• Title/Summary/Keyword: isopropyl alcohol

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Racemization of Optical Active tris-Oxalatocobaltate (III) Ion in Mixed Solvants (혼합용매내에서 광학활성인 tris-Oxalatocobaltate (III) ion의 라세미화에 관한 연구)

  • Dong Jin Lee;Doh Myung Ki
    • Journal of the Korean Chemical Society
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    • v.30 no.4
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    • pp.377-382
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    • 1986
  • Racemic tris-oxalatocobaltate (III) complex ions were optically resolved by an optical active complex, ${\Delta}$-tris-ethylenediamine cobalt (III), and then racemization of ${\bigwedge}-[Co(ox)_3]^{3-}$ obtained was investigated in various mixed solvent such as water-organic solvent (organic solvents=ethanol, iso-propyl alcohol, acetone, and dioxane). The rate of racemization was increased with following order; water < ethanol < acetone < isopropyl alcohol < dioxane; which is the same order for polarizability of organic solvent added. Considering ${\Delta}H^{\neq},\;{\Delta}S^{\neq}$ and above facts for the racemization of ${\bigwedge}-[Co(ox)_3]^{3-}$, it seems to be twist mechanism of plausible mechanisms.

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Occurrence of ELISA Inhibitors, and Inhibitor-free Determination of Cyclobutane Pyrimidine Dimers in Japanese Cypress Leaves

  • Hashimoto, Tohru;Nakagawa, Noriko;Okano, Michiaki;Nikaido, Osamu
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.448-450
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    • 2002
  • DNA samples extracted from Japanese cypress leaf tissues contain isopropyl alcohol-precipitable, high molecular weight compounds, which interfere ELISA for cyclobutane pyrimidine dimers (CPD). Removal of the compounds is achieved by DEAE ion-exchange column chromatography and improves the ELISA responses of the DNA. When extracting DNA repeatedly from the same leaf tissues, the DNA samples show CPD responses which increase with the order in sequential extraction, and hence for a reliable detennination of DNA lesion a thorough extraction of DNA is required. Clearing these two problems it was demonstrated that CPD level was slightly higher in the leaves of trees growing under full sunlight than in those growing under UBV -cut sunlight.

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SWCNT/Nafion Composite Development for Improvement of Mechanical Properties of IPMC (IPMC의 기계적 특성향상을 위한 SWCNT/Nafion 복합체 개발)

  • Kwon, Hui-June;Lee, Heon-Sang;Lee, Jung-Hwa;Jun, Chan-Bong;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.1
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    • pp.47-53
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    • 2011
  • From recent research, it has revealed that Electroacitve polymer(EAP) has a physical limitation. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. In this paper, we suggest the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. Using mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we disperse Single-walled carbon nanotubes(SWCNT). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. In the result, we fabricated a disperse SWCNT/Nafion composite uniformly.

Influence of Molding Conditions on Environmental Stress Cracking Resistance of Injection Molded Part (사출성형품의 공정 조건에 따른 내환경응력균열 특성에 관한 연구)

  • Choi, D.S.;Kim, H.S.
    • Transactions of Materials Processing
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    • v.20 no.2
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    • pp.173-178
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    • 2011
  • Environmental Stress Cracking(ESC) is one of the most common causes of unexpected brittle failure of thermoplastic polymers. The exposure of polymers to liquid chemicals tends to accelerate the crazing process, initiating crazes at stresses that are much lower than the stress causing crazing in air. In this study, ESC of acrylonitirile butadiene styrene(ABS) was investigated as a function of the molding conditions such as injection velocity, packing pressure, and melt temperature. A constant strain was applied to the injection molded specimens through a 1.26% strain jig and a mixture of toluene and isopropyl alcohol was used as the liquid chemical. In order to examine the effects of the molding conditions on ESC, an experimental design method was adopted and it was found that the injection velocity was the dominant factor. In addition, predictions from numerical analyses were compared with the experimental results. It was found that the residual stress in the injection molded part was associated with the environmental stress cracking resistance (ESCR).

Selective Etching of Silicon in TMAH:IPA:Pyrazine Solutions (TMAH:IPA:Pyrazine 용액에서 실리콘의 선택식각)

  • Chung, Gwiy-Sang;Lee, Chae-Bong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.112-116
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    • 2000
  • This paper presents anisotropic ethcing characteristics of single-crystal silicon in tetramethylammonium hydroxide(TMAH):isopropyl alcohol(IPA) solutions containing pyrazine. With the addition of IPA to TMAH solutions, etching characteristics are exhibited that indicate an improvement in flatness on the etching front and a reduction in undercutting, but the etch rate on (100) silicon is decreased. The (100) silicon etch rate is improved by the addition of pyrazine. An etch rate on (100) silicon of $0.8\;{\mu}m/min$, which is faster by 13 % than a 20 wt.% solution of pure TMAH, is obtained using 20 wt.% TMAH:0.5 g/100 ml pyrazine solutions, but the etch rate on (100) silicon is decreased if more pyrazine is added. With the addition of pyrazine to a 25 wt.% TMAH solution, variations in flatness on the etching front were not observed and the undercutting ratio was reduced by 30 ~ 50 %.

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The Photocatalytic Decomposition of Isopropylalcohol(IPA) Using Plastic Optical Fiber(POE) Coated Photocatalyst (광촉매가 코팅된 플라스틱 광섬유를 이용한 Isopropylalcohol 광분해 반응)

  • 홍지녀;하진욱;주현규
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.3
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    • pp.214-217
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    • 2003
  • 본 연구에서는 IPA(isopropyl alcohol)를 분해물질로 선정하여 플라스틱 광섬유(Plastic Optical Fiber, POF)에 TiO₂ 를 코팅하여 오염물질을 분해하였다. P-25가 코팅된 POF의 표면은 유기계, 무기계, 유ㆍ무기 바인더를 사용한 것 모두 깨끗하였고, 무기계 바인더를 사용하여 코팅한 POF는 부착력이 현저히 떨어졌다. IPA분해 결과, 무기계 바인더를 사용한 경우, 다른 종류의 바인더와는 다르게 IPA의 초기농도 값이 매우 작게나왔는데 이러한 결과는 반응기에 주입된 IPA가 평형이 될 때까지 기다리는 동안 흡착이 일어났기 때문으로 생각된다. 유기계 바인더를 사용하여 코팅한 POF는 IPA 분해 효율이 매우 저조하였고 유ㆍ무기 바인더를 사용하여 코팅한 POF의 IPA분해 효율은 우수하였다. P-25와 IPA의 분해 효율이 우수한 유ㆍ무기 바인더의 비율을 10 : 10, 10 : 8, 10 : 6, 10 : 4, 10 : 2로 바꾸어 IPA를 분해한 결과, P-25와 유 ㆍ 무기 바인더의 비율이 10 : 2 일 매 IPA 분해 효율이 가장 우수하였다. 또한 P-25와 코팅액 제조 시 희석제로 사용되는 에탄올의 질량비를 1 : 7, 1 : 11, 1: 15로 바꾸어 IPA를 분해한 결과, P-25와 에탄올의 비율이 1 : 15일 때 IPA분해 효율이 가장 우수하였다.

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Maximization of Extracted Condition of Pro-angiogenic Components in Citrus unshiu Peels using Dimethyl Sulfoxide

  • Lee, Jungwhoi;Kim, Myungseung;Kim, Jae Hoon
    • Natural Product Sciences
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    • v.22 no.4
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    • pp.287-292
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    • 2016
  • Aqueous extraction of Citrus unshiu peels (AECUP) is mainly comprised with pro-angiogenichesperidin and narirutin. In this study, we report approaches to increasing the yields of extracted hesperidin and narirutinfrom Citrus unshiu peels using proper solvents. Significantly improved yields of both compounds were obtained using methanol and dimethyl sulfoxide (DMSO) compared to acetonitrile, ethyl acetate, ethanol, and isopropyl alcohol. Especially, effect of DMSO was by far the better of the two solvents in extraction of hesperidin. In addition, the DMSO extracted hesperidin significantly induced the pro-angiogenic effects of human umbilical vein endothelial cells (HUVECs) and markedly up-regulated phosphorylation of the ERK1/2 signaling pathway. These results demonstrate that pro-angiogenic inducer; hesperidin and narirutin can be simply, easily, and effectively extracted from Citrus unshiu peels.

Development of Display by Screen Printing and Heat-transfer (스크린 인쇄법 및 열 전사법에 의한 디스플레이 개발)

  • 이현철;남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.102-112
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    • 2002
  • Cathode ray tubes (CRT) are the most common electronic display in use in information technology. The CRT consists of an electron gun, electrostatic or magnetic fields to direct the electron beam, and a phosphor screen. When the electron beam strikes the phosphor screen, the phosphor generates light. The phosphor screen has formed by precipitation method, electro-forming and centrifuge method. The high quality product was achieved by electro-forming or centrifuge method. Now applying method is electro-forming used with phosphor and Eh(isopropyl alcohol). Now applying method has been much consumption of raw-material, dirty working environment, dangerous fire and require of high cost. New method to form phosphor surface of monochrome is required to improve this matter. This study was developed novel method to form the phosphor surface by heat-transfer method. This method have advantages of simple process, automatization, clean environment, saving raw material and saving running-cost.

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A study on phase transition of Hydrogel: (II)Solubility of N-Isopropylacrylamide Gel (수화겔의 상전이에 관한 연구 : (II)폴리(N-이소프로필아크릴아미드)겔의 용해도)

  • Park, Sang-Bo;Hwa, Won-Jo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.21 no.1
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    • pp.81-90
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    • 2003
  • To understand the thermoresponsive volume phase transition of an N-isopropyl acrylamide(NIPA) gel on water, the solubility parameter of neutral NIPA gel was determined by swelling the gel with various solvents. Water was found not to be a good solvent for NIPA gel. Equilibrium swelling curves of NIPA gel were respectively obtained by immersing in pure water, ethanol, n-propanol and some mixed solvents. On adding a small amount of alcohols to water, volume phase transition of NIPA gel in water was changed. Phase transition temperature of this gel was decreased with the increase of the carbon number of alcohol.

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Taxonomy, Purification and Physicochemical Properties of Novel Antifungal Antibiotics AF-011A (신규 항진균 물질 AF-011A의 생산균주 동정, 정제 및 물리 화학적 특성)

  • 김성호;현봉철;서정우;김창완;연창석;이덕근;김광표;정재경;임융호
    • Microbiology and Biotechnology Letters
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    • v.21 no.6
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    • pp.556-563
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    • 1993
  • AF-011A is a novel lipopeptide with potent antifungal activity isolated from Pseudomonas cepacia AF6008 deposited as KFCC 10759. The compound was isolated from the fermentation broth by extraction with 50% isopropyl alcohol. Purification was effected by chromatography on Diaion HP-20, Alumina and C18 followed by HPTLC on silica gel. These techniques affored two closelt related compounds. AF-011A1 ans AF-011A2. The molecular weights of AF-011A1/A2 were determined by fast atom bombardment mass spectrometry(A1 m/z 1,215 : A2 m/z 1,199).

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