• Title/Summary/Keyword: iron corrosion

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An Experimental Study on Chloride Ions Penetration of Mortar containing Si/Al Hybrid-Inorganic Salt (Si/Al 복합 무기염을 적용한 모르타르의 염소이온침투깊이에 대한 실험적 연구)

  • Khil, Bae-Su;Kim, Do-Su;Kang, Yong-Sik;Kim, Woo-Jae;Choi, Se-Jin;Kim, Sung-Su
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.417-418
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    • 2009
  • As iron corrosion by means of penetration of chlorides resulted in a serious deterioration of seaside and landfill concrete construction, it is urgently necessary for seaside construction to acquire watertightness and resistance for chloride-attack. Hence in this study, Si/Al liquor type hybrid-inorganic salt which was very effective compound for improving resistance for chloride-attack applied to mortar and then evaluated resistance for chloride-attack with curing(7, 14, 28, 56 days).

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New Water-soluble Cutting Fluids Additives Derived from the Thermal Reaction Products of Unsaturated Fatty Acids with Acrylic Acid and Maleic Anhydride

  • Watanabe, Shoji
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.372-376
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    • 2003
  • Water-soluble cutting fluids are used for processing of aluminium materials. This short article describes properties of new additives of water-soluble cutting fluids for aluminium materials. Various Diels-Alder adducts of unsaturated fatty acids with acrylic acid of maleic anhydride were prepared by thermal reactions. Triethanolamine salts of Diels-Alder adducts of dehydrated castor oil fatty acids with acrylic acid or maleic anhydride showed excellent anti-corrosion property of aluminium materals. These thermal adducts showed anti-rust property for cast-iron chips, too.

Development and Current Status of Gaseous Nitrocarburizing

  • Bell, Tom
    • Journal of the Korean Society for Heat Treatment
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    • v.2 no.2
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    • pp.68-83
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    • 1989
  • Physical metallurgy aspects of gaseous ferritic nitrocarburising are reviewed in the light of basic studies undertaken since 1975 which have illustrated inconsistencies between the iron-carbon-nitrogen ternary phase diagram at $570^{\circ}C$ and the experimental observation of the co-existence of the ${\varepsilon}$ carbonitride phase and ferrite. Thermodynamic investigations by Xu and Li together with those by Slycke et al are reviewed to illustrate compatability between a modified isothermal section of the Fe-C-N system and the formation and growth of a monophased ${\varepsilon}$ structure under a variety of processing conditions. The implications of the modified diagram in terms of innovations in industrial ferritic nitrocarburising practice are discussed, together with limitations on the control of the process. The importance of the developing technology of black nitrocarburising for enhanced wear, fatigue, and corrosion resistance is emphasised. Basic studies and industrial status of austenitic nitrocarburising treatments are also reviewed, which highlight the importance of substrate strengthening for high load bearing applications of anti-scuff thermochemical treatments.

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Analysis of Oxide Film on X65-Line Pile Steel Formed in Hydrogen Induced Cracking Environment by Dynamic Nano-indentation Method (동적 나노압칩법을 이용한 수소유기균열분위기에서 생성된 X65-석유수소용 강관의 산화막 분석)

  • O, Se-Beom;Gang, Bo-Gyeong;Lee, Sang-Heon;Choe, Yong;Kim, Wan-Geun;Go, Seong-Ung;Jeong, Hwan-Gyo;Lee, Chang-Seon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.155-155
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    • 2014
  • The oxide film was formed in hydrogen induced cracking (HIC) environment by potentio-dynamic method. Corrosion potentials and rates of the X-65 and X-80 line pipe steels were -0.3495 $V_{SHE}$, $2.833{\times}10^{-3}A/cm^2$ and 0.2716 $V_{SHE}$ and $2.533{\times}10^{-3}A/cm^2$, respectively. Surface composition analysis of the oxide film contained sulfur. Thermodynamic analysis of the HIC solution chemistry suggested that the oxide phase consisted of iron sulfate. Dynamic nano-indentation method applied to determine nano-hardnesses of the oxide film and base metal hardness.

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Linear Static Structural Analysis of Spent Nuclear Fuel Disposal Canister (고준위 원자핵폐기물 처분용기의 선형정적 구조해석)

  • Kwon, Young-Joo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2001.04a
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    • pp.259-266
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    • 2001
  • This paper presents the results of a structural analysis to determine design variables such as the inner basket array type, and thicknesses of the outer shell and the lid and bottom of a spent nuclear fuel disposal canister. The canister construction type introduced here is a solid structure with a cast iron insert and a corrosion resistant overpack, which is designed for the spent nuclear fuel disposal in a deep repository in the crystalline bedrock, entailing an evenly distributed load of hydrostatic pressure from the groundwater and large swelling pressure from the bentonite buffer. Hence, the canister must be designed to withstand these large pressure loads. Many design variables may affect the structural strength of the canister. In this study, among those variables, the array type of inner baskets and thicknesses of outer shell and lid and bottom are attempted to be determined through a linear static structural analysis. Canister types studied here are one for the pressurized water reactor (PWR) fuel and another for the Canadian deuterium and uranium reactor (CANDU) fuel.

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Desalting Method for Removing $Cl^-$ Ions from the Exacavated Irons Objects (출토 철제 유물의 탈염 처리 방법 고찰)

  • Moon, Whan-Suk;Hwang, Jin-Ju;Jung, Young-Dong
    • 보존과학연구
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    • s.17
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    • pp.1-19
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    • 1996
  • Desalting methods for chloride ions from the excavated iron objects were studied. These methods were compared with room temperature and heating condition of treating solution. During the Desalting treatments the $Cl^-$concentration of the solution were measured regularly and the plotted for $Cl^-$concentrations the square root of time, heating methods showed that the $Cl^-$ ions are more extracted. For the desalting treatments these plots were found to be flattening line, it was showed the changing second solution. Also, the changing solution in the room temperation detected less $Cl^-$ ions of heating treatment solution. As the examination for the relative humidity has compared for desalting objects during 8 days, it was showed a re-corroded appearance of R.H90%. As it did not detected a $Cl^-$ ions of re-corroded section, these phenomena were showed the naturally occuring corrosion of the objects in the high relative humidity.

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Electrodeposition of Zr on AISI 304 Stainless Steel in Molten Chlorides. (염화물계 혼합염욕중에서 AISI 304 Srainless Steel의 Zr 전해피복에 관한연구)

  • 반장호;백영현
    • Journal of the Korean institute of surface engineering
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    • v.30 no.3
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    • pp.159-166
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    • 1997
  • The metalliding technique was adopted to obtain the diffusion coating of zirconium on AISI 304 Stainless Steel in molten mixed chlorides (32.9wt.%LICl-34.8wt.%NaCl-32.3wt.%). Experiments were carried out in argon gas atmosphere. The electrolytic cell was consisted of a AISI 304 Stainless steel cathode and a consumable zirconium anode. The quality of deposit was analysed by SEM, Optical Microscope, EDS, and also examined by the Micro-Vickers hardness and corrosion tests. Interface of deposit layer was identified as zirconium-iron alloy layer caused by diffusion process at elevated temperatures. The optimum condition for the metalliding was found to be the bath temperature of $550^{\circ}C$, the concentration of $K_2ZrF_6$ ,5wt.%, cathodic current derrent density of 7.0 to 10.0mA/$\textrm{cm}^2$ , and anodic current density of 2.0mA/$\textrm{cm}^2$.

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Development of the 400 Series Stainless Steel Powder Sensor Ring for Use in an Antilock Brake System (400계열 스테인레스 스틸 분말을 사용한 ABS Sensor Ring 개발)

  • 양현수;곽창섭;김경환;임종국
    • Journal of the Korean Society of Safety
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    • v.13 no.3
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    • pp.60-66
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    • 1998
  • ABS sensor ring has been manufactured by P/M method using 400 series ferrite stainless steel. The results are as following: It is supposedly sufficient to use for control computer due to good experimental results of magnetic characteristics. Compared with sensor ring made by iron, 400 series ferrite stainless steel has shown a good corrosion resistance without an addition surface treatment. Thus the decreasing production process has been obtained. As a result of hardness and tensile test, 400 series ferrite stainless steel shown a good endurance when it is combined to C/V joint, and has a good hardness properties endurable to sand and pebble impact.

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A Study on Metalliding of Al on Steel from Molten Fluorides (불화물계 용융염중에서 Steel 기지 소재의 Al 전해피복에 관한 연구)

  • 이민구;서길원;백영현
    • Journal of the Korean institute of surface engineering
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    • v.26 no.4
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    • pp.183-191
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    • 1993
  • Diffusion coating(metalliding) of aluminium on steel from molten fluorides(29.2wt.% LiF-11.7wt.% NaF-59.1wt.% KF, FLINAK) was studied. The electrolytic cell consists of a steel cathode and a consumable aluminium anode. Effects of manganese on the aluminium deposition were also investigated. The quality of the deposit was analyzed by SEM, OM, EPMA, EDXA, and also examined by means of Micro-Vickers hardness and corrosion tests. Deposit layer was identified as an aluminium-rich iron alloy caused by diffusion process. The optimum condition for the metalliding was found to be the current density, 50 to $150mA/\textrm{cm}^2$, the bath tem-perature, $57.5^{\circ}C$, and the amount of AlF3, 10wt.%. Addition of manganese fluoride (up to 5wt.%) as a co-de-posit element improved significantly the quality of the deposit layer.

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Application of monodisperse Fe3O4 submicrospheres in magnetorheological fluids

  • Anupama, A.V.;Kumaran, V.;Sahoo, B.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.347-357
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    • 2018
  • Steady shear response of a magnetorheological fluid (MRF) system containing porous mono-disperse magnetite ($Fe_3O_4$) spheres synthesized by solvothermal method is demonstrated. In applied magnetic field the interaction between the spherical particles leads to form strong columnar structures enhancing the yield strength and viscosity of the MRFs. The yield strengths of the MRFs also scale up with the concentration of magnetic particles in the fluid. Considering magnetic dipolar interaction between the particles the magneto-mechanical response of the MRFs is explained. Unlike metallic iron particles, the low-density corrosion resistant soft-ferrimagnetic $Fe_3O_4$ spherical particles make our studied MRF system efficient and reliable for shock-mitigation/vibration-isolation applications.