• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.28 no.12
• /
• pp.1573-1581
• /
• 2004

Thermodynamic principles are described with a new point of view. In present study, the interaction between two systems is focused instead of the behavior of a system in conventional thermodynamics. The state change of a system cannot occur by itself but it is the result of the interaction between systems. However, the interaction itself is also the result of another kind of interaction, the interaction between two interactions. To reconstruct thermodynamics with such a point of view, the reversible world is imagined, in which conservations and measurements are discussed. There exists a conserved quantity for each mode of reversible interaction. The conserved transferring quantity in the interaction between interactions is the effective work, which is supposed to be measurable and conserved in reversible world. Effective work is the primary concepts of energy. It is the key factor to explain measurements, energy conservation and energy dissipation. The concepts developed in reversible world are applied to the real world in which irreversible phenomena may occur. Irreversibility is the result of effective energy dissipation, in which effective work irreversibly changes into entropy. A quantitative relation between the disappearing effective work and the generated entropy is dissipation equation which is given by experiments. A special temperature scale to give a very simple type of the dissipation equation is the absolute temperature scale, which gives the conventional conservation of energy.

• Computers and Concrete
• /
• v.19 no.5
• /
• pp.501-507
• /
• 2017

The predictive utility of a damage model depends heavily on its particular choice of a damage variable, which serves as a macroscopic approximation in describing the underlying micromechanical processes of microdefects. In the case of spatially perfectly randomly distributed microcracks or microvoids in all directions, isotropic damage model is an appropriate choice, and scalar damage variables were widely used for isotropic or one-dimensional phenomenological damage models. The simplicity of a scalar damage representation is indeed very attractive. However, a scalar damage model is of somewhat limited use in practice. In order to entirely characterize the isotropic damage behaviors of damaged materials in multidimensional space, a system theory of isotropic double scalar damage variables, including the expressions of specific damage energy release rate, the coupled constitutive equations corresponding to damage, the conditions of admissibility for two scalar damage effective tensors within the framework of the thermodynamics of irreversible processes, was provided and analyzed in this study. Compared with the former studies, the theoretical formulations of double scalar damage variables in this study are given in the form of matrix, which has many features such as simpleness, directness, convenience and programmable characteristics. It is worth mentioning that the above-mentioned theoretical formulations are only logically reasonable. Owing to the limitations of time, conditions, funds, etc. they should be subject to multifaceted experiments before their innovative significance can be fully verified. The current level of research can be regarded as an exploratory attempt in this field.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2008.05a
• /
• pp.33-47
• /
• 2008

Non-equilibrium (irreversible) themodynamics is used to investigate colloidal back-diffusion during crossflow membrane filtration. The chemical potential is generalized as a superposition of equilibrium and irreversible contributions, originating from Brownian and shear-induced diffusion, respectively. As a result, an effective drag force is derived using the irreversible thermodynamics for a particle undergoing both Brownian and shear-induced diffusion in a sheared concentrated suspension. Using the drag force, a hydrodynamic force bias Monte Carlo method is developed for crossflow membrane filtration to determine the critical flux of hard sphere suspensions. Effects of shear rate and particle size on the critical flux are studied, and results show a good agreement with experimental observations reported in the literature.

• Journal of the Korean Chemical Society
• /
• v.17 no.5
• /
• pp.324-331
• /
• 1973

We study a mixture of ideal gases by use of recently developed methods in continuum thermodynamics of irreversible processes. A complete form of the free energy function and the gas law for each component are derived directly from an entropy production inequality by assuming that: (1) Constitutive functions depend on the mass densities, the diffusion velocities, the temperature and its gradient only. (2) Phenomenological coefficients appearing in an extra entropy flux are material constants. (3) The internal energy density per unit mass is independent of the total mass density (Joule).

• Journal of the Korean Ceramic Society
• /
• v.25 no.3
• /
• pp.243-250
• /
• 1988

The cross effect between an ion flux and an electronic current in a nonstoichiometric binary oxide, $A_{1-\delta}O_\mu$, has been analyzed in the light of irreversible thermodynamics. It has been shown that a net flux of the mobile cation vacancy is induced through the system in an electrical potential gradient applied across a pair of the reversible electrodes, which makes the Fick frame shift relative to the laboratory frame. As a consequence, the relative shift is a measure of the effective charge responsible for the cross effect. Two experiments are proposed to measure the shift.

• Journal of the Korean Chemical Society
• /
• v.58 no.2
• /
• pp.153-159
• /
• 2014

Herein, the cyclic voltammetric (CV) investigations of structurally similar bisnitrocompounds (N3, N4, N5, N6, having different-$CH_2$-spacer length) is presented. CV study offered interesting interactional possibilities of bisnitrocompounds with chicken blood ds.DNA at physiological pH 4.7 and human body temperature, 310 K. The results indicated strong interaction by these symmetric molecules with ds.DNA and strength of binding is found to depend on length of $CH_2$ spacer group in their molecular structure. Thermodynamics derived from electrochemical binding parameters also favored the irreversible interactions. Moreover, threading intercalation mode of binding is suggested based on thermodynamic and kinetic binding parameters extracted from CV studies.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.24 no.5 s.176
• /
• pp.1352-1361
• /
• 2000

We obtain a micromechanics-based Helmholtz free energy and then in the framework of irreversible thermodynamics, a kinetic relation, a martensitic nucleation criterion and the reorientation criterion of martensitic variants are obtained. These relations are valid for a three-dimensional proportional and non-proportional loadings and for a combination of mechanical and thermal loading. From the simulated pseudoelastic stress-strain relation of a single crystal with loading rate effect, polycrystalline behavior in case of proportional and non-proportional loading is predicted by a homogenization method. The obtained results are compared quantitatively with experimental results.

• Proceedings of the KSR Conference
• /
• 2000.05a
• /
• pp.250-257
• /
• 2000

A Helmholtz free energy for a martensitic transformation of a single crystalline shape-memory alloy is obtained by a micromechanical approach, 24 variants of the single crystal are taken into account. In the framework of irreversible thermodynamics, a kinetic relation, a martensitic nucleation criterion and the reorientation criterion of martensitic variants are obtained. These relations are valid for a three-dimensional proportional or non-proportional mechanical loading or a combination of mechanical and thermal loading. Reorientation behavior of a single crystalline shape-memory alloy CuZnAl is simulated. When a tensile load is applied to a thermally-induced martensite, 24 self-accommodated martensitic variants are reoriented to the most favorable variant. In the following unloading, the most favorable variant in the tensile load is reoriented to the most favorable variant in this loading condition.

• Journal of the Korean Chemical Society
• /
• v.40 no.6
• /
• pp.409-414
• /
• 1996

The limit of applicability of Navier-Stokes equation to stationary plane shock-waves is examined by using the principle of minimum entropy production of linear irreversible thermodynamics. In order to obtain analytic results, the equation is linearized near the equilibrium of downstream. Results show that the solution of Navier-Stokes equation which fits the boundary condition of far downstream flow is consistent with the thermodynamic requirement within the first order when the solution is expanded around the M=1, where M is the Mach number of upstream speed.

• Journal of Microbiology and Biotechnology
• /
• v.20 no.7
• /
• pp.1077-1085
• /
• 2010

With an emphasis on its thermal behavior with different pHs and salts, the kinetic and thermodynamic parameters of the purified polygalacturonase (PG) from E. carotovora subsp. carotovora (Ecc) BR1 were studied, as the characterization of an enzyme is significant in the context of burgeoning biotechnological applications. The thermodynamic parameters for polygalacturonic acid hydrolysis by the purified PG were ${\Delta}H^*$=7.98 kJ/mol, ${\Delta}G^*$=68.86 kJ/mol, ${\Delta}S^*$=-194.48 J/mol/K, ${\Delta}G_{E-S}$=-1.04 kJ/mol, and ${\Delta}G_{E-T}$=-8.96 kJ/mol. In addition, its turnover number ($k_{cat}$) was 21/sec. The purified PG was stable within a temperature range of $20-50^{\circ}C$ and was deactivated at $60^{\circ}C$ and $70^{\circ}C$. The thermodynamic parameters (${\Delta}H^*$, ${\Delta}G^*$, ${\Delta}S^*$) for the irreversible inactivation of the PG at different temperatures ($30-60^{\circ}C$) were determined, where the effectiveness of various salts and different pHs (4-8) for the thermal stability of the PG were also characterized. The efficacy of various salts for the thermal stability of the PG was in the following order: $MgCl_2$ > $BaCl_2$ > KCl > $CaCl_2$ >NaCl. Therefore, the present work presents the biochemical, substrate hydrolysis thermodynamics and the thermal stabilization parameters of the PG from Ecc.