• Journal of the Mineralogical Society of Korea
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• v.23 no.4
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• pp.347-356
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• 2010

Bauxite is a main raw material for the production of alumina and aluminum hydroxide in the processing plant of KC company. It is a NORM (Naturally Occurring Radioactive Materials), and its waste, red mud, is a TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials). The purpose of the geochemical and mineralogical investigations of the bedrock and soils in and around the plant, a large NORM source, was to provide basic data for measuring the radiation dose and protecting from radioactive hazards. Soils were mixtures of minerals derived from the country rock (quartz, feldspar, mica, kaolin, gibbsite, and sepiolite) and bauxite (hematite, boehmite, and calcite) of open-air storage. Average U and Th contents of the soil samples were 4.7 ppm and 23 ppm, respectively, indicating somewhat Th anomaly. The average concentrations of radionuclides are $^{40}K$ 100~1,433 Bq/kg, $^{226}Ra$ anomaly in the red mud open-air storage. Soil external hazard indices range from 0.10 to 1.66 with an average of 0.63. Although most of the indices are below 1.0 that is a regulation value, those of 4 samples of total 41 soil samples exceed 1.0, requiring further detailed investigation.

• Journal of Microbiology and Biotechnology
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• v.8 no.6
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• pp.606-612
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• 1998

A microbial flocculant-producing gram-positive bacterium, strain TE11, was isolated from soil samples, and was identified as Bacillus subtilis by using the Midi system, the Biolog system, 16S rDNA sequence analysis, and some physiological and morphological characteristics. The maximum flocculant capsular biopolymer of TE11 strain (BCP, 4.9mg/ml) was obtained when it was grown in GA broth medium containing 3% glutamic acid, 2% glycerol, 0.5% citric acid, 0.5% $NH_4$Cl, 0.05% $MgSO_4.7H_2O,\; 0.05%\;K_2HPO_4\;,\; and\; 0.004%\; FeC1_3. 6H_2O,\; pH 7.2,\; at\; 30^{\circ}C$ for 70 h with shaking. When glycerol was used as an additional carbon source in the GA medium, TE11 produced only flocculant BCP without any by-product. The flocculant (BCP) was found to aggregate suspended kaolin and activated charcoal powder without cations, and its flocculating activity was significantly enhanced by the addition of bivalent cations such as $Ca^{2＋}.Zn^{2},\; and\; Mn^{2＋}$. The flocculation activity by addition of $Ca^{2+}$ was high in an acidic pH 4.0. In the case of $Zn^{2＋}$, high flocculating activity remained without significant loss in the broad range of pH 4.0 to 9.0.

• Journal of Industrial Technology
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• v.26 no.B
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• pp.93-99
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• 2006

Centrifuge model experiments were performed to investigate the confining effects of the sheet piles, installed to the sides of soft clay ground treated with sand compaction piles, on the bearing capacity and concentration ratio of composite ground. For the given g-level in the centrifuge model tests, replacement ratio of SCP and the width of surcharge loads on the surface of ground with SCP, the confining effects of installing the sheet piles on the edges of SCP ground on the bearing capacity, change of stress concentration ratio and failure mechanism were investigated. Kaolin, one of typical clay mineral, and Jumunjin standard sand were used as a soft clay ground and sand compaction pile irrespectively. As results of experiments, lateral confining effect by inserting the model sheet piles fixed to the loading plate was observed. For the strip surcharge loading condition, the yielding stress intensity in the form of the strip surcharge loads tends to increase with increasing the embedded depth of sheet piles. The stress concentration ratio was found not to be influenced consistently with the embedded depth of sheet piles whereas the effect of stress intensity on stress concentration ratio shows the general trend that values of stress concentration ratio are relatively high at the initial stage of loading and tend to decrease and converge to the certain values. For the failure mechanism in the case of reinforced with sheet piles, displacement behavior related to the punching failure, settlement right beneath the loading plate occurred since the soil was confined with sheet piles, was observed.

• Journal of the Mineralogical Society of Korea
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• v.13 no.3
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• pp.147-163
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• 2000

The mineralogy and chemical composition of reddish to brownish yellow residual soils, so called "Hwangto" have been examined according to representative host rocks. The result of the study indicates that Hwangto consists of 40-80% clay minerals and various minerals such as quartz, feldspar, hornblende, goethite, and gibbsite. Clay minerals include kaolinite, halloysite, illite, hydroxy interlayered vermiculite (HIV), mica/vermiculite interstratifield mineral and chlorite. The mineralogical constituents and contents of Hwangto were different depending on the types of host rocks. Moreover, the Jurassic granitic rocks contain relatively more kaolin minerals, whereas the Cretaceous granitic rocks contain more HIV and illite. In addition, reddish Hwangto contains relatively more kaolinite and HIV, and yellowish Hwangto contains more illite and halloysite. It is suggested that feldspars and micas of host rocks were chemically weathered into illite, halloysite, illite/vermiculite interstratified minerals, and HIV, and finally into kaolinite. Compared with their host rocks, the major chemical compositions of Hwangto tend to contain more $Al_2O_3,\;Fe_2O_3,\;H_2O$ in amount and less Ca, Mg, and Na. Hwangto contains relatively high amount of trace elements, P, S, Zr, Sr, Ba, Rb, and Ce including considerable amount of Li, V, Cr, Zn, Co, Ni, Cu, Y, Nb, La, Nd, Pb, Th in excess of 10 ppm. Relatively high amount of most trace elements were detected in the Hwangto. The major and minor chemical compositions of the Hwangto were different depending on the types of host rocks. However, their difference was in the similar range compared with the compositions of host rocks.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.4
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• pp.255-264
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• 2021

Asian dust (Hwangsa) deposited on the surface of the Korean Peninsula is difficult to recognize their existence in mountainous terrain undergoing active erosion and weathering. This study examined Asian dust sediments mixed in soils by analysing clay mineralogy, mineral composition, and microtextures of fine silt (< 20 ㎛) in the alkali feldspar granite area of Seoraksan. The fine silt was composed of detrital particles derived from bedrocks, Asian dust sediments, and their weathering products. Clay minerals of 2:1 structural type, chlorite, amphibole, epidote, and Ca-bearing plagioclase were identified as eolian mineral particles. During the weathering of the bedrock composed of quartz and alkali feldspars, albite was partially weathered to produce small amounts of gibbsite and kaolin minerals. Hydroxy-Al interlayered clay minerals were formed by the exchange and fixation of polynuclear Al cationic species into the interlayers of expandable 2:1 clay minerals dominated by illite-smectite series clay minerals. Contribution of Asian dust to the fine silt of soils was estimated around 70% on the basis of total contents of 2:1 phyllosilicates.

• Korean Journal of Soil Science and Fertilizer
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• v.41 no.4
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• pp.239-246
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• 2008

This research tried to find out the optimum fabrication method of calcined clay granules comprising zeolite. Kaolin clay and natural zeolite powder were used as raw materials of calcined clay, and silica stone powder was used for controlling the porosity of the granules. The granulation was performed with two kinds of granulators: a pan granulator and a high-shear mixer granulator. Various granules were fabricated by the mixing ratios and the rotation speeds of the granulators, and were heated from 400 to $700^{\circ}C$ at $100^{\circ}C$ interval. The crushing strength, pore size distribution, and CEC of the granules were measured. The evaluation method for the resistance of granules to human treading was created and the tests were conducted at dry and wet conditions. The resistance and crushing strength improved in proportion to the rotation speed of the granulator and the heating temperature, but the CEC decreased. The pellet made by the pan granulator did not have the strength against treading upon heating to below $700^{\circ}C$, but the pellet made by the high-shear mixer granulator endured the treading test upon heating to over $500^{\circ}C$

• Journal of the Mineralogical Society of Korea
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• v.30 no.4
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• pp.179-186
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• 2017

This study investigated the mineralogical characteristics of lime mortars used in pointing of Namhansanseon Yeojang from Joseon dynasty. Polarization microscopy revealed quartz, feldspar, mica, pyroxene and opaque minerals in the lime mortars. XRD analysis also confirmed clay minerals chlorite and kaolin. As a result of particle size analysis of lime mortars, the particle size distribution was wide and size was not uniform. 60% of samples were corresponded to the sand area. The chemical components detected from XRF analysis, 8.71-11.18 % of Ca as the main component of lime and $SiO_2$, $Al_2O_3$, and $Fe_2O_3$ in soil minerals were main components. The lime mortars showed an endothermic peak due to decarbonization reaction of $CaCO_3$ at $750^{\circ}C$ and weight reduction rate of 10%. The microstructures were agglomerated amorphous and observed rhombohedral calcite crystals by scanning electron microscope. It is considered that the pointing of Yeojang is a mortar mixed with lime and soil. In addition the Hanbongseong Yeojang was constructed using the same materials and construction technique because the minerals composition is not different according to the Yeojang location and use.

• Economic and Environmental Geology
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• v.44 no.1
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• pp.37-48
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• 2011

Some industrial minerals used in domestic industries such as monazite, apatite, bauxite, and ilmenite belong to NORM (Naturally Occurring Radioactive Materials) because they show a high radioactivity. Products, semi-products, wastes, and by-products which show higher radioactivity than NORM belong to TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials). Apatite used for manufacturing phosphate fertilizer in Namhae Chemical company belongs to NORM, and its by-product, phospo-gypsum, belongs to TENORM. A geological investigation is needed for the future environmental impact assessment of the Namhae Chemical company's site. According to survey results of the Namhae Chemical company's site, soil mineral composition indicated the mixture of minerals derived from the country rock (quartz, feldspar, mica, $l4{\AA}$ mineral, kaolin and amphibole) and minerals from the gypsum open-air storage yard (gypsum and apatite). Soil samples showed average content of U 4.6 ppm and Th 10 ppm, which are similar to average crustal abundances. They also show average contents of $^{40}K$ 191-1,166 Bq/kg, $^{226}Ra$ 15.6-710 Bq/kg, and $^{232}Th$ 17.4-72.7 Bq/kg, which indicate moderate levels of radio nuclide. But $^{226}Ra$ anomaly in the gypsum open storage yard is clearly confirmed and $^{232}Th$ anomaly is also confirmed in the east road side of the factory and nearby mountain areas. Soil external hazard indices ranged 0.24-2.01 with the average 0.54. Although most external hazard indices were lower than 1, which means radiation hazard index to be negligible, 5 samples out of total 40 samples showed higher values than 1, and further detailed investigation is needed.

• Journal of Conservation Science
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• v.32 no.3
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• pp.403-416
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• 2016

Mineral composition and content of 22 Korean Dancheong pigment products were obtained by Rietveld quantitative analysis. Jubosa, Hwang, Seokrok, Seokcheong and Hobun consist of pure cinnabar, orpiment, malachite, azurite and calcite (or aragonite), respectively. Whereas Seokganju, Hwangto, Noerok, Lapis lazuli, Baekto and Cockie hobun mainly consist of hematite, goethite, celadonite, lazurite, kaolin mineral and portlandite, respectively. And they all consist of soil minerals (quartz, feldspar, sericite and vermiculite) and filler minerals in the industry field (calcite, gypsum and anhydrite) at a different content. Quantitative XRD proved more useful method to determined exact mineral composition and content than chemical or microscopical data. If this method utilize for specification of natural pigment product, it is considered to be applicable in restoration technology and conservation science field.