• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.4
• /
• pp.310-315
• /
• 2012

A simple drying process was developed for the preparation of a Pt/Nafion self-humidifying membrane to be used for a proton-exchange membrane fuel cell (PEMFC). Platinum (II) bis (acetylacetonate), $Pt(acac)_2$ was sublimed, penetrated into the surface of a Nafion film and then reduced to Pt nanoparticles simultaneously without any support of a reducing agent in a glass reactor at $180^{\circ}C$ for 15 min. The process was carried out in $N_2$ atmosphere to prevent the oxidation of Pt nanoparticles at high temperature. The morphology and distribution of the Pt nanoparticles were observed by transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS), and we found that the average Pt particle size was ca. 3.7 nm, the penetration depth was ca. $17{\mu}m$. Almost all Pt nanoparticles were formed just beneath the surface and the number density decreased rapidly as the penetration depth increased. To estimate water absorption characteristics of the Nafion membranes, water uptake at an isothermal condition was measured by dynamic vapor sorption (DVS), and it was found that water uptake of the Pt/Nafion membrane was higher than that of the neat Nafion membrane.

• Elastomers and Composites
• /
• v.34 no.1
• /
• pp.3-10
• /
• 1999

Kinetics of solution photopolymerization of acrylonitrile(AN) with sensitizer, such as $NaSCN,\;KSCN,\;Ba(SCN)_2,\;NH_4SCN,\;ZnCl_2$ and $Na_2SeO_3$, were studied using UV crosslinker at various monomer concentrations($1.8{\sim}7.58mo1/1$), sensitizer concentrations($10{\sim}60%$), reaction temperature($10{\sim}70^{\circ}C$), energy intensities($1,000{\sim}9,900{\mu}J/cm^2$) at isothermal condition under nitrogen atmosphere. Under the irradiation of high pressure mercury lamp(${\lambda}=365nm$). High conversion and uniform molecular weight were obtained compare to thermal polymerization at reaction temperature of $50^{\circ}C$, reaction time of 3hr and 50% NaSCN without any initiator. Their kinetic model was as follows : $R_p=0.0142[M]^{0.82}[I]^{0.49}[S]^{0.52}$ exp(-1.33/RT).

• Applied Chemistry for Engineering
• /
• v.23 no.2
• /
• pp.169-175
• /
• 2012

In the study, the effects of $130{\sim}150^{\circ}C$ annealing condition and 1~10 wt% isopropylphenyl diphenyl phosphate (IPPP) on crystallization behavior and flame retardancy of a full name (PLA) film were determined. The crystallization kinetics of PLA films with adding 1, 5, and 10 wt% IPPP at $140^{\circ}C$ were higher than those at 130 and $150^{\circ}C$. The average crystallinity and crystallite size of PLA film with 1 wt% IPPP were 21.3% and 24.8 nm, respectively. With an increasing IPPP content, the crystallinity of PLA film increased and the crystallite size decreased. The burning rate lowered with an increasing IPPP content as well.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.14 no.1
• /
• pp.156-164
• /
• 2010

A total of 6 stepwise constructions were made for building the floating mass concrete foundation. The optimal curing strategies and specialized construction guidelines were adoptively extracted from the 1.5m cube mock-up test prior to the main concrete work. Two different thermal crack index(TCI) calculations from current construction manual exhibit relatively low values as comparing the measured temperature data. This implies that the hydration-induced cracking could be developed in parts of concrete mass. However, the controversial phenomenons in reality were observed. No significant surface cracks are detected at the successive construction stages. Thereby, this paper raises the question regarding on the existence of characteristic length with varying size and shape of a target specimen which are missing in the current construction manual. The isothermal core area and high thermal gradient area in the edge volume should be identified and be introduced to TCI calculation for the purpose of an accuracy.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.31 no.2
• /
• pp.84-88
• /
• 2021

The change of the photoluminescence properties of La2O3-CaF2-Al2O3-SiO2 glass-ceramics doped with rare earth material, that is used as laser and optical sensors, was analyzed according to heat treatment temperature. The heat treatment conditions for fabricating glass-ceramics were obtained through non-isothermal thermal analysis, and X-ray diffraction analysis was performed to determine the degree of crystal growth and kinds of crystal phases generated according to the heat treatment temperature. Using Scherrer's equation, it was predicted that crystals with a size of 25~40 nm would be generated inside the glass-ceramics. Photoluminescence (PL) analysis showed that the specimens heat-treated at 660℃ to 670℃ for 1 hour had the highest PL intensity. Also, from the CIE color coordinate analysis, all glass-ceramics specimens emitted red-orange light regardless of the heat treatment condition.

• Korean Chemical Engineering Research
• /
• v.59 no.1
• /
• pp.77-84
• /
• 2021

To control hot spot in a plug flow reactor (PFR) is important for the yield and purity of products and safety. In this paper, coolant temperature is set as a state variable, and radial distributions of heat and mass are considered to model the PFR more realistic than without considering radial distributions. The model consists of three state variables, reactant concentration, reactant temperature, and the coolant temperature. The flow rate of the isothermal coolant is a manipulated variable. This paper shows that the controller considering the radial distributions of heat and mass is more effective than the controller without them. Assuming that u3,0 is 0.7, the suggested control equation was robust when St is bigger than 1.3, and Ac/A is smaller than 2.0. Under this condition, the hot spot temperature changed within the relative error of one percent when the temperature of input altered within the range of five percent.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.26 no.2
• /
• pp.1-11
• /
• 2022

The heat transfer coefficient on the wall, which is used as a boundary condition in the thermal analysis of general contract-divergent supersonic nozzles, affects the thermal analysis accuracy of the entire nozzle. Accordingly, many methods of deriving a heat transfer coefficient have been proposed. In this study, the accuracy of each method was compared. For this purpose, the heat transfer coefficients were calculated through theoretical-based analogy methods, semi-empirical equations, and CFD simulations for the previously performed heat transfer experiment with an isothermal wall and compared with the experimental results. The results show that the Prandtl-Taylor analogy methods and the CFD results with the k-ω SST turbulence model were in good agreement with the experimental results. Furthermore, the Modified Bartz empirical formula showed an overall over-prediction tendency.

• Journal of the Korean Wood Science and Technology
• /
• v.36 no.6
• /
• pp.138-146
• /
• 2008

The chemical compositions, cell wall biopolymers and non-isothermal behavior of the stem biomass of Nicotiana Tabacum originated from tobacco industry were investigated in depth. On a weight basis, the contents of total ash and total sugar are 19.1% and 20.7% respectively. Lignin content was around 3% of tobacco stem biomass while pectin was over 7%. The holo-cellulose content in cell wall biopolymer was around 13% and the $\alpha$-cellulose constitutes 60% of the total holo-cellulose. The thermal behavior of stem biomass showed different patterns depending on either inert (nitrogen) or oxidizing (air) atmospheric condition. In the air atmosphere, the rapid thermal decompositions at around $473^{\circ}C$ and $581^{\circ}C$ were recorded as the peaks in DTG curve, while the peaks were not shown in the nitrogen atmosphere condition. The thermal analysis of the freeze dried soluble obtained from hot water extraction of tobacco stem biomass showed that the rapid thermal decomposition at around $581^{\circ}C$ in the air atmosphere was due to the residual char originated from the soluble fraction. The distinct difference in thermal decomposition between hemicellulose and cellulose were easily found in the DTG curve obtained in the nitrogen atmosphere.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.16 no.4
• /
• pp.341-348
• /
• 1983

The Relationship between the distribution of the fishing grounds of anchovy and the oceanographic conditions in the Korean Waters are investigated by using the data of the catch of anchovy by the gill net fishery (Fisheries Research and Development Agency, 1969-1982) and the oceanographic observation data (Fisheries Research and Development Agency, 1979). The main fishing ground of anchovy by the gill net fishery was five fishing areas located in the adjacent seas of Sockcho, Kuryong-po, Kijang, Keoje island and Chungmu, the area of which occupies no more than $20\%$ of all fishing grounds, and it appeared that about $80\%$ of mean catches of fourteen years was concentrated in this area. The main fishing periods were from April to June and October to November. The coefficient of variation of the catch for the main fishing ground were from 0.3 to 0.6 and the condition of all fishing ground was generally stable. The mean CPUE was 81.2 kg/set at the main fishing ground. The annual mean catch of anchovy by the gill net was the smallest in February and the largest in May through a year. It was found that the fluctuation is related to the expansion and reduction of the isothermal line of $10^{\circ}C$.

• Korean Chemical Engineering Research
• /
• v.50 no.1
• /
• pp.149-154
• /
• 2012

The adsorption and desorption behavior of biofilter-medium was investigated on the performance of an adsorption column. Continuous flow-isothermal adsorption experiments were performed to treat waste air containing such a VOC as ethanol under the same condition of > 90% relative humidity as the condition of the feed to a biofilter process. In case of feeding waste air containing ethanol of 1,000 ppmv (or 2,050 mg ethanol/$m^3$) to the adsorption system at the rate of 2 L/min, the onsets of its breakthrough and reaching the state of dynamic equilibrium at the exit had been delayed 10 and 3 times, respectively, later than those at the 1st stage sampling port. Moreover, in case of 2,000 ppmv (or 4,100 mg ethanol/$m^3$), they had been delayed 9 and 3 times, respectively. Thus, regardless of feeding concentration, the ratios of delaying period were observed to be quite consistent each other at the exit of the adsorption column. With regard to the period of desorption, the ratios of delaying period were consistent each other to be 1.5 for both cases. In addition, the effect of microbial activity and sterilization-process was studied on adsorption equilibrium. The ethanol concentration in the vapor phase of vials packed with sterilized granular activated carbon (GAC) was quite consistent to that with unsterilized GAC. However, the ethanol concentrations in the vapor phase of vials packed with unsterilized compost and the unsterilized mixture of GAC and compost were higher than those with sterilized compost and the sterilized mixture of GAC and compost, respectively.