ye-ji;Choi, Eun-young;Park, Hea-Kyung
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.4
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    • pp.723-732
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    • 2020
  • The spent RHDS (Residue HydroDeSulfurization) catalyst is deactivated mainly by deposition of various contaminants such as coke, sulfur and vanadium on the surface of catalyst. To eliminate those contaminants, the following remanufacturing process was conducted. The first, heavy oil on the surface of the spent RHDS catalyst was removed by kerosene and dehydrated. The second, the high temperature incineration was carried out to eliminate coke and sulfur components deposited on the surface of spent RHDS catalyst. The third, the excessive quantity of Vanadium deposited on the surface of catalyst was removed by leaching process as follows: ultrasonic agitation was carried out at 50℃, for 10 seconds with 0.5% and 1% oxalic acid solution. The purpose of this process is to find out regenerated RHDS catalyst can be used as SCR catalyst for NOx reduction by controlling the vanadium residual content of the regenerated RHDS catalyst through leaching process. The composition of regenerated RHDS catalyst was analyzed by XRF and the NOx reduction efficiency was also measured by continuous catalytic fixed bed reactor. As the result, regenerated catalyst, with 0.5% oxalic acid, ultrasonic agitation in 10 seconds, showed the most stable NOx reduction efficiency. Also, in comparison with commercial SCR catalyst, the NOx reduction performance of regenerated catalyst was similar to that of commercial SCR catalyst at the temperature 375℃ and higher whereas was lower than commercial SCR catalyst at the temperature range between 200~250℃. Therefore, it was confirmed that the regenerated catalyst as powder form wash coated on the surface of metal corrugated substrate can be used for commercial SCR catalyst.

Optimization of Medium Components for the Production of Crude Biosurfactant by Bacillus subtilis JK-1 (Bacillus subtilis JK-1의 생물계면활성도를 위한 최적 배지 조성)

  • Joo, Myeong-Hoon;Kim, Ji-Yeon
    • Journal of Applied Biological Chemistry
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    • v.54 no.1
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    • pp.7-14
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    • 2011
  • Bacillus subtilis JK-1 showed degradation activity against crude oil, gasoline, kerosene, and light oil, and this strain was used as a crude biosurfactant producing microorganism in this study. To optimize the culture medium for production of crude biosurfactant, the influences of various carbon, nitrogen and mineral sources were assessed. The highest biosurfactant production by B. subtilis JK-1 was observed after 96 h cultivation, containing 1.0% (w/v) soluble starch as a carbon source and 0.5% (w/v) skim milk as a nitrogen source, and carbon to nitrogen concentraion (C/N) ratio was 2.0. For the biosurfactant production 0.1% (w/v) of $KNO_3$ was the most effective mineral source. Comparison of biosurfactant production indicates that B. subtilis JK-1 produces more biosurfactant in the optimum medium established in this study than LB and TSB. Under the optimum medium, the surface tension of culture broth of B. subtilis JK-1 was decreased from 47.3 dyne/cm to 24.0 dyne/cm after cultivation of 48 h.

An Evaluation of Energy Quality for Distributed Powersystem (분산형 발전설비 병열운전 에너지 품질평가)

  • Hur, Kwang-Beom;Park, Jung-Keuk;Yoon, Gi-Gab;Rhim, Sang-Kyu;Choi, In-Kyu
    • Journal of Energy Engineering
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    • v.19 no.1
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    • pp.8-15
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    • 2010
  • As environmental friendly energy system, distributed micro gasturbine is focused on new energy source for overcoming brand new construction area of power generation. This distributed micro gasturbine system has the powerful characteristics as belows; 1) environmental friendly features NOx < 9 ppm, noise < 65 db 2) various fuel flexbility which is used such as natural gas, diesel, low calory new & renewable fuel, kerosene. 3) high specific output power based on small area and is avilable for very easy and compact installation. There are many new installation sites in USA and Japan from 1998. On the other hand the exhisting large power system was constructued by the sea side, this compact power system is now installed by enduser in downtown area and supplying combined heat & power, has the various apllication on-site power generation. In recently, there is the very important issue for new & reliablbe energy development and spreading out. This paper represent as belows for important system characteristics; 1) grid connection modeling 2) system operation characteristics 3) on-site operation result and evaluation output of power quality analysis.

A Review on Conception of Policy for Production of Imported Tropical and Temperate Fresh Fruits Using Hot Waste Water from Power Plant (발전소 온배수를 활용한 온·열대 신선과일 수입대체 정책 방안)

  • Kim, Yean-Jung;Park, Jiyun;Kim, Bae-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.10
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    • pp.48-53
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    • 2017
  • One of the policies of the Ministry of Agriculture, Forestry and Livestock Food and Livestock aims to export $10 billion worth of products. Although it was not easy to achieve the export goal of $ 6.5 billion in 2016, the policy should be pursued continuously. Accordingly, a facility modernization project and high-tech greenhouse project are being implemented to facilitate exports. Moreover, it is possible to consider substitution of imports in the policy shift. Imports of temperate and tropical fresh fruits totaled 1.2 trillion won in 2016. Accordingly, identification of alternatives to tropical and temperate fresh fruit imports will enable farm income to increase and the fresh fruit industry to grow. The major obstacle to tropical fruit production in Korea is high heating costs. However, Jeju Island apple mango farmers found that using non-taxable kerosene and hot water from power plants could reduce heating costs by 42.5%. Indeed, using hot wastewater can reduce heating costs by more than 40%. To improve competition with imported fruits, farmers can change their heating systems using financial support plans (e.g., 20% government subsidies, 20% loans, 30% subsidies from local governments). The income effect and import substitution effect of fruit tree farmers should be carefully analyzed in the future and the study will be closed to discuss the policy direction.

Solvent Extraction of Platinum Group Metals from the leach Liquor of Spent Automotive Catalyst (자동차(自動車) 폐촉매(廢觸媒)의 침출액(浸出液)으로부터 백금족(白金族) 금속(金屬)의 용매추출(溶媒抽出))

  • Kim, Mi-Ae;Lee, Jae-Chun;Kim, Chi-Kwon;Kim, Min-Seuk;Kim, Byung-Su;Yoo, Kyoung-Keun
    • Resources Recycling
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    • v.15 no.5 s.73
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    • pp.3-10
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    • 2006
  • The solvent extraction for the separation of platinum group metals from the leach liquor of spent automotive catalysts has been studied. Tri-n-butyl phosphate (TBP), tri-n-octylamine (TOA) and di-n-hexyl sulfide (DHS) were used as extractants and kerosene as a diluent. The extraction behavior of platinum, palladium and rhodium has been investigated as functions of different kinds of extractants and their concentrations. In addition, the extraction behavior of the major metal impurities such as cerium, lead, iron, magnesium and aluminum has been investigated. Platinum and palladium were extracted with TBP. And platinum, palladium and rhodium were extracted with TOA. Platinum was co-extracted with palladium into the organic phase by solvent extraction using SFI-6 of DHS extractant, but only palladium was selectively extracted with SFI-6R. The selective extraction of palladium with SFI-6R was found better than that with SFI-6, but the kinetics of extraction with SFI-6R was found poor in comparison to SFI-6. The metal impurities extracted simultaneously during the extraction of platinum group metals should be removed in scrubbing and stripping processes. A suitable process has been proposed for the separation of platinum group metals from the leach liquor of spent automotive catalysts. Initially palladium was extracted with SFI-6R, followed by the separation of platinum with TBP or TOA leaving rhodium in the raffinate.

Solvent Extraction of Light (Pr, Nd) and Medium (Tb, Dy) Rare Earth Elements with PC88A of Rare Earth Chloride Solution from Waste Permanent Magnet (폐 영구자석으로부터 회수한 염화희토류용액에서 PC88A를 이용한 경희토류(Pr, Nd)/중희토류(Tb, Dy) 용매추출)

  • Jeon, Su-Byung;Son, InJoon;Lim, Byung-Chul;Kim, Jeong-Mo;Kim, Yeon-Jin;Ha, Tae-Gyu;Yoon, Ho-Sung;Kim, Chul-Joo;Chung, Kyeong-Woo
    • Resources Recycling
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    • v.27 no.3
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    • pp.8-15
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    • 2018
  • Solvent extraction behavior of light rare earth elements (Pr, Nd) and medium rare erath elements (Tb, Dy) in the HCl-PC88A-kerosene extraction system was investigated in order to separate high-purity light rare earths (Pr, Nd) and medium rare earths (Tb, Dy) in the mixed rare earth chloride solution. In the batch test step, it was confirmed that the separation efficiency was good when the extractant concentration (PC88A) was 0.5 M, the equilibrium pH after extraction was 0.8 to 1.0 (initial pH 1.3 of the feed), the concentrations of hydrochloric acid in scrubbing solution was set as 0.1 M, the concentrations of hydrochloric acid in stripping solution was set as 2.0 M or more. Based on the experimental data obtained from the batch test, the mixer-settler was composed as follows; 4 stages of extraction, 8 stages of scrubbing, 4 stages of stripping, and 3 stages of pickling organic solution. The Mixer-settler was operated for 180 hours, and the operating conditions were continuously adjusted to obtain the high-purity light/medium rare earths. Finally, the purity of light (Pr, Nd) and medium rare earth elements (Tb, Dy) was reached as 3 N class.